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鐒℃鍖栧(xu茅)鍩烘湰鍘熺悊锛岃敗灏戣彲銆侀緮瀛熸總銆佸彶鑿磪 绶ㄨ憲锛屼腑灞卞ぇ瀛�(xu茅)鍑虹増绀撅紝2001 骞寸増
鍏冪礌?z茅)o姗熷寲瀛�(xu茅)锛岃敗灏戣彲銆侀粌鍧よ€€銆佸嫉鐜夊 绶ㄨ憲锛屼腑灞卞ぇ瀛�(xu茅)鍑虹増绀�锛�2003 骞寸増
鍥涖€佹ǎ鍗�
涓€銆侀伕鎿囬锛堝叡 20 灏忛锛屾瘡灏忛 2 鍒嗭紝鍏� 40 鍒嗭級
1锛庝笅鍒楀垎瀛愭垨闆㈠瓙鑸� BF3 浜掔偤绛夐浕瀛愰珨锛屽苟鍏锋湁鐩镐技绲�(ji茅)妲�(g貌u)鐨勪竴绋槸锛� 锛�
A锛嶯O3
-
B锛嶯F3 C锛庢埃鎱�(t脿i) AlCl3 D锛嶴O2
绗� 5 闋侊紝鍏� 8 闋�
2锛嶢 鑸� B 鐧�(f膩)鐢熷弽鎳�(y墨ng)锛岀暥(d膩ng) A 婵冨害鐐哄師渚� 2 鍊嶆檪锛屽弽鎳�(y墨ng)閫熷害澧炲姞鐐� 4 鍊�锛岀暥(d膩ng) B 婵冨害澧炲姞鐐哄師渚�
2 鍊嶆檪锛屽弽鎳�(y墨ng)閫熷害澧炲姞鐐� 2 鍊�锛屾鍙嶆噳(y墨ng)鐨勫弽鎳�(y墨ng)绱氭暩(sh霉)鐐猴紙 锛�
A锛�1 绱� B锛�2 绱� C锛�3 绱� D锛�4 绱�
3锛庢湁鍏╁€嬪钩琛屽弽鎳�(y墨ng) A 鈫� B 鍜� A 鈫� C锛屽鏋滆鎻愰珮 B 鐨勭敘(ch菐n)鐜�锛岄檷浣� C 鐨勭敘(ch菐n)鐜�锛屾渶濂界殑杈︽硶
鏄紙 锛�
A锛庡鍔� A 鐨勬績搴� B锛庡鍔� C 鐨勬績搴�
C锛庢帶鍒跺弽鎳�(y墨ng)婧害 D锛庨伕鎿囨煇绋偓鍖栧姂
4锛庢渶杩戞剰澶у埄绉戝(xu茅)瀹剁敤鏅€氱殑姘у垎瀛愬拰甯舵闆昏嵎鐨勬哀闆㈠瓙鍒堕€犲嚭浜嗙敱 4 鍊嬫哀鍘熷瓙妲�(g貌u)鎴愮殑姘у垎
瀛愶紝骞剁敤璩�(zh矛)璀滃剙鎺㈡脯鍒颁簡瀹冨瓨鍦ㄧ殑璀夋摎(j霉)銆傝嫢瑭叉哀鍒嗗瓙鍏锋湁绌洪枔灏嶇ū绲�(ji茅)妲�(g貌u)锛屼笅鍒楅棞(gu膩n)浜庤┎姘у垎瀛�
鐨勮娉曟纰虹殑鏄紙 锛�
A锛庢槸涓€绋柊鐨勬哀鍖栫墿
B锛庢槸涓€绋潪妤垫€у垎瀛�
C锛庢槸姘у厓绱犵殑涓€绋悓浣嶇礌
D锛庢槸鑷哀鐨勫悓鍒嗙暟妲�(g貌u)楂�
5锛庝笅鍒楀悇绲勭墿璩�(zh矛)姹藉寲鎴栫啍鍖栨檪锛屾墍鍏嬫湇鐨勭矑瀛愰枔鐨勪綔鐢ㄥ姏灞簬鍚岀ó椤炲瀷鐨勬槸锛� 锛�
A锛庝簩姘у寲纭呰垏鐢熺煶鐏扮殑鐔斿寲
B锛庢隘鍖栭垑鑸囬惖鐨勭啍鍖�
C锛庣鑸囧共鍐扮殑鍗囪彲
D锛庢隘鍖栭姩鑸囪嫰鐨勬苯鍖�
6锛庝笅鍒楁湁闂�(gu膩n) pH 璁婂寲鐨勫垽鏂蜂腑锛屾纰虹殑鏄紙 锛�
A锛庨毃钁楁韩搴︾殑鍗囬珮锛岀⒊閰搁垑婧舵恫鐨� pH 娓涘皬
B锛庨毃钁楁韩搴︾殑鍗囬珮锛岀磾姘寸殑 pH 澧炲ぇ
C锛庢柊鍒舵隘姘寸稉(j墨ng)鍏夌収涓€娈垫檪闁撳悗锛宲H 娓涘皬
D锛庢矮姘у寲閳夋憾娑蹭箙缃簬绌烘埃涓�锛宲H 澧炲ぇ
7锛庣浉鍚岄珨绌嶇殑 pH=3 鐨勫挤閰告憾娑插拰寮遍吀婧舵恫鍒嗗垾璺熻冻閲忕殑閹傚畬鍏ㄥ弽鎳�(y墨ng)锛屼笅鍒楄娉曟纰虹殑鏄�
锛� 锛�
A锛庡急閰告憾娑茬敘(ch菐n)鐢熻純澶氱殑姘埃 B锛庡挤閰告憾娑茬敘(ch菐n)鐢熻純澶氱殑姘埃
C锛庡叐鑰呯敘(ch菐n)鐢熺瓑閲忕殑姘埃 D锛庣劇娉曟瘮杓冨叐鑰呯敘(ch菐n)鐢熸矮姘ｇ殑閲�
8锛巔H=伪 鐨勬煇闆昏В璩�(zh矛)婧舵恫涓�锛屾彃鍏ュ叐鏀儼鎬ч浕妤甸€氱洿娴侀浕涓€娈垫檪闁撳悗锛屾憾娑茬殑 pH锛炍� 锛屽墖
瑭查浕瑙ｈ唱(zh矛)鍙兘鏄紙 锛�
A锛嶯aOH B锛嶩2SO4 C锛嶢gNO3 D锛嶯a2SO4
9锛庝笅鍒楁弿杩颁腑锛屼笉绗﹀悎鐢熺敘(ch菐n)瀵﹂殯鐨勬槸锛� 锛�
A锛庨浕瑙ｇ啍铻嶇殑姘у寲閶佸埗鍙栭噾灞媮锛岀敤閻典綔闄芥サ
B锛庨浕瑙ｆ硶绮剧厜绮楅妳锛岀敤绱旈妳浣滈櫚妤�
C锛庨浕瑙ｉ＝鍜岄楣芥按鍒剁噿鍫�锛岀敤娑傞幊纰抽嫾缍�(w菐ng)浣滈櫚妤�
D锛庡湪閸嶄欢涓婇浕閸嶉媴锛岀敤閶呬綔闄芥サ
10锛庤兘浣垮弽鎳�(y墨ng) Cu + 2H2O == Cu(OH)2 + H2鈫戠櫦(f膩)鐢熺殑鏄紙 锛�
A锛庨妳鐗囦綔鍘熼浕姹犵殑璨犳サ锛岀偔妫掍綔鍘熼浕姹犵殑姝ｆサ锛屾隘鍖栭妳浣滈浕瑙ｈ唱(zh矛)婧舵恫
B锛庨妳閶呭悎閲戝湪娼繒绌烘埃鐧�(f膩)鐢熼浕鍖栧(xu茅)鑵愯潟
C锛庣敤閵呯墖浣滈櫚銆侀櫧闆绘サ锛岄浕瑙ｇ～閰搁垑婧舵恫
D锛庣敤閵呯墖浣滈櫚銆侀櫧闆绘サ锛岄浕瑙ｇ～閰搁妳婧舵恫
绗� 6 闋�锛屽叡 8 闋�
11锛庨棞(gu膩n)浜庣７鐨勪笅鍒楁晿杩颁腑锛屾纰虹殑鏄紙 锛�
A锛庣磪纾疯垏鐧界７鍧囩偤鍘熷瓙鏅堕珨
B锛庣櫧纾峰湪绌烘埃涓姞鐔辫嚦 260
o
C 鍙綁(zhu菐n)璁�?y艒u)姒纾�
C锛庣磪纾峰彲鐢ㄤ簬鍒堕€犲畨鍏ㄧ伀鏌�
D锛庡皯閲忕櫧纾锋噳(y墨ng)淇濆瓨鍦ㄤ簩纭寲纰抽噷
12锛庢垜鍦嬧€滅宸� 6 铏熲€濊級浜鸿埅澶╅鑸圭殑鎴愬姛鐧�(f膩)灏�锛岃〃鏄庢垜鍦嬭級浜鸿埅澶╂妧琛�(sh霉)宸蹭綅浜庝笘鐣屽墠鍒椼€�
鍦ㄦ煇浜涢亱杓夐鑸圭殑鐏鎺ㄩ€插櫒涓洓鏈夐倓鍘熷姂娑叉厠(t脿i)鑲硷紙N2 H4锛夊拰姘у寲鍔戞恫鎱�(t脿i)闆欐哀姘�锛屽畠鍊戝厖鍒�
娣峰悎鍙嶆噳(y墨ng)鍚庣殑鐢�(ch菐n)鐗╀箣涓€鏄紙 锛�
A锛庢哀姘� B锛庢矮姘� C锛庢皑姘� D锛庢爱姘�
13锛庡鏋滅敤鎺掓按娉曟敹闆嗘績纭濋吀鍙楃啽鍒嗚В鎵€鐢�(ch菐n)鐢熺殑姘ｉ珨锛屽墖锛� 锛�
A锛庢敹闆嗗埌 NO B锛庢敹闆嗗埌 NO2
C锛庢敹闆嗗埌 O2 D锛庢敹闆嗕笉鍒颁换浣曟埃楂�
14锛庝笅鍒楅棞(gu膩n)浜庣磾閻电殑鎻忚堪姝ｇ⒑鐨勬槸锛� 锛�
A锛庣啍榛炴瘮鐢熼惖浣�
B锛庤垏鐩稿悓婵冨害鐨勯菇閰稿弽鎳�(y墨ng)鐢熸垚姘埃鐨勯€熺巼姣旂敓閻靛揩
C锛庡湪娼繒鐨勭┖姘ｄ腑姣旂敓閻靛鏄撹鑵愯潟
D锛庡湪鍐风殑婵冪～閰镐腑鍙垗鍖�
15锛庡皣琛ㄩ潰宸插畬鍏ㄩ垗鍖栫殑閶佹锛屾彃鍏ヤ笅鍒楁憾娑蹭腑锛屼笉鏈冪櫦(f膩)鐢熷弽鎳�(y墨ng)鐨勬槸锛� 锛�
A锛庣█纭濋吀 B锛庣█楣介吀 C锛庣閰搁妳 D锛庢矮姘у寲閳�
16锛庝笅鍒楀悇绲勯噺瀛愭暩(sh霉)涓�锛岄偅涓€绲勭殑闆诲瓙鎵€铏曠殑鑳界礆鏈€楂� 锛� 锛夛紵
锛圓锛塶 =3锛宭=1锛宮=0锛宮s=1/2. 锛圔锛塶=4锛宭=2锛宮=-2锛宮s=1/2
锛圕锛塶=4锛宭=0锛宮=0锛宮s=-1/2 锛圖锛塶=3锛宭=2锛宮=-1锛宮s=-1/2
17锛庢煇鍖栧悎鐗� A 鐨勬按鍚堟櫠楂� A路3H2O锛坰锛夌殑鑴按閬庣▼鐐猴紙 锛�
鈶� A路3H2O锛坰锛� A路2H2O锛坰锛�+ H2O锛坓锛� K1
0
鈶� A路H2O锛坰锛�+ H2O锛坓锛� A路2H2O锛坰锛� K2
0
鈶� A路H2O锛坰锛� A锛坰锛�+ H2O锛坓锛� K3
0
鐐轰簡浣� A路2H2O锛坰锛変繚鎸佺┅(w臎n)瀹�锛岋紙鏃笉鐧�(f膩)鐢熼ⅷ(f膿ng)鍖�锛屼篃涓嶇櫦(f膩)鐢熸疆瑙ｏ級锛屽墖瀹瑰櫒涓�
H2O 鐨勮捀姹藉鑸囧钩琛″父鏁�(sh霉)鐨勯棞(gu膩n)绯绘噳(y墨ng)婊胯冻 锛� 锛�
锛圓锛�1/K2
0
銆塸 (H2O) / p
0
銆塊3
0
锛圔锛塊1
0
銆塸(H2O) / p
0
銆�/1K2
0
锛圕锛塸(H2O) / p
0
銆塊1
0
锛圖锛塸(H2O) / p
0
銆�1/K2
0
18锛庨懎绯绘敹绺殑鍚庢灉涔嬩竴鏄娇涓嬪垪鍝祫鍏冪礌鐨勬€ц唱(zh矛)鏇寸浉浼� 锛� 锛�
A锛嶮n 鍜� Tc B锛嶯b 鍜� Ta C锛嶴c 鍜� La D锛嶳u銆丷h銆丳d
19锛嶮nO4
-
(aq) 鍛堢传绱呰壊锛屽叾灞簬 锛� 锛�
A锛巇-d 鍏夎瓬 B锛巉-f 鍏夎瓬 C锛庤嵎绉诲厜璀� D锛庢媺鏇煎厜璀�
20锛庡湪鏅澹棈 KFe[Fe(CN3)6] 涓�锛孎(xi脿n)e
2+
鍜� Fe
3+
鐨勯厤浣嶆柟寮忔槸 锛� 锛�
A锛嶤N
-
涓殑 C 鍘熷瓙鍜� N 鍘熷瓙鍒嗗垾鑸� Fe
2+
鍜� Fe
3+
褰㈡垚閰嶄綅閸�锛�
B锛嶤N
-
涓殑 C 鍘熷瓙鍜� N 鍘熷瓙鍒嗗垾鑸� Fe
3+
鍜� Fe
2+
褰㈡垚閰嶄綅閸�锛�
C锛嶤N
-
涓殑 C 鍘熷瓙鍜� N 鍘熷瓙鍧囪垏 Fe
2+
閰嶄綅閸�锛�
D锛嶤N
-
涓殑 C 鍘熷瓙鍜� N 鍘熷瓙鍧囪垏 Fe
3+
閰嶄綅閸�銆�
浜屻€侀伕鎿囬锛堝叡 20 灏忛锛屾瘡灏� 1 鍒�锛屽叡 20 鍒嗭級
1. 鐩稿悓璩�(zh矛)閲忔懇鐖炬績搴﹀拰鐩稿悓楂旂⿳鐨� K3PO4锛孋6 H12O6(钁¤悇绯�)锛孠H2PO4 鍜� K2 HPO4 绋€婧舵恫
绗� 7 闋�锛屽叡 8 闋�
锛圚3PO4 鏄急闆昏В璩�(zh矛)锛�锛屽叾鍑濆浐榛炵敱浣庡埌楂樼殑闋嗗簭鏄紙1锛夈€�
2. 绗﹁櫉 d 琛ㄧず鐨勯浕瀛愪簽灞や腑鏈夛紙2锛夊€嬬啊骞惰粚閬�銆�
3. 鍦ㄥ師瀛愮殑杩戜技鑳界礆鍦栦腑锛�6s銆� 4f 鏄敱浜庯紙3锛変箣鏁�銆�
4. AB 鍨嬮洟瀛愬寲鍚堢墿涓洟瀛愬崐寰戞瘮 r+/r-澶т簬 0.732锛屽墖瑭插寲鍚堢墿灞簬锛�4锛夊瀷闆㈠瓙鏅堕珨銆�
5. 鍦ㄧ浉鍚屾浠朵笅锛孲O2(g)鍜� H2S(g) 鐩告瘮锛屾摯鏁ｉ€熷害鎱㈢殑鏄紙5锛夈€�
6. NH4
+
鐨勪腑蹇冨師瀛� N 鐨勫児杌岄亾浠ワ紙6锛夐洔鍖栨柟寮忔垚閸�銆�
7. 涓€灏侀枆楂旂郴鍦ㄦ煇閬庣▼涓悜鐠�(hu谩n)澧冩斁鍑轰簡 50 kJ 鐨勭啽閲忥紝寰炵挵(hu谩n)澧冨緱鍒颁簡 20 kJ 鐨勫姛锛屽墖
楂旂郴鍦ㄨ┎閬庣▼涓殑鐔卞姏瀛�(xu茅)鑳借畩鍖栫偤锛�7锛�銆�
8. 鍦� Co锛堚參锛夌殑閰嶅悎鐗╀腑锛岃嫢涓績闆㈠瓙 Co
3+
锛坉 杌岄亾锛夌殑闆诲瓙鍒嗚鑳藉ぇ浜庢垚灏嶈兘锛屽墖鍏� d 杌�
閬撶殑闆诲瓙閲囩敤锛�8锛夎嚜鏃嬬殑鎺掑竷鏂瑰紡銆�
9. 灏嶇鍩鸿嫰鑳虹殑娌搁粸姣旈劙纭濆熀鑻兒鐨勶紙9锛夛紙浣庢垨楂橈級銆�
10. 浜屽厓寮遍吀鐨勯吀鏍规績搴﹁繎浼肩瓑浜庯紙10锛�銆�
11. 鍋囧畾 CO + H2O CO2 + H2 鏄熀鍏冨弽鎳�(y墨ng)锛屽墖瑭插弽鎳�(y墨ng)鐨勭礆鏁�(sh霉)鐐猴紙11锛夈€�
12. 涓€绱氬弽鎳�(y墨ng)鐨勫崐琛版湡 t1/2 鑸囧弽鎳�(y墨ng)鐗╃殑鍘熷婵冨害锛�12锛�銆�
13锛嶺eF6 鐨勭祼(ji茅)妲�(g貌u)鏄紙13锛�锛�
14锛庡湪 O2銆丱2
+
銆丱2
-
銆丱2
2-
銆佷腑锛屾哀鍖栨€ф渶寮风殑鏄紙14锛�锛�
15. 鏈€纭殑鍠唱(zh矛)鏄紙15锛�銆�
16锛嶩3PO3 鏄紙16锛夊厓閰革紱
17锛庣〖鐮傜殑姘存憾娑插叿鏈夌珐娌栦綔鐢�锛屾槸鍥犵偤鐢�(ch菐n)鐢熺墿璩�(zh矛)鐨勯噺鐩哥瓑鐨� H3 BO3 鍜岋紙17锛�锛�
18锛嶯a2HPO4 姘存憾娑插憟锛�18锛夋€�锛�
19锛庣⒊閰告矮閳夌殑鐔辩┅(w臎n)瀹氭€у皬浜庣⒊閰搁垑锛屾槸鍥犵偤 H
+
鐨勬サ鍖栦綔鐢ㄦ瘮 Na
+
鐨勶紙19锛�锛�
20锛庝箼纭肩兎鏄己闆诲瓙鍖栧悎鐗�锛屽垎瀛愪腑闄や簡鏈夊洓鍊� B鈥擧 閸靛锛岄倓鏈夊叐鍊嬶紙20锛夐嵉锛�
涓夈€佸畬鎴愬苟閰嶅钩涓嬪垪鍙嶆噳(y墨ng)鏂圭▼寮忥紙鍏� 5 灏忛锛屾瘡灏忛 4 鍒�锛屽叡 20 鍒嗭級
1锛嶱bO + Cl2 + NaOH 鈫�
2锛嶤o(OH)3 + HCl 鈫�
3锛嶪2 + H2SO3 + H2O 鈫�
4锛嶮nO2 + HBr 鈫�
5锛嶬I + KIO3 + H2SO4 (绋€) ==
鍥�銆佺啊绛旈锛堝叡 5 灏忛锛屾瘡灏忛 6 鍒嗭紝鍏� 30 鍒嗭級
1锛庨媷楣戒竴鑸湁姣掞紝渚嬪 0.8 鍏嬬殑 BaCl2路2H2O 鑳藉鑷翠汉浜庢锛屼絾閱�(y墨)瀛�(xu茅)涓婄殑鈥滈媷椁愰€忚鈥�
鍗荤敤 BaSO4 鑸囩硸婕挎贩鍚堝悗璁撲汉鏈嶄笅锛岃│瑙ｉ噵锛�
锛�1锛塀aSO4 浣滅偤鑵歌儍 X 灏勭窔閫犲奖鏉愭枡锛涳紙2锛塀aSO4 涓嶆渻涓瘨
2锛庡湪鍏€嬫矑鏈夋(bi膩o)绨界殑瑭﹀姂鐡朵腑锛屽垎鍒ヨ鏈夌櫧鑹插浐楂旇│鍔戯細Na2CO3 銆丅aCO3銆� CaCl2銆�
Na2SO4 銆丮g(OH)2 銆丮gCO3銆傝│瑷�(sh猫)娉曢憭鍒ュ苟浠ラ洟瀛愭柟绋嬪紡琛ㄧず涔嬨€�
3. 鏌愪汉鍋氬椹楁檪锛岀櫦(f膩)鐝�(xi脿n) SnS 琚�(NH4)2S 婧舵恫婧惰В锛屼綘瑾嶇偤鍙兘鐨勫師鍥犳槸浠€涔�锛熷浣曡瓑鏄�
浣犵殑鍒ゆ柗鏄纰虹殑锛�
4. 宸茬煡瀹ゆ韩涓� H3PO4 鐨� Ka1 = 7.5脳10
-3
锛孠a2 = 6.2脳10
-8
锛孠a3 =2.2脳10
-13
锛孒2O 鐨�
Kw = 1脳10
-14
銆傝│瑙ｉ噵 NaH2PO4 婧舵恫鍛堥吀鎬�锛岃€� Na2HPO4 婧舵恫鍛堝牽鎬�銆�
5锛庡椹椾簨瀵﹁〃鏄�锛孎(xi脿n)2 鐨勯潪閲戝爆鎬ф瘮 Cl2 寮�锛岀偤浠€涔� F 鍏冪礌鐨勯浕瀛愯Κ鍜岃兘鍗绘瘮鍚屾棌鐨� Cl
鍏冪礌鐨勯浕瀛愯Κ鍜岃兘灏�锛�
浜�銆佽▓绠楅锛堝叡 2 灏忛锛屽叡 20 鍒嗭級
绗� 8 闋�锛屽叡 8 闋�
1. 鎿�(j霉)鐮旂┒鍫遍亾锛屼互 Cu銆乑n 鍜� Fe 鐨勬哀鍖栫墿鐐哄偓鍖栧姂锛屽湪 573 K锛�70000 kPa锛孋O2 : H2 =1:3
(楂旂⿳姣�)鐨勬浠朵笅锛岃兘浣� CO2 鑸� H2 鍙嶆噳(y墨ng)杞�(zhu菐n)鍖栫偤涔欓唶銆傚凡鐭ワ細
2CO2(g) + 6 H2(g) = CH3CH2OH (g) + 3 H2O (g)
鈻砯H 0
m
/ kJ路mol
-1
-393.5 0 -234.4 -241.8
鈻砯G 0
m
/ kJ路mol
-1
-394.4 0 -167.9 -228.6
S 0
m
/ J路mol
-1
路K
-1
213.6 130.6 282.6 188.7
锛�1锛夎▓绠� 298 K 涓嬭┎鍙嶆噳(y墨ng)鐨勨柍rG0
m
鍜屾(bi膩o)婧栧钩琛″父鏁�(sh霉)锛�
锛�2锛夊弽鎳�(y墨ng)鍦� 573 K锛�70000 kPa 姊濅欢涓嬬殑鑷櫦(f膩)鎬�锛�
锛�3锛夎鏄庡弽鎳�(y墨ng)鍦� 573 K锛�70000 kPa 姊濅欢涓嬮€茶鐨勫繀瑕佹€�銆�
锛�4锛夌偤浜嗘彁楂樺弽鎳�(y墨ng)鐨勮綁(zhu菐n)鍖栫巼锛屽悎鎴愭浠舵噳(y墨ng)鏈変粈涔堣畩鍖�锛熸彁鍑轰綘鐨勭湅娉曘€傦紙10 鍒嗭級
2. 瑭﹂€氶亷瑷堢畻瑾槑 [Co(NH3)6]
3+
+ 2Ag + S
2-
??? [Co(NH3)6]
2+
+ Ag2S 鍙嶆噳(y墨ng)鐨勮嚜鐧�(f膩)鎬�銆�
宸茬煡 ?
? (Co3+
/Co2+
) = 1.83 V锛� ?
? (Ag+
/Ag) = 0.799 V锛沎Co(NH3)6]3+
鐨� K 绌�(w臎n) 鈮�1035
锛孾Co(NH3)6]2+
鐨� K 绌�(w臎n) 鈮�105
锛孉g2S 鐨� Ksp鈮�1脳10-49
锛堝亣瀹氶櫎[Co3+
]銆乕Co2+
]鍜孾Ag+
]澶栵紝鍏跺畠闆㈠瓙鐨勬績搴﹀潎鐐�
1 mol/dm
-3
锛夈€傦紙10 鍒嗭級
鍏�銆佺稖鍚堥锛堝叡 2 灏忛锛屽叡 20 鍒嗭級
1. 閲戝爆 A 婧朵簬绋€楣介吀鐢熸垚 ACl2锛屽叾纾佺煩鐐� 4.93 B.M.銆侻Cl2 鍦ㄧ劇姘ф浠朵笅閬� NaOH 婧舵恫
鐢熸垚鐧借壊娌夋穩锛岃┎娌夋穩鎺ヨЦ绌烘埃閫愭几璁婄伆缍狅紝鏈€鍚庤畩鎴愭鑹叉矇娣€ B锛涘湪瓒抽噺鐨勭┖姘ｄ腑鐏肩噿 B
寰楃磪鑹茬矇鏈� C锛孋 缍�(j墨ng)涓嶅竟搴曢倓鍘熷緱榛戣壊纾佹€х墿璩�(zh矛) D锛汢 婧朵簬绋€楣介吀鐢熸垚娣洪粌鑹叉憾娑� E锛孍 鍙哀
鍖� KI锛涙憾娑� E 鍙厫铦曢噾灞� F 鐢熸垚 ACl2 鍜� G 婧舵恫锛涘悜婧舵恫 G 涓淮鍔� NaOH锛屾湁铇壊鑶犵媭娌夋穩
鐢熸垚锛屽姞鐔辫┎鑶犵媭娌夋穩绔嬪嵆杞�(zhu菐n)璁�?y艒u)妤硅皬顐▂婧剁墿 H锛汬 鍦ㄦ績楣介吀涓張璁婃垚榛冪稜鑹叉憾娑�锛屽悜婧舵恫
G 涓姞閬庨噺鐨� NaOH 鑷虫矇娣€婧惰В锛屽啀婊村姞閬╅噺钁¤悇绯栨憾娑�锛屽井鐔卞悗鏈夌绱呰壊涓嶆憾鐗� I 鏋愬嚭锛�
灏� I 鑸囩█纭吀浣滅敤寰楄棈鑹叉憾娑� J 鍜屽浐楂� F锛孎(xi脿n) 涓嶆憾浜庣█纭吀鍙憾浜庢績纭吀寰楄棈鑹叉憾娑� G銆傝│纰�
瀹� A銆丅銆丆銆丏銆丒銆丗銆丟銆丠銆両銆丣 鍚勭偤浣曠墿銆傚鍑� E鈫扜銆丟鈫扞銆両鈫扟 鍜� F鈫扜 鐨勫寲瀛�(xu茅)鏂�
绋嬪紡銆傦紙14 鍒嗭級
2. 鏌愭贩鍚堟憾娑蹭腑鍍呭惈 Fe
3+
銆丄l
3+
鍜� Cr
3+
鍜� NO3
-
锛岃珛瑷�(sh猫)瑷堜竴鏂规鍒嗛洟涔嬨€傦紙6 鍒嗭級
鍏嶈铂(z茅)鑱叉槑锛氭湰鏂囩郴杞�(zhu菐n)杓夎嚜缍�(w菐ng)绲�(lu貌)锛屽鏈変镜鐘�锛岃珛鑱�(li谩n)绯绘垜鍊戠珛鍗冲埅闄�锛屽彟锛氭湰鏂囧儏浠ｈ〃浣滆€呭€嬩汉瑙€榛烇紝鑸囨湰缍�(w菐ng)绔欑劇闂�(gu膩n)銆傚叾鍘熷壍(chu脿ng)鎬т互鍙婃枃涓櫝杩版枃瀛楀拰鍏�(n猫i)瀹规湭缍�(j墨ng)鏈珯璀夊锛屽皪鏈枃浠ュ強鍏朵腑鍏ㄩ儴鎴栬€呴儴鍒嗗収(n猫i)瀹广€佹枃瀛楃殑鐪熷鎬�銆佸畬鏁存€�銆佸強鏅傛€ф湰绔欎笉浣滀换浣曚繚璀夋垨鎵胯锛岃珛璁€鑰呭儏浣滃弮鑰�锛屽苟璜嬭嚜琛屾牳瀵︾浉闂�(gu膩n)鍏�(n猫i)瀹�銆�
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鏂囩珷鎼滅储
鎮ㄧ従(xi脿n)鍦ㄧ殑浣嶇疆锛� 
