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Ziegler-Natta 寮曠櫦(f膩)楂旂郴鐨勭祫鎴�锛涗笝鐑殑閰嶄綅鑱氬悎姗�(j墨)鐞嗗強瀹氬悜姗�(j墨)鐞�
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鍩烘湰瑕佹眰锛氭帉鎻¤仛鍚堢墿鍖栧(xu茅)鍙嶆噳(y墨ng)鐨勭壒寰侊紱鎺屾彙甯歌(ji脿n)鑱氬悎鐗╃殑鍩哄湗(tu谩n)鍙嶆噳(y墨ng)锛涙帉鎻�
鑱氬悎鐗╃殑鐩镐技杞�(zhu菐n)璁�銆佹帴鏋濄€佹摯(ku貌)閺�銆佷氦鑱�(li谩n)鍙嶆噳(y墨ng)鍘熺悊锛涙帉鎻￠珮鍒嗗瓙鐨勯檷瑙ｈ垏鑰佸寲锛涚悊
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4
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鏈璺濈殑瑷�(j矛)绠�銆�
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妲�(g貌u)锛岃仛鍚堢墿鐨勭祼(ji茅)鏅跺舰鎱�(t脿i)銆佹櫠鎱�(t脿i)楂樿仛鐗╃殑绲�(ji茅)妲�(g貌u)妯″瀷锛涚悊瑙ｉ潪鏅舵厠(t脿i)鍜屾恫鏅舵厠(t脿i)楂樿仛鐗╃殑
绲�(ji茅)妲�(g貌u)銆傛帉鎻￠珮鍒嗗瓙鍚堥噾鐩稿鎬�銆佸舰鎱�(t脿i)鍜屾€ц兘涔嬮枔鐨勯棞(gu膩n)绯�銆�
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鏅跺害鐨勬蹇�銆佹脯(c猫)瀹氭柟娉曞拰瑷�(j矛)绠楁柟娉�锛涘彇鍚戝拰瑙ｅ彇鍚戠殑姒傚康銆佹(j墨)鐞嗕互鍙婂彇鍚�?q奴)惟鍛�?br/>鐗╂€ц兘鐨勫奖闊裤€�
绗崄绔� 楂樺垎瀛愭憾娑�
鍩烘湰瑕佹眰锛氶珮鍒嗗瓙婧舵恫銆佹憾搴﹀弮鏁�(sh霉)鐨勫熀鏈蹇�锛屾眰鍙栭珮鑱氱墿婧跺害鍙冩暩(sh霉)鐨勫(sh铆)椹�(y脿n)
鏂规硶鍜岃▓(j矛)绠楁柟娉�锛涗笉鍚岀殑绶氬舰楂樿仛鐗╋紙绲�(ji茅)鏅�銆侀潪鏅�銆佹サ鎬�銆侀潪妤垫€э級鐨勬憾瑙ｇ壒鎬�
鍜屼氦鑱�(li谩n)楂樿仛鐗╃殑婧惰劰锛涢珮鍒嗗瓙绋€婧舵恫鐨� Huggins 鍙冩暩(sh霉)銆佹贩鍚堢啽銆佹贩鍚堢喌銆佹贩鍚堣嚜
鐢辫兘鍜屽寲瀛�(xu茅)浣嶈〃閬�(d谩)寮�銆傛帉鎻¤秴椤嶅寲瀛�(xu茅)浣�銆佄� 婧跺姂銆佄� 婧舵恫銆佹徊閫忓鐨勬蹇靛拰楂樺垎
瀛愭績婧舵恫銆佸嚌鑶犲拰鍑嶈啝绛夊熀鏈蹇点€�
閲嶉粸(di菐n)锛氶珮鍒嗗瓙婧舵恫銆佹憾搴﹀弮鏁�(sh霉)鐨勫熀鏈蹇�锛涗笉鍚岀殑绶氬舰楂樿仛鐗╋紙绲�(ji茅)鏅躲€侀潪鏅�銆�
妤垫€�銆侀潪妤垫€э級鐨勬憾瑙ｇ壒鎬у拰浜よ伅(li谩n)楂樿仛鐗╃殑婧惰劰锛涢珮鍒嗗瓙绋€婧舵恫鐨� Huggins 鍙冩暩(sh霉)銆�
娣峰悎鐔便€佹贩鍚堢喌銆佹贩鍚堣嚜鐢辫兘鍜屽寲瀛�(xu茅)浣嶈〃閬�(d谩)寮�銆�
绗崄涓€绔� 鑱氬悎鐗╃殑鍒嗗瓙閲忓拰鍒嗗瓙閲忓垎甯�
5
鍩烘湰瑕佹眰锛氫笉鍚屽垎瀛愰噺鍜屽垎瀛愰噺鍒嗗竷瀵害鐨勮〃绀烘柟娉�锛屼簡瑙ｅ垎瀛愰噺鐨勫井鍒嗗垎
甯冩洸绶氬拰绌嶅垎鍒嗗竷鏇茬窔銆傛帉鎻＄鍩哄垎鏋愭硶銆佹哺榛�(di菐n)涓婂崌娉曘€佸啺榛�(di菐n)闄嶄綆娉�銆佽捀姘ｅ涓�
闄嶆硶銆佽啘婊查€忓娉�銆佺矘搴︽硶鍜屽嚌鑶犳徊閫忚壊璀滄硶锛圙PC锛夋脯(c猫)瀹氳仛鍚堢墿鍒嗗瓙閲忕殑鍘熺悊
鍜屾柟娉曘€傛帉鎻� Mark-Houwink 鏂圭▼銆丟PC 鏂规硶涓殑鏅仼鏍℃鏇茬窔銆佹牎姝ｆ洸绶氫互鍙�
绗簩缍埄绯绘暩(sh霉)绛夊収(n猫i)瀹�銆�
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鍘熺悊鍜屽(sh铆)椹�(y脿n)鏂规硶銆傛帉鎻� Mark-Houwink 鏂圭▼銆丟PC 鏂规硶涓殑鏅仼鏍℃鏇茬窔銆�
绗崄浜岀珷 鑱氬悎鐗╃殑杞�(zhu菐n)璁婅垏鏉惧紱
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瑕佹眰鎺屾彙闈炴櫠鍏遍珮鑱氱墿銆佺祼(ji茅)鏅堕珮鑱氱墿鐨勬韩搴�-褰㈣畩鏇茬窔浠ュ強鍒嗗瓙閲忓皪(du矛)婧害-褰㈣畩鏇�
绶氱殑褰遍熆锛汿g 鐨勫奖闊垮洜绱�銆乀g 鐨勬脯(c猫)瀹�銆乀g 杞�(zhu菐n)璁婄殑鑷敱楂旂⿳鐞嗚珫锛涜仛鍚堢墿绲�(ji茅)鏅惰兘
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璁婄殑姒傚康銆�
閲嶉粸(di菐n)锛氶潪鏅堕珮鑱氱墿銆佺祼(ji茅)鏅堕珮鑱氱墿鐨勬韩搴�-褰㈣畩鏇茬窔浠ュ強鍒嗗瓙閲忓皪(du矛)婧害-褰㈣畩鏇�
绶氱殑褰遍熆锛涚悊瑙ｉ珮鍒嗗瓙閬�(y霉n)鍕�(d貌ng)鍠厓鐨勫閲嶆€�銆佸垎瀛愰亱(y霉n)鍕�(d貌ng)鐨勬檪(sh铆)闁撲緷璩存€у拰婧害渚濊炒鎬�
鐨勫奖闊垮洜绱�銆俆g 鐨勫奖闊垮洜绱�銆乀g 鐨勬脯(c猫)瀹氥€乀g 杞�(zhu菐n)璁婄殑鑷敱楂旂⿳鐞嗚珫锛涜仛鍚堢墿绲�(ji茅)鏅�
鑳藉姏鑸囩祼(ji茅)妲�(g貌u)鐨勯棞(gu膩n)绯�銆傜啍榛�(di菐n)鐨勬蹇点€佷互鍙婂奖闊胯仛鍚堢墿 Tm 鐨勫洜绱�銆�
绗崄涓夌珷 姗¤啝褰堟€�
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姘忔ā閲忋€佸垏璁婃ā閲忕殑姒傚康銆傞噸榛�(di菐n)鎺屾彙姗¤啝褰堟€х殑鐔卞姏瀛�(xu茅)鍒嗘瀽銆佷氦鑱�(li谩n)姗¤啝鐙€鎱�(t脿i)鏂圭▼銆�
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閲嶉粸(di菐n)锛氭鑶犲綀鎬х殑鐔卞姏瀛�(xu茅)鍒嗘瀽銆佷氦鑱�(li谩n)姗¤啝鐙€鎱�(t脿i)鏂圭▼銆傚祵娈靛叡鑱氱啽濉戞€у綀鎬ч珨
鐨勭祼(ji茅)妲�(g貌u)銆佷娇鐢ㄧ殑涓婁笅闄愭韩搴�銆�
绗崄鍥涚珷 鑱氬悎鐗╃殑绮樺綀鎬�
鍩烘湰瑕佹眰锛氳爼璁�銆佹噳(y墨ng)鍔涙澗寮�銆佹化鍚庡拰鍏�(n猫i)鑰楃殑鍩烘湰姒傚康锛岀窔鎬у拰鐞嗘兂浜よ伅(li谩n)楂樿仛
6
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绶氾紱鑱氬悎鐗╃祼(ji茅)妲�(g貌u)鑸囧収(n猫i)鑰椾箣闁撶殑闂�(gu膩n)绯�锛汢oltzmann 鐤婂姞鍘熺悊銆佹檪(sh铆)婧瓑鏁堝師鐞嗭紱鏈�(hu矛)鐢�
WLF 鏂圭▼閫�(j矛n)琛岃▓(j矛)绠�銆備簡瑙ｆ弿杩扮矘褰堟€х殑鍔涘(xu茅)妯″瀷銆傛帉鎻＄矘褰堟€х殑鐮旂┒鏂规硶鍜屽嫊(d貌ng)
鎱�(t脿i)鍔涘(xu茅)璀滅爺绌惰仛鍚堢墿鐨勭祼(ji茅)妲�(g貌u)鍜屽垎瀛愰亱(y霉n)鍕�(d貌ng)銆�
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锠曡畩鍜屽洖寰�(f霉)鏇茬窔锛涚窔鎬у拰浜よ伅(li谩n)楂樿仛鐗╃殑鎳�(y墨ng)鍔涙澗寮涙洸绶�锛岃仛鍚堢墿鍏�(n猫i)鑰�-婧害鏇茬窔锛�
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鎮ㄧ従(xi脿n)鍦ㄧ殑浣嶇疆锛� 
