鍙嬫儏鎻愮ず锛氭湰绔欐彁渚涘叏鍦�400澶氭墍楂樼瓑闄㈡牎鎷涙敹纰╁+銆佸崥澹爺绌剁敓鍏ュ(xu茅)鑰冭│姝峰勾鑰冪爺鐪熼銆佽€冨崥鐪熼銆佺瓟妗�锛岄儴鍒嗗(xu茅)鏍℃洿鏂拌嚦2012骞�锛�2013骞达紱鍧囨彁渚涙敹璨讳笅杓�銆� 涓嬭級娴佺▼锛� 鑰冪爺鐪熼 榛炴搳鈥�鑰冪爺瑭﹀嵎鈥濃€濅笅杓�; 鑰冨崥鐪熼 榛炴搳鈥�鑰冨崥瑭﹀嵎搴�鈥� 涓嬭級
鍐堕噾鐗╃悊鍖栧(xu茅)鑰冭│澶х侗 I 鑰冩煡鐩(bi膩o) 鎺屾彙鍐堕噾鐗╃悊鍖栧(xu茅)鐨勫熀鏈蹇�銆佸熀鏈悊璜栧強瑷堢畻鏂规硶锛屾纰洪亱鐢ㄤ簬鍒嗘瀽鍜岃В姹哄叿楂斿晱椤�銆� 鍩烘湰鐞嗚珫鍖呮嫭婧舵恫鐔卞姏瀛�(xu茅)鐞嗚珫銆丟ibbs 鑷敱鑳借畩鍖栫殑瑷堢畻銆佹噳(y墨ng)鐢ㄥ師鍓囧強娲诲害鏁�(sh霉)鎿�(j霉)鐨勭嵅寰楀師鐞� 鍜屾柟娉曘€佺浉鍦栧熀鏈師鐞嗗強鍏稿瀷浜屼笁鍏冪浉鍦栧熀绀�(ch菙)鐭ヨ瓨銆佽〃闈㈠拰鐣岄潰鍩烘湰鐞嗚珫銆佸喍閲戝嫊鍔涘(xu茅)鍩烘湰 鐞嗚珫绛夛紝鍐堕噾鍩烘湰鐔旈珨锛堢啍娓g殑鍩烘湰鐗╃悊鍖栧(xu茅)鎬ц唱(zh矛)鍙婂湪鍐堕噾涓殑浣滅敤锛�銆佽В姹哄喍閲戝闅涘晱椤� 甯哥敤鐨勫咕绋熀鏈墜娈靛拰鏂规硶锛堝寘鎷寲瀛�(xu茅)鍙嶆噳(y墨ng)绛夋韩鏂圭▼寮忓拰骞宠 绉诲嫊鍘熺悊鐨勯潏娲婚亱鐢�锛涘劒(y艒u)鍕㈠崁(q奴) 鍦栥€佷綅鍕㈠湒绛夊咕绋啽鍔涘(xu茅)鐙€鎱�(t脿i)鍦栫殑妲�(g貌u)鎴愬師鐞嗗強浣跨敤鏂规硶绛夛級銆� II 鑰冭│褰㈠紡鍜岃│鍗风祼(ji茅)妲�(g貌u) 涓€銆佽│鍗锋豢鍒嗗強鑰冭│鏅傞枔 瑭﹀嵎婊垮垎鐐� 150 鍒�锛岃€冭│鏅傞枔 180 鍒嗛悩銆� 浜�銆佺瓟椤屾柟寮� 绛旈鏂瑰紡鐐洪枆鍗�銆佺瓎瑭︺€傚厑瑷变娇鐢ㄨ▓绠楀櫒锛屼絾涓嶅緱浣跨敤甯舵湁鍏紡鍜屾枃鏈瓨鍎插姛鑳界殑瑷堢畻 鍣�銆� 涓夈€佽│鍗峰収(n猫i)瀹硅垏椤屽瀷绲�(ji茅)妲�(g貌u) 1銆佸悕瑭炶В閲嬮 6 椤�锛屾瘡灏忛 5 鍒�锛屽叡 30 鍒� 2銆佺啊绛旈 6 椤�锛屾瘡灏忛 10 鍒�锛屽叡 60 鍒� 3銆佽▓绠楄垏鍒嗘瀽椤� 4 椤�锛屽叡 60 鍒� III 鑰冩煡鍏�(n猫i)瀹� 1銆佸喍閲戠啽鍔涘(xu茅)鍩虹(ch菙) 鍖栧(xu茅)鍙嶆噳(y墨ng)鐨勬(bi膩o)婧�(zh菙n)鍚夊竷鏂嚜鐢辫兘璁婂寲鍙婂钩琛″父鏁�(sh霉)锛屾憾娑茬殑鐔卞姏瀛�(xu茅)鎬ц唱(zh矛)锛嶆椿搴﹀強娲诲害绯绘暩(sh霉)锛� 婧舵恫鐨勭啽鍔涘(xu茅)闂�(gu膩n)绯诲紡锛屾椿搴︾殑瑷堢畻鏂规硶锛屾(bi膩o)婧�(zh菙n)婧惰В鍚夊竷鏂嚜鐢辫兘鍙婃憾娑蹭腑鍙嶆噳(y墨ng)鐨勫悏甯冩柉鑷敱 鑳借▓绠�銆� 閲嶉粸锛氬寲瀛�(xu茅)鍙嶆噳(y墨ng)鐨勫悏甯冩柉鑷敱鑳借▓绠楀強鐢辨鍒ゆ柗鍖栧(xu茅)鍙嶆噳(y墨ng)閫�(j矛n)琛岀殑鏂瑰悜锛屾椿搴﹁▓绠�銆� 2銆佸喍閲戝嫊鍔涘(xu茅)鍩虹(ch菙) 鍖栧(xu茅)鍙嶆噳(y墨ng)鐨勯€熺巼锛屽垎瀛愭摯鏁e強灏嶆祦鍌宠唱(zh矛)锛屽弽鎳�(y墨ng)閬庣▼鍕曞姏瀛�(xu茅)鏂圭▼鐨勫缓绔�锛屾柊鐩稿舰鎴愮殑鍕曞姏 瀛�(xu茅)銆� 閲嶉粸锛氫竴銆佷簩绱氬寲瀛�(xu茅)鍙嶆噳(y墨ng)鍙婁竴绱氬彲閫嗗寲瀛�(xu茅)鍙嶆噳(y墨ng)閫熺巼鏂圭▼鎺ㄥ皫(d菐o)锛岃彶鍏嬬涓€銆佺浜屽畾寰�锛岄洐鑶� 鐞嗚珫锛屾湭鍙嶆噳(y墨ng)鏍告ā鍨�銆� 3銆侀噾灞啍楂� 鐔旈惖鍙婂叾鍚堥噾鐨勭祼(ji茅)妲�(g貌u)锛岄惖娑蹭腑绲勫垎娲诲害鐨勭浉浜掍綔鐢�锛岄惖娑蹭腑鍏冪礌鐨勬憾瑙e強瀛樺湪褰㈠紡锛岀啍 閻靛強鍏跺悎閲戠殑鐗╃悊鎬ц唱(zh矛)銆� 閲嶉粸锛氭椿搴︾浉浜掍綔鐢ㄧ郴鏁�(sh霉)鍙婂叾杞�(zhu菐n)鎻涢棞(gu膩n)绯汇€� 4銆佸喍閲戠垚娓� 浜屽厓绯�銆佷笁鍏冪郴鐩稿湒鐨勫熀鏈煡璀樺強鍩烘湰椤炲瀷锛屼笁鍏冩福绯荤殑鐩稿湒锛岀啍娓g殑绲�(ji茅)妲�(g貌u)鐞嗚珫锛岀啍娓� 鐨勯洟瀛愭憾娑茬祼(ji茅)妲�(g貌u)妯″瀷锛岀啍娓g殑娲诲害鏇茬窔鍦�锛岀啍娓g殑鍖栧(xu茅)鎬ц唱(zh矛)锛岀啍娓g殑鐗╃悊鎬ц唱(zh矛)銆� 閲嶉粸锛氫簩銆佷笁鍏冪郴骞宠 鐩哥殑瀹氶噺娉曞墖锛堢洿绶氭硶鍓囧拰鏉犳】瀹氬緥, 閲嶅績娉曞墖锛夛紝鍒嗘瀽绛夋韩鎴潰鍦� 鍜屾姇褰卞湒銆傜啍娓g殑绲�(ji茅)妲�(g貌u)鐞嗚珫銆� 5銆佸寲鍚堢墿鐨勫舰鎴愶紞鍒嗚В銆佹矮鐨勭噧鐕掑弽鎳�(y墨ng) 鍖栧悎鐗╃殑褰㈡垚锛嶅垎瑙e弽鎳�(y墨ng)鐨勭啽鍔涘(xu茅)鍘熺悊锛岀⒊閰搁菇鐨勫垎瑙e弽鎳�(y墨ng)锛屾哀鍖栫墿鐨勫舰鎴愶紞鍒嗚В鍙嶆噳(y墨ng)锛� 閲戝爆锛堥惖锛夋哀鍖栫殑鍕曞姏瀛�(xu茅)锛屽彲鐕�?x矛)鎬弚鐨勭噧鐕掑弽鎳�(y墨ng)锛屽浐楂旂⒊鐨勭噧鐕掑弽鎳�(y墨ng)锛岀噧鐕掑弽鎳�(y墨ng)楂旂郴姘g浉骞� 琛℃垚鍒嗙殑瑷堢畻銆� 閲嶉粸锛氬钩琛$祫鎴愯▓绠楀強鍒ゆ柗閬庣▼閫�(j矛n)琛岀殑鏂瑰悜銆� 6銆佹哀鍖栫墿閭勫師鍙嶆噳(y墨ng) 姘у寲鐗╅倓鍘熺殑鐔卞姏瀛�(xu茅)姊濅欢锛屾哀鍖栫墿鐨勯枔鎺ラ倓鍘熷弽鎳�(y墨ng)锛屾哀鍖栫墿鐨勭洿鎺ラ倓鍘熷弽鎳�(y墨ng)锛岄噾灞啽閭� 鍘熷弽鎳�(y墨ng)锛岀啍娓d腑姘у寲鐗╃殑閭勫師鍙嶆噳(y墨ng)锛岄珮鐖愬喍鐓夌殑鑴~鍙嶆噳(y墨ng)銆� 閲嶉粸锛氭哀鍖栫墿閭勫師鐨勭啽鍔涘(xu茅)姊濅欢锛屾哀鍖栫墿鐨勯枔鎺ラ倓鍘熷弽鎳�(y墨ng)锛屾哀鍖栫墿鐨勭洿鎺ラ倓鍘熷弽鎳�(y墨ng)锛岄噾灞啽 閭勫師鍙嶆噳(y墨ng)锛岄珮鐖愬喍鐓夌殑鑴~鍙嶆噳(y墨ng)鐔卞姏瀛�(xu茅)鍙婂嫊鍔涘(xu茅)銆� 7銆佹哀鍖栫啍閻靛弽鎳�(y墨ng) 姘у寲鐔旈惖鍙嶆噳(y墨ng)鐨勭墿鐞嗗寲瀛�(xu茅)鍘熺悊锛岄尦銆佺銆侀壔銆侀嚛鐨勬哀鍖栧弽鎳�(y墨ng)锛岃劔纰冲弽鎳�(y墨ng)锛岃劔纾峰弽鎳�(y墨ng)锛岃劔 纭弽鎳�(y墨ng)锛屽惛姘e強鑴埃鍙嶆噳(y墨ng)锛岃劔姘у弽鎳�(y墨ng)銆� 閲嶉粸锛氶伕鎿囨€ф哀鍖栧師鐞�锛屽厓绱犲湪娓i噾闁撶殑骞宠 鍒嗛厤甯告暩(sh霉)銆� IV. 椤屽瀷绀轰緥鍙婂弮鑰冪瓟妗� 涓€銆佽В閲嬩笅鍒楁蹇碉紙姣忛 5 鍒嗭紝鍏� 30 鍒嗭級 1銆佸亸鎽╃埦閲� 2銆佹摯鏁h劔姘� 3銆佺~瀹归噺 4銆佸寲瀛�(xu茅)鍙嶆噳(y墨ng)娲诲寲鑳� 5銆佺垚娓� 6銆佷竴娆″ぞ闆滅墿 浜�銆佺啊瑕佸洖绛斾笅鍒楀晱椤�銆傦紙姣忛 10 鍒�锛屽叡 60 鍒嗭級 1銆佸鍑虹敤浜庝簩鍏冪郴娲诲害瑷堢畻鐨勫悏鈥旀潨鏂圭▼銆� 2銆佺啊杩扮垚娓f哀鍖栬劔纾风殑鐔卞姏瀛�(xu茅)姊濅欢銆� 3銆佺啊杩扮啍娓e垎瀛愮祼(ji茅)妲�(g貌u)鍋囪銆� 4銆佺敤鍏╃ó浠ヤ笂鑴哀鍏冪礌閫�(j矛n)琛屽京(f霉)鍚堣劔姘ф槸鍚︿竴瀹氭瘮鍏朵腑浠讳竴鍠竴鍏冪礌鑴哀鏁堟灉濂�锛岀偤浠€涔�锛� 5銆佺啊杩版哀姘h綁(zhu菐n)鐖愬惞鐓夐亷绋嬭劔纰抽€熷害鐨勮畩鍖栨儏娉�锛屽鍑虹浉鎳�(y墨ng)鐨勯棞(gu膩n)绯诲紡骞惰鏄庝箣銆� 6銆佸緸姘у嫝鍦栦笂锛� TG ?? 0 锛夊彲浠ュ緱鍒板摢浜涗俊鎭�锛� 涓夈€佽│纰哄畾鍘熷绲勬垚鐐� 50%CO銆�20%O2銆�30%CO2 鐨勬贩鍚堟埃楂旂噧鐕掑悗鐨勬埃鐩哥祫鍒嗙殑婵冨害銆傦紙10 鍒嗭級 鍥涖€佸湪 1540鈩冩檪锛孎(xi脿n)e-C 绯诲収(n猫i)纰崇殑婧惰В搴︾偤 5.2%锛屽姞鍏ョ 2%鍚�锛岀⒊鐨勬憾瑙e害涓嬮檷鍒� 4.6%銆� 姹傞惖娑插収(n猫i)纭呭皪纰崇殑鐩镐簰浣滅敤绯绘暩(sh霉)锛� Si C e 銆傦紙15 鍒嗭級 浜斻€佸湪鐪熺┖鎰熸噳(y墨ng)鐖愮殑姘у寲閹傚潻鍫濆収(n猫i)鐔旂厜鍚⒊ 0.1%锛屽惈閴� 18~20%鐨勪笉閵归嫾杩斿洖鏂�锛岀垚鍏�(n猫i)鐪熺┖ 搴︾偤 10 -2 ~10 -3 mmHg銆傚晱鍦� 1600鈩冩檪姘у寲閹傚潻鍫濇槸鍚︽渻鍙楀埌渚佃潟锛燂紙15 鍒嗭級 宸茬煡锛氬悎閲戜腑纰崇殑娲诲害绯绘暩(sh霉) fc=0.2銆� 2C+O2=2CO TG 8.1 6 72 3 2 6 0 0 0 1 ???? 2Mg(g)+O2=2MgO(g) TG 4.3871428800 0 2 ???? C=[C] TG 84.4121338 0 3 ??? 鍏€佽珫杩伴洐鑶滃偝璩�(zh矛)鐞嗚珫鐨勫熀鏈榛�锛岃│鐢ㄩ洐鑶滅悊璜栫啊瑕佸垎鏋愭福閶煎弽鎳�(y墨ng)閫熷害銆傦紙20 鍒嗭級 鍙冭€冪瓟妗� 涓€銆佽В閲嬩笅鍒楁蹇碉紙姣忛 5 鍒�锛屽叡 30 鍒嗭級 1銆佸亸鎽╃埦閲忥細灏辨槸鍦ㄦ亽婧�銆佹亽澹撲笅婧舵恫鐨勫唬搴︽€ц唱(zh矛) g锛圲銆丠銆乂銆丼銆丟锛夊皪鍏剁祫鍒嗘懇鐖鹃噺 鐨勫亸寰晢鍊�銆� 2銆佹摯鏁h劔姘э細鍦ㄧ厜閶奸亷绋嬩腑锛屾牴鎿�(j霉)鍒嗛厤瀹氬緥閶兼恫涓殑[O]鍚戠啍娓d腑鎿存暎锛岃€岃垏鍔犲叆娓g浉涓殑 鑴哀鍏冪礌閫�(j矛n)琛岀殑鑴哀鍙嶆噳(y墨ng)绋辩偤鎿存暎鑴哀銆� 3銆佺~瀹归噺锛氱垚娓e绱嶆垨婧惰В纭殑鑳藉姏锛屽嵆 2/1 22 )/()(% SOS PPSC ?? 銆� 4銆佸寲瀛�(xu茅)鍙嶆噳(y墨ng)娲诲寲鑳斤細鍦ㄥ寲瀛�(xu茅)鍙嶆噳(y墨ng)涓�锛岀敱鏅€氬垎瀛愯畩鎴愭椿鍖栧垎瀛愰渶瑕佸惛鏀剁殑鏈€灏忚兘閲忋€� 5銆佺垚娓o細鐖愭福鏄伀娉曞喍閲戜腑浠ユ哀鍖栫墿鐐轰富瑕佹垚鍒嗗舰鎴愮殑澶氱祫鍒嗙啍楂斻€� 6銆佷竴娆″ぞ闆滅墿锛氱敱浜庤劔姘х敘(ch菐n)鐗╂湭鑳藉畬鍏ㄦ帓鍑鸿€屾畼鐣欏湪閶间腑鐨勫ぞ闆滅墿绋辩偤涓€娆″闆滅墿銆� 浜�銆佺啊瑕佸洖绛斾笅鍒楀晱椤屻€傦紙姣忛 10 鍒�锛屽叡 60 鍒嗭級 1锛� 瀵嚭鐢ㄤ簬浜屽厓绯绘椿搴﹁▓绠楃殑鍚夆€旀潨鏂圭▼銆� 绛旓細浜屽厓绯诲悏鈥旀潨鏂圭▼鐐猴細 02211 ???? ?? GdxGdx 鍥犵偤锛� i alnRTG i ?? ? 0lnln 2211 ?? adxadx 鍙緱锛� ? ? ? ?? 222 22 ln ln0 2 1 2 1 lnln axx ax ad x x a 鐨� 鐨� 2锛� 绨¤堪鐖愭福姘у寲鑴7鐨勭啽鍔涘(xu茅)姊濅欢銆� 绛旓細鐢辩垚娓h劔纾峰弽鎳�(y墨ng)鍙煡锛� 92 45 245 2 52 )(%)(% ][% )(% OCaP CaOFeO PPP fCaOFeOK P OP L ? ?? ? ?? 鐢变笂杩板叕寮忓彲鐭�锛岀偤浣胯劔纾峰弽鎳�(y墨ng)閫�(j矛n)琛屽畬鍏�锛屽繀瑕佺殑鐔卞姏瀛�(xu茅)姊濅欢鏄細 锛�1锛� 杓冮珮鐨勭垚娓e牽搴︼紱 锛�2锛� 杓冮珮鐨勬哀鍖栭惖鍚噺锛� 锛�3锛� 杓冧綆鐨勭啍姹犳韩搴︼紱 锛�4锛� 澶ф福閲�銆� 3锛� 绨¤堪鐔旀福鍒嗗瓙绲�(ji茅)妲�(g貌u)鍋囪銆� 绛旓細鐔旀福鍒嗗瓙绲�(ji茅)妲�(g貌u)鍋囪瑕侀粸濡備笅锛� 锛�1锛夌啍娓f槸鐢卞悇绋浕涓€х殑姘у寲鐗╁垎瀛愬強瀹冨€戜箣闁撳舰鎴愮殑寰�(f霉)闆滃寲鍚堢墿鍒嗗瓙绲勬垚鐨勭悊鎯虫憾 娑�锛� 锛�2锛夊悇绋哀鍖栫墿鍜屽叾褰㈡垚鐨勫京(f霉)闆滃寲鍚堢墿鐨勫垎瀛愪箣闁撳瓨鍦ㄨ憲鐢熸垚鍜屽垎瑙g殑骞宠 鍙嶆噳(y墨ng)銆� 锛�3锛夌啍娓d腑姣忕ó姘у寲鐗╅兘鏈夊叐绋笉鍚岀殑瀛樺湪鐙€鎱�(t脿i)锛屼互绨″柈姘у寲鐗╁垎瀛愬瓨鍦ㄧ殑鍙嚜鐢辨哀鍖� 鐗╋紝浠ュ京(f霉)闆滃寲鍚堢墿鍒嗗瓙瀛樺湪鐨勫彨绲�(ji茅)鍚堟哀鍖栫墿銆傚湪鐔旀福鐨勫垎瀛愮祼(ji茅)妲�(g貌u)鍋囪涓嚜鐢辨哀鍖栫墿鐨� 婵冨害绛変簬鍏舵椿搴�銆� 4锛� 鐢ㄥ叐绋互涓婅劔姘у厓绱犻€�(j矛n)琛屽京(f霉)鍚堣劔姘ф槸鍚︿竴瀹氭瘮鍏朵腑浠讳竴鍠竴鍏冪礌鑴哀鏁堟灉濂�锛岀偤浠€涔�锛� 绛旓細鍏╃ó浠ヤ笂鑴哀鍏冪礌閫�(j矛n)琛屽京(f霉)鍚堣劔姘ф瘮鍏朵腑浠讳竴鍠竴鍏冪礌鑴哀鏁堟灉濂�銆� 鐞嗙敱濡備笅锛� 锛�2锛� 鑴哀鍏冪礌鍏卞悓瀛樺湪浜庨嫾娑蹭腑锛岃劔姘ц兘鍔涙湁杓冨ぇ鐨勬彁楂�锛� 锛�3锛� 鑴哀鐢�(ch菐n)鐗╂槸鐔旇瀺鐨勶紝骞惰兘淇冮€�(j矛n)楂樼啍榛炴哀鍖栫墿鐔斿寲锛屾湁鍒╀簬寰為嫾娑蹭腑娑堥櫎鍑哄幓锛� 锛�4锛� 鑳戒娇瀹规槗鎻櫦(f膩)鐨勯垼銆侀巶鍦ㄩ嫾姘翠腑鐨勬憾瑙e害澧炲姞锛� 锛�5锛� 鑳戒娇澶鹃洔鐗╁舰鎱�(t脿i)鍜岀祫鎴愮櫦(f膩)鐢熻畩鍖�锛屾湁鍒╀簬鏀瑰杽閶肩殑鎬ц兘銆� 5锛� 绨¤堪姘ф埃杞�(zhu菐n)鐖愬惞鐓夐亷绋嬭劔纰抽€熷害鐨勮畩鍖栨儏娉�锛屽鍑虹浉鎳�(y墨ng)鐨勯棞(gu膩n)绯诲紡骞惰鏄庝箣銆� 绛旓細姘ф埃杞�(zhu菐n)鐖愯劔纰抽亷绋嬪彲浠ュ垎鐐轰笁鍊嬮殠娈碉紝鍚圭厜鍒濇湡浠ョ鐨勬哀鍖栫偤涓�锛岃劔纰抽€熷害杓�?銆傝緣璇�?br/>鐓変腑鏈�锛岃劔纰抽€熷害骞句箮鐐哄畾鍊�锛涘惞鐓夊悗鏈�锛岄毃钁楅噾灞腑鍚⒊閲忕殑娓涘皯锛岃劔纰抽€熷害涔熼檷浣�銆傚洜 姝�锛屾暣鍊嬭劔纰抽亷绋嬩腑鑴⒊閫熷害璁婂寲鐨勬洸绶氬舰鎴愮偤鑷洪殠褰�銆� 鍚勯殠娈电殑鑴⒊閫熷害鍙互瀵嚭浠ヤ笅闂�(gu膩n)绯诲紡锛� 绗竴闅庢锛� tk dt Cd 1 ][ ?? 绗簩闅庢锛� 2 ][ k dt Cd ?? 绗笁闅庢锛� ][ ][ 3 Ck dt Cd ?? 鍏朵腑锛歬1鈥斺€旀焙瀹氫簬[Si]鍙婄啍姹犳韩搴︾瓑鍥犵礌鐨勫父鏁�(sh霉)锛� t 鈥斺€斿惞鐓夋檪闁�锛� k2鈥斺€旈珮閫熻劔纰抽殠娈电敱姘ф埃娴侀噺鎵€纰哄畾鐨勫父鏁�(sh霉)锛� k3鈥斺€旂⒊鍚噺娓涗綆鍚�锛岃劔纰冲弽鎳�(y墨ng)鍙楃⒊鐨勫偝璩�(zh矛)鎺у埗鏅�锛岀敱姘ф祦閲�銆佹浣嶇瓑姹哄畾鐨勫父 鏁�(sh霉)銆� 6锛� 寰炴哀鍕㈠湒涓婏紙 TG ?? 0 锛夊彲浠ュ緱鍒板摢浜涗俊鎭紵 绛旓細锛�1锛� TG ?? 0 鐨勯棞(gu膩n)绯绘槸鐩寸窔锛岀洿绶氱殑鏂滅巼鏄哀鍖栫墿鐢熸垚鍙嶆噳(y墨ng)鐔电殑璨�(f霉)鍊硷紙- 0 鍙� S? 锛夈€傜暥(d膩ng)鍙� 鎳�(y墨ng)鐨� 0 鍙� S? 鐐鸿矤(f霉)鍊兼檪锛岀洿绶氱殑鏂滅巼鐐烘锛岃〃鏄庢哀鍖栫墿鐨勭┅(w臎n)瀹氭€ч毃婧害鍗囬珮鑰屾笡灏�銆傜暥(d膩ng)鍙嶆噳(y墨ng)鐨� 0 鍙� S? 鐐烘鍊兼檪锛岀洿绶氱殑鏂滅巼鐐鸿矤(f霉)锛岃〃鏄庢哀鍖栫墿鐨勭┅(w臎n)瀹氭€ч毃婧害鍗囬珮鑰屽澶�銆傜暥(d膩ng)鍙嶆噳(y墨ng)鐨� 0 鍙� S? 鎺ヨ繎浜庨浂鏅�锛岀洿绶氱殑鏂滅巼瓒ㄤ簬闆�锛岃〃鏄庢哀鍖栫墿鐨勭┅(w臎n)瀹氭€т笉闅ㄦ韩搴﹁€屾敼璁�銆� 锛�2锛夊湪宸茬煡婧害鍜屾埃鐩镐腑姘х殑澹撳姏鏅�锛屽彲浠ョ⒑瀹氶噾灞垨姘у寲鐗╃殑绌�(w臎n)瀹氭€�銆� 锛�3锛夊湪鎸囧畾鐨勬韩搴︿笅鍙互姣旇純鍚勭ó姘у寲鐗╃殑鐩稿皪绌�(w臎n)瀹氭€�銆� 锛�4锛夊彲浠ョ⒑瀹� CO/CO2 鎴� H2O/H2 娣峰悎姘e皪閲戝爆鐨勬哀鍖栭倓鍘熶綔鐢ㄣ€� 涓�銆佽│纰哄畾鍘熷绲勬垚鐐� 50%CO銆�20%O2銆�30%CO2 鐨勬贩鍚堟埃楂旂噧鐕掑悗鐨勬埃鐩哥祫鍒嗙殑婵冨害銆傦紙10 鍒嗭級 瑙o細鍙� 100m 3 鐨勬贩鍚堟埃楂旂偤瑷堢畻鍩虹(ch菙)銆� 瑭查珨绯诲収(n猫i)鐨勫弽鎳�(y墨ng)鐐猴細2CO+O2=2CO2 鍙煡 CO 鑸� O2 鍙嶆噳(y墨ng)鐨勬懇鐖鹃噺姣旂偤 2锛�1銆傚洜姝� 20m 3 鐨� O2 鍜� 40m 3 鐨� CO 鍙嶆噳(y墨ng)锛屽舰鎴� 40m 3 鐨� CO2锛岃€屽師濮嬬祫鎴愪腑 50m3 CO 涓紝鍓╀綑 10m3 CO锛岃€屾哀姘e墖鍏ㄩ儴鍙嶆噳(y墨ng)銆� 鏁呭钩琛℃埃鐩哥殑绺介珨绌嶇偤锛�10m 3 CO+70m 3 CO2銆� 鍥犳锛岀噧鐕掑悗鐨勬埃鐩稿钩琛℃垚鍒嗙偤锛� CO=10/80脳100%=12.5% CO2=70/80脳100%=87.5% 鍥�銆佸湪 1540鈩冩檪锛孎(xi脿n)e-C 绯诲収(n猫i)纰崇殑婧惰В搴︾偤 5.2%锛屽姞鍏ョ 2%鍚庯紝纰崇殑婧惰В搴︿笅闄嶅埌 4.6%銆� 姹傞惖娑插収(n猫i)纭呭皪纰崇殑鐩镐簰浣滅敤绯绘暩(sh霉)锛� Si C e 銆傦紙15 鍒嗭級 瑙o細閻垫恫涓⒊鐨勬憾瑙e弽鎳�(y墨ng)鐐猴細 椋界煶 ][% CC ? 鍙嶆噳(y墨ng)鐨勫钩琛″父鏁�(sh霉) ][C aK ? 銆� 妯�(bi膩o)婧�(zh菙n)鎱�(t脿i)鐩稿悓鏅�锛孎(xi脿n)e鈥擟 绯诲拰 Fe鈥擟鈥擲i 绯荤殑骞宠 甯告暩(sh霉)鎳�(y墨ng)鐩哥瓑銆� 鍗筹細 ][%][% CfCff C CSi Si C C C ? 13.16.4/2.5 ][% ][% ??? Si Si C C C f 鍋囧畾鍦� 0~2%Si 婵冨害鑼冨湇鍏�(n猫i)锛� ][%lg Sif Si C ? 鎴愮窔鎬ч棞(gu膩n)绯伙紝鍙緱锛� 2 1065.2 2 13.1lg ][% lg ][% lg ? ??? ? ? ? ? ? ? Si f Si f e Si C Si CSi C 浜�銆佸湪鐪熺┖鎰熸噳(y墨ng)鐖愮殑姘у寲閹傚潻鍫濆収(n猫i)鐔旂厜鍚⒊ 0.1%锛屽惈閴� 18~20%鐨勪笉閵归嫾杩斿洖鏂�锛岀垚鍏�(n猫i)鐪熺┖ 搴︾偤 10 -2 ~10 -3 mmHg銆傚晱鍦� 1600鈩冩檪姘у寲閹傚潻鍫濇槸鍚︽渻鍙楀埌渚佃潟锛燂紙15 鍒嗭級 宸茬煡锛氬悎閲戜腑纰崇殑娲诲害绯绘暩(sh霉) fc=0.2銆� 2C+O2=2CO TG 8.167232600 0 1 ???? 2Mg(g)+O2=2MgO(g) TG 4.3871428800 0 2 ???? C=[C] TG 84.4121338 0 3 ??? 瑙o細鍥犵偤 2C+O2=2CO TG 8.167232600 0 1 ???? 2Mg(g)+O2=2MgO(g) TG 4.3871428800 0 2 ???? C=[C] TG 84.4121338 0 3 ??? 鍥犳鍙緱 MgO 琚镜铦曠殑鍙嶆噳(y墨ng)鐐猴細 2Mg(s)+[C]=Mg(g)+CO KRTG ln 0 4 ??? 鍏朵腑锛� 235.76T-576762 2 1 2 1 0 3 0 2 0 1 0 4 ???????? GGGG 鍦� 1873K 鏅傚彲浠ユ眰寰� 0 4 G? =135183.52J锛屽墖锛� 681.8 1873314.8 52.135183 ln 0 4 ?? ? ?? ? ?? RT G K 姹傚緱锛欿=1.7脳10 -4 1.02.0][% 22 ? ?? ? ? CO C CO C COMg P Cf P a PP K PCO=1.84脳10-3 atm=1.4mmHg 鍙嶆噳(y墨ng)鏋愬嚭姘i珨鐨勫鍔涚偤 PMg+PCO=2.8mmHg锛屾鍊奸仩(yu菐n)澶т簬鐖愬収(n猫i)鐨勫鍔� 10-2 ~10-3 mmHg锛� 鎵€浠ュ弽鎳�(y墨ng)鑳藉閫�(j矛n)琛�锛屽潻鍫濇渻琚镜铦�銆� 鍏€佽珫杩伴洐鑶滃偝璩�(zh矛)鐞嗚珫鐨勫熀鏈榛�锛岃│鐢ㄩ洐鑶滅悊璜栫啊瑕佸垎鏋愭福閶煎弽鎳�(y墨ng)閫熷害銆傦紙20 鍒嗭級 绛旓細1.闆欒啘鍌宠唱(zh矛)鐞嗚珫鐨勫熀鏈榛炲涓嬶細 锛�1锛� 鍦ㄥ叐鍊嬬浉锛堟恫-娑�銆佹埃-娑诧級鐨勭浉鐣岄潰鍏╁伌(c猫)閮芥湁涓€灞ら倞鐣岃杽鑶滐紝閫欏堡钖勮啘灏嶇墿璩�(zh矛)寰炰竴 鐩搁€�(j矛n)鍏ュ彟涓€鐩稿缓绔嬩簡鍩烘湰鐨勫偝璩�(zh矛)闃诲姏銆� 锛�2锛� 鍦ㄥ叐灞よ杽鑶滀箣闁撶殑鐣岄潰涓婅檿浜庡嫊鎱�(t脿i)骞宠 銆� 锛�3锛� 姣忕浉涓祫鍏冪殑鎿存暎璩�(zh矛)娴侊紙j锛� ? ?ill CCkj ?? 鎴� ? ?gig ppkj ?? 鍏朵腑锛� l l l D k ? ? 锛� g g g RT p k ? ? 锛�4锛� 钖勮啘涓殑娴侀珨鏄潨姝笉鍕曠殑锛屼笉鍙楁祦楂旈珨鍏�(n猫i)娴佸嫊鐙€鎱�(t脿i)鐨勫奖闊�锛屽悇鐩镐腑鍌宠唱(zh矛)鐛ㄧ珛閫�(j矛n)琛�锛� 浜掍笉褰遍熆銆� 2锛庢福閶煎弽鎳�(y墨ng)閫熷害鐨勫垎鏋� 灏嶅涓嬫福閶煎弽鎳�(y墨ng)锛歔A]+(B Z+ )=(A Z+ )+[B] 鍦ㄩ嫾娑茶啘鐨勪竴鍋�(c猫)鐨勬摯鏁h唱(zh矛)娴侊細 ? ?* ][][][][ AAAA CCkj ?? 锛�1锛� 鍦ㄦ福鑶滅殑涓€鍋�(c猫)鐨勬摯鏁h唱(zh矛)娴侊細 ? ?锛夛紙锛夛紙锛夛紙 AAAA CCkj ?? * )( 锛�2锛� 濡傛灉鐣岄潰涓婂寲瀛�(xu茅)鍙嶆噳(y墨ng)閫熷害寰堝揩锛岀晫闈笂鐨勫弽鎳�(y墨ng)閬�(d谩)鍒板嫊鎱�(t脿i)骞宠 锛屽墖锛� K C C A A ?* ][ * )( 锛�3锛� 鐢变簬鐣岄潰鍏╁伌(c猫)鐐虹┅(w臎n)鎱�(t脿i)鍌宠唱(zh矛)锛屾晠绲勫厓 A 鍦ㄥ叐鑶滀腑鐨勬摯鏁h唱(zh矛)娴佹噳(y墨ng)鐩哥瓑銆傚嵆锛� )(][ AAA jjj ?? 锛�4锛� ? ? ? ? ? ? ? ? ? ? ?? ? ? ? ? ? ? ? ? ???? K C K C Kk K C CkCCkj AA A A AAAAAA )( * )( )( * )( ][][ * ][][][ 锛�5锛� K C C k j A A A A * )( ][ ][ ?? 锛�6锛� K C K C Kk j AA A A )( * )( )( ?? 锛�7锛� 鍙緱锛� Kkk K C C j AA A A A )(][ )( ][ 11 ? ? ? 锛�8锛� 鐣�(d膩ng)鐣岄潰鍖栧(xu茅)鍙嶆噳(y墨ng)閫熷害姣旀福銆侀嫾鍏╃浉涓殑鍌宠唱(zh矛)閫熷害蹇緱澶氭檪锛屽弽鎳�(y墨ng)绺介€熷害鐢憋紙8锛夊紡?j墨ng)Q瀹�銆� 鐣�(d膩ng)鐣岄潰鍖栧(xu茅)鍙嶆噳(y墨ng)閫熷害鑸囨福閶煎叐鐩镐腑鐨勫偝璩�(zh矛)閫熷害鐩稿樊涓嶅緢澶ф檪锛屽繀闋堣€冩叜鐣岄潰鍖栧(xu茅)鍙嶆噳(y墨ng)閫熷害灏� 绺介€熷害鐨勫奖闊�銆�
鍏嶈铂(z茅)鑱叉槑锛氭湰鏂囩郴杞�(zhu菐n)杓夎嚜缍�(w菐ng)绲�(lu貌)锛屽鏈変镜鐘紝璜嬭伅(li谩n)绯绘垜鍊戠珛鍗冲埅闄�锛屽彟锛氭湰鏂囧儏浠h〃浣滆€呭€嬩汉瑙€榛�锛岃垏鏈恫(w菐ng)绔欑劇闂�(gu膩n)銆傚叾鍘熷壍(chu脿ng)鎬т互鍙婃枃涓櫝杩版枃瀛楀拰鍏�(n猫i)瀹规湭缍�(j墨ng)鏈珯璀夊锛屽皪鏈枃浠ュ強鍏朵腑鍏ㄩ儴鎴栬€呴儴鍒嗗収(n猫i)瀹广€佹枃瀛楃殑鐪熷鎬�銆佸畬鏁存€�銆佸強鏅傛€ф湰绔欎笉浣滀换浣曚繚璀夋垨鎵胯锛岃珛璁€鑰呭儏浣滃弮鑰�锛屽苟璜嬭嚜琛屾牳瀵︾浉闂�(gu膩n)鍏�(n猫i)瀹�銆�
|