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I 鑰冩煡鐩........................................................................................ 2
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III 鑰冩煡鍏у..................................................................................... 2
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I 鑰冩煡鐩
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鐨勭稉婵熷缓瑷煿椁�(y菐ng)鍏锋湁鑹ソ鑱锋キ(y猫)閬撳痉銆佹硶鍒惰蹇靛拰鍦嬮殯瑕栭噹銆佸叿鏈夎純寮峰垎鏋愯垏瑙ｆ焙瀵﹂殯鍟忛鑳�
鍔涚殑楂樺堡娆�銆佹噳鐢ㄥ瀷銆佸京鍚堝瀷鐨勫寲瀛稿伐绋嬪皥妤�(y猫)浜烘墠銆傚叿楂旇€冭│瑕佹眰鐐猴細
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II 鑰冭│褰㈠紡鍜岃│鍗风祼妲�
涓€銆佽│鍗锋豢鍒嗗強鑰冭│鏅傞枔
瑭﹀嵎婊垮垎鐐� 150 鍒�锛岃€冭│鏅傞枔 180 鍒嗛悩銆�
浜�銆佺瓟椤屾柟寮�
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鐢ㄥ付鏈夊叕寮忓拰鏂囨湰瀛樺劜鍔熻兘鐨勮▓绠楀櫒銆�
涓�銆佽│鍗峰収瀹硅垏椤屽瀷绲愭
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瑷堢畻椤� 9 椤岋紝姣忓皬椤� 10 鍒�锛屽叡 90 鍒�
III 鑰冩煡鍏у
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绗簩绔� 鐔卞姏瀛哥浜屽畾寰�
1锛� 鍗¤寰挵(hu谩n)銆佸崱璜惧畾鐞嗐€佺啽姗熸晥鐜囪〃閬斿紡銆�
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绗笁绔� 澶氱祫鍒嗙郴绲�(t菕ng)鐨勭啽鍔涘
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绗叚绔� 鐩稿钩琛�
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鐩告暩鍜岃嚜鐢卞害 F銆傚吀鍨嬪寲瀛稿弽鎳夌郴绲�(t菕ng)鐨勭祫鍒嗘暩銆佺浉鏁稿拰鑷敱搴︾殑鍒ゆ柗銆傛潬妗胯(gu墨)鍓囬仼鐢ㄧ殑
姊濅欢銆�
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鐩稿湒銆�
绗竷绔� 闆诲寲瀛�
1锛� 闆昏В璩憾娑茬殑灏庨浕姗熺悊鈥斺€旀硶鎷夌瀹氬緥锛涢€茶绨″柈瑷堢畻銆�
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鐨勮▓绠�锛涘挤寮遍浕瑙ｈ唱鐒￠檺绋€閲嬫懇鐖鹃浕灏庣巼鐨勬眰娉曪細锛�1锛夌敱鍠崹闆㈠瓙鐨勭劇闄愮█閲嬬殑鎽╃埦
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6锛� 楣芥⿱鐨勪綔鐢紱鑳戒綔楣芥⿱鐨勫寲瀛哥墿璩槸浠€涔�锛�
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妤典笂鐧�(f膩)鐢熷弽鎳夌殑鍏堝悗闋嗗簭纰哄畾锛涢浕妤靛弽鎳夌殑鎳夌敤銆�
绗叓绔� 鐣岄潰鑸囪啝楂斿寲瀛�
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4锛� 鑶犻珨鐨勭壒榛�銆佽啝鍦樼殑绲愭琛ㄩ仈鍜岄浕鍕曠従璞�銆傚 Fe(OH)3銆丄s2S3銆丄gI 婧惰啝绛夈€�
绗節绔� 鍖栧鍕曞姏瀛�
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4锛� 闃跨疮灏肩儚鏂叕寮忥細鎸囨暩寮�銆佸井鍒嗗紡銆佸畾绌嶅垎寮忓拰涓嶅畾绌嶅垎寮�锛涙渻纰哄畾鏈€浣虫韩搴︼紝骞惰垏婵�
搴�-鏅傞枔闂滅郴缍滃悎閬嬬敤銆�
5锛� 閺堝弽鎳夌殑绋銆佺壒榛炲拰姗熺悊銆傚皪宄欏弽鎳�銆佸钩琛屽弽鎳夊拰鑱珛鍙嶆噳鐨勫嫊鍔涘鐗瑰緛銆�
6锛� 婧舵恫涓殑鍙嶆噳锛氭椿鍖栨帶鍒剁殑鍙嶆噳鑸囨摯鏁ｆ帶鍒剁殑鍙嶆噳銆�
7锛� 鍌寲鍔戠殑浣滅敤鍘熺悊锛屼互鍙婂皪鍙嶆噳閫熺巼鐨勫奖闊�銆傞€氶亷绨″柈瑷堢畻姣旇純閫熺巼鐨勫ぇ灏�銆�
IV. 椤屽瀷绀轰緥鍙婂弮鑰冪瓟妗�
涓€銆侀伕鎿囬锛�20 鍒嗭紝姣忛 2 鍒嗭級
1. 鏌愭埃楂旂殑鐙€鎱�(t脿i)鏂圭▼鐐� pVm=RT+bp(b 鐐哄ぇ浜庨浂鐨勫父鏁�)锛屾姘ｉ珨閯�(xi膩ng)閹�(zh猫n)绌虹禃鐔辫啫鑴瑰悗鐨勬韩搴�
灏� 锛� 锛�
锛圓锛変笉璁�锛� (B) 涓婂崌锛� (C) 涓嬮檷锛� (D) 涓嶇⒑瀹�
2. NH4HS(s) 鍜屼换鎰忛噺鐨� NH3(g) 鍙� H2S(g) 閬斿钩琛℃檪锛岀崹绔嬬祫鍒嗘暩銆佺浉鏁稿拰鑷敱搴﹀垎鍒ョ偤
锛� 锛�
锛圓锛塁=2, 桅=2锛宖=2 ; (B) C=1, 桅=2锛宖=1;
(C) C=2, 桅=3锛宖=2 ; (D) C=3, 桅=2锛宖=3;
3. 娑叉厠(t脿i)姘村湪 373K 鍙� 101325Pa 涓嬫苯鍖栫偤姘磋捀姘�锛屽墖瑭查亷绋嬬殑 锛� 锛�
(A) ?G=0; (B) ?S=0; (C) ?A=0; (D) ?H=0
4. 鏌愬師闆绘睜鍦ㄧ瓑婧瓑澹撴浠朵笅鍙€嗘斁闆�锛屽墖闆绘睜鍙嶆噳鐨勭創璁�?fHm鑸囩瓑澹撳彲閫嗙啽鏁堟噳 Qp 鐨勯棞
绯荤偤 锛� 锛�
锛圓锛� ?fHm锛濹p; (B) ?fHm锛淨p; (C) ?fHm=Qp ; (D) 涓嶈兘纰哄畾
5. PCl5(g)鐨勫垎瑙ｅ弽鎳夋槸 PCl5(g)=PCl3(g)+Cl2(g)鍦� 473K 閬斿埌骞宠 鏅� PCl5(g)鏈� 48.5%鍒嗚В锛屽湪
573K 骞宠 鏅�锛屾湁 97%鍒嗚В锛屽墖姝ゅ弽鎳夌偤 锛� 锛�
锛圓锛夋斁鐔卞弽鎳�; (B) 鍚哥啽鍙嶆噳;
(C) 鏃笉鍚哥啽涔熶笉鏀剧啽; (D) 閫欏叐鍊嬫韩搴︿笅鐨勫钩琛″父鏁哥浉绛�
6. 寮烽浕瑙ｈ唱 MgCl2 姘存憾娑�锛屽叾闆㈠瓙骞冲潎娲诲害 a卤鑸囬浕瑙ｈ唱娲诲害 aB 涔嬮枔闂滅郴鐐� 锛� 锛�
锛圓锛塧卤= aB; (B) a卤= aB
1/2
; (C) a卤= aB
1/3
; (D)a卤= aB
3
7. 涓嬪垪鍏╅浕姹犲弽鎳夌殑妯欐簴闆诲嫊鍕㈠垎鍒ョ偤 E1
胃
鍜� E2
胃
,鍓囧叐鍊嬪€煎緱闂滅郴鐐猴細 锛� 锛�
锛�1锛�1/2 H2(p
胃
)+ 1/2 Cl2(p
胃
)=HCl(a=1)
(2) 2HCl(a=1)=H2(p
胃
)+ Cl2(p
胃
)
(A) E1
胃
= 2E2
胃
; (B) E1
胃
=-2E2
胃
; (C) E2
胃
=-E1
胃
; (D)E2
胃
=2E1
胃
8. 浠讳綍绱氭暩鐨勫弽鎳�锛屽叾鍗婅“鏈熼兘鑸� 锛� 锛�
(A) k,c0 鏈夐棞锛� (B) c0 鏈夐棞; (C) k 鏈夐棞; (D) k, c0 鐒￠棞
9. 鏈変竴绋€婧舵恫璩噺鎽╃埦婵冨害鐐� m锛屾哺榛炲崌楂樺€肩偤鈻砊b锛屽嚌鍥洪粸闄嶄綆鍊肩偤鈻砊f锛屽墖 锛� 锛�
(A) 鐒＄⒑瀹氶棞绯�; (B) 鈻砊f锛濃柍Tb (C) 鈻砊f锛溾柍Tb; (D)鈻砊f锛炩柍Tb
10. 鍦ㄦ婧栫媭鎱�(t脿i)涓嬶紝绱呰景鐮偽� -HgS 鑸囬粦杈扮爞尾 -HgS 鐨勮綁鎻涘弽鎳壩� -HgS=尾 -HgS锛屽叾涓柍rGm
胃
=
锛�980-1.456T锛�锛屽墖鍦� 373K 鏅� 锛� 锛�
(A) 鐒℃硶鍒ゆ柗浣曡€呯┅(w臎n)瀹�; (B)绱呰景鐮偽� -HgS 鑸囬粦杈扮爞尾 -HgS 铏曚簬骞宠
(C) 绱呰景鐮偽� -HgS 杓冮粦杈扮爞尾 -HgS 绌�(w臎n)瀹�; (D)榛戣景鐮偽� -HgS 杓冪磪杈扮爞伪 -HgS 绌�(w臎n)瀹�
椤岃櫉 1 2 3 4 5 6 7 8 9 10
绛旀 A A A B B C C C D D
浜�銆� 璜栬瓑椤岋紙40 鍒�锛屾瘡椤� 8 鍒嗭級
1. 灏囧寲瀛稿弽鎳� H2(g)+1/2O2(g)鈫扝2O(l)瑷▓鎴愪竴鍊嬪師闆绘睜锛屽鍑鸿┎鍘熼浕姹犵殑琛ㄩ仈寮�銆傝│鍟忚┎
闆绘睜闆诲嫊鍕㈣垏婧舵恫鐨� pH 鍊兼湁闂滃棊锛熺偤浠€涔�锛�
绛旓細Pt,H2(g)|H2SO4(aq)|O2(g),Pt銆傞浕鍕曞嫝鐨勮兘鏂壒(Nernst)鏂圭▼琛ㄩ仈寮�
aa
a
F
RT
EE
OH
OHo
21
22
2
2 /
ln?? 銆�
鐢辨寮忓彲浠ョ湅鍑猴紝闆诲嫊鍕㈣垏婧舵恫鐨� pH 鐒￠棞銆�
2. 灏� 0.010dm
3
銆�0.02mol?dm
-3
AgNO3 婧舵恫锛岀珐鎱㈠湴婊村姞鍒� 0.100dm
3
銆�0.005mol?dm
-3
鐨� KCl
婧舵恫涓�锛屽彲寰楀埌 AgCl 婧惰啝锛岃│瀵嚭鍏惰啝鍦樼祼妲嬬殑琛ㄧず寮忥紝骞舵寚鍑鸿啝楂旂矑瀛愰浕娉崇殑鏂瑰悜銆�
绛旓細AgNO3 鑸� KCl 鍙嶆噳鍚�,KCl 鏈夐亷閲�,寰楀埌鐨� AgCl 婧惰啝鍎�(y艒u)鍏堝惛闄� Cl
?
闆㈠瓙,鍥犳鑶犳牳甯舵闆�.
鍦ㄩ浕娉充腑鑶犵矑鍚戣矤妤电Щ鍕�.鑶犲湗绲愭鐐�: [(AgCl)m路nCl
?
路(n-x)K
+
]
x?
路xK
+
3锛�298K 鏅� A 鍜� B 鍏╃ó姘ｉ珨鍦ㄦ煇涓€婧跺姂涓憾瑙ｇ殑浜埄甯告暩鍒嗗垾鐐� kA 鍜� kB锛屼笖 kA>kB锛岀暥 A
鍜� B 鐨勫钩琛″鍔涚浉鍚屾檪锛屽墖鍦ㄨ┎婧舵恫涓摢绋埃楂旂殑婵冨害澶�锛熷鏋滆鎻愰珮姘ｉ珨鍦ㄦ憾鍔戜腑鐨勬憾
瑙ｅ害锛屾噳閲囩敤鍝簺鏂规硶锛�
绛旓細鏍规摎浜ㄥ埄瀹氬緥锛岀暥 A 鍜� B 鍏╃ó姘ｉ珨鐨勫钩琛″垎澹撶浉绛夋檪锛屾湁 1??
xk
xk
p
p
BB
AA
B
A
銆傚洜鐐� kBxA銆侭 姘ｉ珨鍦ㄦ憾娑蹭腑鐨勬績搴﹀ぇ浜� A 姘ｉ珨銆�
4锛庡伐妤�(y猫)涓婂埗姘寸叅姘ｅ弽鎳夌偤锛欳(s)+H2O(g)=CO(g)+H2(g)锛屽弽鎳夌殑妯欐簴鎽╃埦鐒撹畩?y艒u)?33.5kJmol
-1
锛�
瑷弽鎳夊湪 673K 鏅傞仈鍒板钩琛°€傝│瑷庤珫濡備笅鍥犵礌灏嶅钩琛＄殑褰遍熆锛屽苟灏囩祼鏋滃～鍏ヤ笅琛ㄤ腑銆�(绲愭灉
蹇呴爤瀵湪绛旈绱欎笂)
褰遍熆鍥犵礌
(1)鍗囬珮
鍙嶆噳婧害
(2)澧炲姞
N2 鍒嗗
(3)澧炲姞
绺藉
(4)澧炲姞
C(s)鐨勫惈閲�
骞宠 绉诲嫊鏂瑰悜(濉€滃悜宸︹€�銆佲€滃悜
鍙斥€濇垨鈥滀笉绉诲嫊鈥濅腑鐨勪竴鍊嬮伕闋�)
鍚戝彸 鍚戝彸 鍚戝乏 涓嶇Щ鍕�
5. 闆诲嫊鍕㈢殑婧害绯绘暩
?
?
?
?
?
?
?
?
T
E
p
濡備綍娓畾锛熻│瀵嚭鎳夋脯鐨勬暩鎿氬強鐩搁棞鏁稿铏曠悊閬庣▼銆�
绛旓細閲濆皪鐗瑰畾鐨勯浕姹�锛屾脯瀹氫笉鍚屾韩搴︿笅鐨勯浕鍕曞嫝锛屼竴鑸閬告搰浜斿€嬫韩搴�銆傚皣鐛插緱鐨勪簲绲勬暩鎿�
(T,E)锛屼互闆诲嫊鍕㈢偤绺卞潗妯�锛屾韩搴︾偤姗潗妯欎綔鍑� E~T 鏇茬窔锛岀劧鍚庡湪鏇茬窔涓婁綔鏌愭韩搴﹀皪鎳夐粸鐨�
鍒囩窔锛屽垏绶氱殑鏂滅巼鍗崇偤闆诲嫊鍕㈢殑婧害绯绘暩?锛涜洏鍝備滑顚嶁偓鎿悎鏂规硶寰楀埌 E~T 鏂圭▼锛屽皪鏂圭▼姹�
涓€闅庡皫鏁�锛屽苟浠ｅ叆婧害鍊煎嵆寰楀埌婧害绯绘暩銆�
涓�銆佽▓绠楅锛�90 鍒�锛屾瘡椤� 10 鍒嗭級
1. 5mol 闆欏師瀛愮悊鎯虫埃楂�(
RC mp
2
7
?,
)锛屾亽瀹瑰姞鐔�,寰� 120K 鍒� 240K锛屾眰姝ら亷绋� Q銆乄銆佄擴銆�
螖H 鐨勫€�銆�
绛旓細鏍规摎
RC mp
2
7
,
?
鍙緱锛�
RRC mp
2
5
R-
2
7
,
??
鐢变簬閬庣▼鎭掑锛屽墖 W=0銆�
kJTTCnUQ mvV
47121202403148
2
5
512 .)(.)(, ??????????
kJTTCnH mp 46171202403148
2
7
512 .)(.)(, ?????????
2. 鍦ㄦ按鐨勬甯告哺榛�(373K 鍜� 101.325kPa)锛屾湁 1mol H2O(l)璁婃垚鍚屾韩鍚屽涓嬬殑 H2O(g)锛屽凡鐭�
姘寸殑鎽╃埦姹藉寲鐒撹畩鍊� molkJH mvap ???
?1
6940 .
銆傝珛瑷堢畻瑭茶畩鍖栫殑 Q銆乄銆佄擴銆佄擧銆佄擲銆佄擜銆�
螖G 鐨勫€煎悇鐐哄灏�锛�(蹇界暐娑查珨楂旂⿳锛屾按钂告埃瑕栫偤鐞嗘兂姘ｉ珨)
绛旓細姘村湪姝ｅ父娌搁粸涓嬫苯鍖�锛屾槸涓€鍊嬬瓑澹撻亷绋嬶紝鎵€浠ユ湁锛�
694069401 .. ????? HnQ mvapp kJ
?H=Qp=40.69 kJ
1mol 姘村湪姹藉寲閬庣▼鎵€鍋氱殑鍔熺偤锛�
kJnRTVpVVpW glg 1031537331481 ...)( ?????????????
?U=Qp+W=40.69-3.10=37.59 kJ
?S= Qp/T=40690/373=109.09 J?K
-1
锛�?A=W= -3.10kJ锛�?G=0銆�
3. 2mol 鍠師瀛愮悊鎯虫埃楂斿鎱�(t脿i)鐐� 298K锛�3039.75kPa锛岀稉绲曠啽鑶ㄨ劰澹撳姏绐佺劧闄嶅埌 1013.25kPa锛�
鍋氫簡 2095 J 鐨勫姛锛屾眰瑭查珨绯荤殑鐔佃畩鍊�銆�
绛旓細鍥犵偤鏄禃鐔遍亷绋�锛屾墍浠� Q=0锛屾墍浠ユ湁锛�
20952983148
2
3
2 212 ??????????? )(.)(, TTTCnUW mv 銆傛眰瑙ｅ緱鍒� T2=214K銆�
KJ
p
p
nR
T
T
CnS mp ?????????? ?!
, .
.
.
ln.ln.lnln 504
251013
753039
31482
298
214
3148
2
5
2
2
1
1
2
4. 宸茬煡 101.325kPa 涓�锛屽弽鎳� FeCO3(s)=FeO(s)+CO2(g)鐨�
)(..ln. JTTTTG
o
mr
23
105344251962678073 ?????? 銆�
瑭﹁▓绠� 25鈩冩檪鐨� H
o
mr? 鍜� S
o
mr? 銆�
绛旓細鍥犵偤 S
T
G o
mr
o
m
p
?????
?
?
??
?
?
?
??
锛屾墍浠ユ湁锛�
TT
T
G
S
o
m
p
o
mr 10694251962619626 3?
???????
?
?
??
?
?
?
??
??? .ln.. =180.28J?mol
-1
銆�
灏囨韩搴� 298K 浠ｅ叆 G
o
mr? 琛ㄩ仈寮�锛屽嵆鍙眰寰� G
o
mr? =29.093kJ
kJSTGH
o
mr
o
mr
o
mr 848200102818029809329 .... ??????????
5锛庨€氬父鍦ㄥぇ姘ｅ鍔涚偤 101.325kPa 鏅�锛屾按鐨勬哺榛炵偤 373K锛岃€屽湪娴锋嫈寰堥珮鐨勯珮鍘熶笂锛岀暥澶ф埃
澹撳姏闄嶇偤 66.9kPa 鏅傦紝閫欐檪姘寸殑娌搁粸鐐哄灏�锛熷凡鐭ユ按鐨勬婧栨懇鐖炬苯鍖栫啽鐐� 40.67kJ?mol
-1
锛屽苟
瑷叾鑸囨韩搴︾劇闂溿€傜敱瑷堢畻绲愭灉鍥炵瓟:鐐轰粈涔堢敤楂樺閸嬬叜椋熺墿瀹规槗鐔熼€�?
绛旓細鏍规摎鍏嬪嫗淇柉-鍏嬫媺浣╅緧鏂圭▼: ??
?
?
??
?
?
?
?
?
TTR
H
p
p
o
mvap
211
2 11
ln , 浠ｅ叆鏈夐棞鏁告摎,鍙緱:
??
?
?
??
?
?
??
T 2
1
373
1
3148
40670
325101
966
..
.
ln
瑙ｆ柟绋嬪緱 T2=361.6K銆�
鐢辫▓绠楃祼鏋滃彲鐭ワ紝澶栧瓒婂ぇ锛屾按鐨勬哺榛炶秺楂�銆傜暥椋熺墿缃簬楂樺閸嬮噷鏅�锛岀敱浜庡鍔涜純楂�锛屾墍浠�
姘寸殑娌搁粸涔熼珮锛岄€欐ǎ鐛插緱鐨勯珮婧娇椋熺墿鏄撲簬鐔熼€�锛屽悓鏅備篃绡€(ji茅)绱勬檪闁�銆�
6锛庡弽鎳� 2NaHCO3(s)=Na2CO3(s)+H2O(g)+CO2(g)銆傚凡鐭ョ暥 p 鐨勫柈浣嶇偤 kPa 鏅�锛屽垎瑙ｅ鍔涜垏婧�
搴︾殑闂滅郴鐐猴細
9510
3345
.)/lg( ???
T
Pap
銆傛眰锛�
(1)妯欐簴骞宠 甯告暩 K
o
p
鑸� T 鐨勯棞绯�锛�(2)鍙嶆噳鐨� Hr
o
m? 鍜� Sr
o
m? 銆�
绛旓細(1)鍒嗚В澹撳姏鏄寚鍥虹浉鍒嗚В鍙嶆噳鍦ㄦ煇涓€婧害涓嬮仈骞宠 鏅�,姘ｇ浉鐢㈢墿鐨勭附澹撳姏:
p 绺�=p(H2O,g)+ p(CO2,g)
鍥犵偤 p(H2O,g)= p(CO2,g)=p 绺�/2
鎵€浠� ?
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p
p
p
p
p
p
K oo
CO
o
OHo
p
2
2
22
,鍏╅倞鍙栧父鐢ㄥ皪鏁�,寰楀埌:
)lg(lg)lg(lglg 100222222 ????? pppK
oo
p
鍐嶅皣 9510
3345
.)/lg( ???
T
Pap 浠ｅ叆涓婂紡,鍗冲緱
3017
6690
100229510
3345
2 .)lg().(lg ????????
TT
K
o
p
(2)鏍规摎涓婅堪鍖栧鍙嶆噳鐨勫钩琛″父鏁歌垏婧害闂滅郴鐨勪笉瀹氱⿳鍒嗗舰寮�(鐗瑰垾娉ㄦ剰:閫欏€嬭〃閬斿紡鐢ㄧ殑
鏄父鐢ㄥ皪鏁�),鍙煡:
m o lkJH
o
mr
1
1128669031483032 ?
??????? ...
m o lKJS
o
mr
11
333131731483032 ??
???????? ....
7锛庢埃鐩稿弽鎳� N2O5(g)鈫�2NO2(g)+1/2O2(g)锛屽湪 67鈩冩脯寰椾互涓� N2O5(g)婵冨害闅ㄥ弽鎳夋檪闁撹畩鍖栫殑
鏁告摎濡備笅銆傝│姹傚弽鎳夌礆鏁�銆侀€熺巼甯告暩鍜屽崐琛版湡銆�
t/min 0 1.0 2.0 3.0 4.0 5.0
[N2O5]/(mol路dm
-3
) 1.000 0.705 0.497 0.349 0.246 0.173
绛旓細鏈鍙互閫氶亷绌嶅垎娉曟眰瑙�銆傚厛瑷┎鍙嶆噳鐐轰竴绱氬弽鎳�锛屽埄鐢ㄤ竴绱氬弽鎳夊嫊鍔涘绌嶅垎鍏紡锛�
c
c
t
k
01
ln? 銆傞€愬€嬩唬鍏ュ椹楁暩鎿�锛岃▓绠楀緱鍒伴€熺巼甯告暩濡備笅琛�銆傜敱浜庨€熺巼甯告暩鍧囩偤瀹氬€硷紝鎵€
浠ヨ┎鍙嶆噳鐐轰竴绱氬弽鎳�銆�
t/min 0 1.0 2.0 3.0 4.0 5.0
[N2O5]/(mol?dm
-3
) 1.000 0.705 0.497 0.349 0.246 0.173
k/min
-1
* 0.35 0.35 0.35 0.35 0.35
鐢辫〃涓€熺巼甯告暩鐨勬暩鎿氾紝鏍规摎 min./.
ln
/ 23506930
2
21 ?? 寰楀弽鎳夊崐琛版湡鐐�
k
t 銆�
8. 鍦� 5.0?10
-2
kg CCl4(A)涓憾鍏� 5.126?10
-4
kg 钀�(B)(MB=0.12816kg?mol
-1
)锛屾脯寰楁憾娑茬殑娌搁粸
杓冪磾婧跺姂鍗囬珮 0.402 K銆傝嫢鍦ㄥ悓閲忕殑婧跺姂 CCl4 涓憾鍏� 6.216?10
-4
kg 鐨勬湭鐭ョ墿锛屾脯寰楁哺榛炲崌楂�
绱� 0.647 K銆傛眰瑭叉湭鐭ョ墿鐨勬懇鐖捐唱閲�銆�
绛旓細鏍规摎
m
MBm
k
m
n
kmkT
A
B
b
A
B
bBbb
/)(
???? 锛屼唬鍏ユ暩鎿氬悗寰楀埌
100.5
12816.0/10126.5
402.0 2
4
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?
k b
100.5
/10216.6
647.0 2
4
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?
M
k
B
b
鍏╁紡鐩搁櫎鍗冲彲娑堝幓 kb锛岀敱姝ゅ緱鍒� MB=9.66?10
-2
kg?mol
-1
(鎴� MB=96.6g?mol
-1
)
9. 鍦ㄦ埃鐩镐腑锛岀暟涓欑儻鍩洪啔(A)鐣版鍖栫偤涓欑儻鍩轰笝閰�(B)鐨勫弽鎳夋槸涓€绱氬弽鎳�锛屽叾閫熺巼甯告暩鑸囨韩搴�
鐨勯棞绯荤偤锛�
? ? 0227
147341
.
/
/ln ????
KT
sk
銆�
(1)姹傚弽鎳夌殑娲诲寲鑳� Ea 鍙婃寚鍓嶅洜瀛� A銆�
(2)瑕佷娇鍙嶆噳鐗╁湪 20min 鍏ц綁鍖栫巼閬� 60%锛屽弽鎳夌殑婧害鎳夋帶鍒跺湪澶氬皯搴�锛�
绛旓細(1)灏囪┎鍙嶆噳閫熺巼甯告暩鑸囨韩搴︾殑闂滅郴鑸囬樋绱凹鐑忔柉鍏紡閫茶灏嶇収,绲愭灉鍙緱锛�
molkJE a ???? ?
5122314814734 1
.. 锛� sA 111
104350227 ?
??? .).exp(
(2)瑷湪婧害 T 鏅�锛� st 12006020 ??? 锛岃綁鍖栫巼 600.?? 銆備唬鍏ヤ竴绱氬弽鎳夊嫊鍔涘绌嶅垎鍏紡锛�
鍙緱鍒帮細
s
t
kT
14
1067
601
1
1200
1
1
11 ??
??
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? .
.
lnln
灏� kT 鍊间唬鍏ラ涓叕寮�,绲愭灉鏈�: 0227
14734
1067
4
.).(ln ????
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T
瑙ｅ緱 T=431K
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