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1. 鐒�(w煤)姗�(j墨)鍖栧(xu茅)(涓�銆佷笅鍐�(c猫)锛岀涓夌増)锛屾婕㈠ぇ瀛�(xu茅)銆佸悏鏋楀ぇ瀛�(xu茅)绛夋牎绶�锛岄珮绛夋暀鑲插嚭鐗堢ぞ锛�2010
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2. 鐒�(w煤)姗�(j墨)鍖栧(xu茅)鍩烘湰鍘熺悊锛岃敗灏戣彲銆侀緮瀛熸總銆佸彶鑿磪 绶ㄨ憲锛屼腑灞卞ぇ瀛�(xu茅)鍑虹増绀�锛�2001 骞寸増
3. 鍏冪礌?z茅)o姗�(j墨)鍖栧(xu茅)锛岃敗灏戣彲銆侀粌鍧よ€€銆佸嫉鐜夊 绶ㄨ憲锛屼腑灞卞ぇ瀛�(xu茅)鍑虹増绀�锛�2003 骞寸増
绗� 6 闋�(y猫)锛屽叡 11 闋�(y猫)
鍥涖€佹ǎ鍗�
鎻愮ず锛�
鎻愮ず 1銆佽€冭│绛旈鏅�(sh铆)涓€寰嬪(xi臎)鍦ㄧ瓟椤岀礄涓�锛屽惁鍓囨紡鎵硅铂(z茅)浠昏嚜璨�(f霉)锛�
鎻愮ず 2銆佸彲鍏佽ū浣跨敤瑷�(j矛)绠楀櫒锛�
鎻愮ず 3銆佽€冭│鏅�(sh铆)闁撶偤 3 灏忔檪(sh铆)锛屾湰鍗锋豢(m菐n)鍒� 150 鍒�銆�
涓€銆侀伕鎿囬锛堝叡 25 灏忛锛屾瘡灏忛 2 鍒嗭紝鍏� 50 鍒嗭級
1. 濡傛灉楂旂郴缍�(j墨ng)閬�(gu貌)涓€绯诲垪璁婂寲锛屾渶鍚庡張璁婂洖鍒濆鐙€鎱�(t脿i)锛屽墖楂旂郴鐨�
A. Q = 0, W = 0, 鈻砋 = 0, 鈻矵 = 0 B. Q = W, 鈻砋 = 0, 鈻矵 = 0
C. Q = -W, 鈻砋 = Q + W, 鈻矵 = 0 D. Q 鈮� W, 鈻砋 = Q + W, 鈻矵 = 0
2. 涓嬪垪鐗╄唱(zh矛)涓�锛屼笉灞簬鍏跺叡杌涢吀鍫跨殑鏄�
A. NH4
+
, NH3 B. H2O, OH-
C. NH3, NH2
-
D. HF, H2F+
3. 涓嬪垪鍒嗗瓙鍜岄洟瀛愪腑锛岄嵉鑳芥渶澶х殑鏄�
A. N2 B. O2
+
C. NO D. O2
-
4. 涓嬪垪鍚勯厤闆㈠瓙涓�锛屽叿鏈夐爢纾佹€х殑鏄�
A. [Ni(CN)4]2-
B. [NiCl4]2-
C. [PtCl4]2-
D. [PtCl6]2-
5. 鏅堕珨鍫�(ch菐ng)绌�(w臎n)瀹氬寲鑳芥渶澶х殑鏄�
A. [Fe(H2O)6]2+
B. [Fe(H2O)6]3+
C. [Fe(CN)6]3-
D. [Fe(CN)6]4-
6. 涓嬪垪鐗╄唱(zh矛)涓�锛岄倓鍘熸€ф渶寮�(qi谩ng)鐨勬槸
A. HF B. PH3 C. NH3 D. H2S
7. 涓嬪垪纭寲鐗╀腑锛屽彲婧朵簬 Na2S 婧舵恫鐨勬槸
A. HgS B. CuS C. SnS D. Ag2S
8. 鐩稿悓姊濅欢涓嬶紝 ?
4
ClO 銆� ?
4
BrO 銆� ?
4
IO 姘у寲鎬ц兘鍔涘ぇ灏忕殑闋嗗簭鏄�
A. ?
4
ClO 锛� ?
4
BrO 锛� ?
4
IO B. ?
4
ClO 锛� ?
4
IO 锛� ?
4
BrO
C. ?
4
ClO < ?
4
BrO 锛� ?
4
IO D. ?
4
ClO < ?
4
BrO < ?
4
IO
9. 涓嬪垪鍚勭祫閲忓瓙鏁�(sh霉)涓�锛岄偅涓€绲勭殑闆诲瓙鎵€铏曠殑鑳界礆(j铆)鏈€浣�锛�
A. n = 3锛宭 = 2锛宮 = 0锛宮s = 1/2. B. n = 4锛宭 = 2锛宮 = -2锛宮s = 1/2
C. n = 4锛宭 = 0锛宮 = 0锛宮s = -1/2 D. n = 3锛宭 = 1锛宮 = -1锛宮s = -1/2
10. 鏌愬厓绱犱綅浜庡懆鏈熻〃涓� 36 铏�(h脿o)鍏冪礌涔嬪墠锛屽け鍘� 3 鍊�(g猫)闆诲瓙鍚�锛岃閲忓瓙鏁�(sh霉)鐐� 2 鐨勮粚
閬撲笂閭勬湁 3 鍊�(g猫)闆诲瓙锛岃┎鍏冪礌鏄�
A. Cr B. Zn C. As D. Fe
绗� 7 闋�(y猫)锛屽叡 11 闋�(y猫)
11. 鍗囬珮婧害鍙嶆噳(y墨ng)閫熷害鍔犲揩鐨勪富瑕佸師鍥犳槸
A. 娲诲寲鍒嗗瓙鐨勭櫨鍒�?j菒n)?sh霉)澧炲姞 B. 娲诲寲鑳藉鍔�
C. 楂旂郴鑳介噺澧炲姞 D. 鍒嗗瓙閬�(y霉n)鍕�(d貌ng)閫熷害鍔犲揩
12. 鍦� 25 鈩冨拰 101.3 kPa 澹撳姏涓嬬櫦(f膩)鐢熶笅鍒楀弽鎳�(y墨ng)
锛�1锛�2H2(g) + O2 (g)鈥斺啋2H2O锛坓锛�锛涳紙2锛塁aCO3锛坰锛夆€斺啋CaO(s) + CO2(g).
鍏剁喌璁婂垎鍒ョ偤鈻砈1 鍜屸柍S2锛屽墖涓嬪垪鎯呮硜浣曡€呮纰�锛�
A. 鈻砈1 ?0锛屸柍S2 ?0 B. 鈻砈1 ?0锛屸柍S2 ?0
C. 鈻砈1 ?0锛屸柍S2 ?0 D. 鈻砈1 ?0锛屸柍S2 ?0
13. 鍦ㄥ弽鎳�(y墨ng) CO2(g) + C(s) 2CO(g)鍦� 298K锛�101.3 kPa 澹撳姏涓嬬殑
鈻硆H0
m
=171.5kJ路mol-1
锛屼笅鍒楅偅绋柟娉曡兘浣垮钩琛″悜鍙崇Щ鍕�(d貌ng)
A. 闄嶄綆澹撳姏锛岄檷浣庢韩搴� B. 闄嶄綆澹撳姏锛屽崌楂樻韩搴�
C. 鍗囬珮澹撳姏锛屽崌楂樻韩搴� D. 鍗囬珮澹撳姏锛岄檷浣庢韩搴�
14. 鍚戠洓鏈� Br-
銆両-
娣峰悎娑插強 CCl4(l)鐨勮│绠′腑閫愭淮鍔犲叆姘按锛屽湪 CCl4 灞や腑鍙瀵�
鍒扮殑鐝�(xi脿n)璞＄偤
A. 鍏堝嚭鐝�(xi脿n)绱壊锛岄毃鍚庤畩榛冭壊
B. 鍏堝嚭鐝�(xi脿n)榛冭壊锛岄毃鍚庡嚭鐝�(xi脿n)绱壊
C. 鍏堝嚭鐝�(xi脿n)绱壊锛岄毃鍚庡嚭鐝�(xi脿n)榛冭壊锛屽啀璁婃垚鐒�(w煤)鑹�
D. 鍏堝嚭鐝�(xi脿n)绱壊锛岄毃鍚庤畩鐒�(w煤)鑹�锛屾渶鍚庡嚭鐝�(xi脿n)榛冭壊
15. 鏌愬寲鍚堢墿 A 鐨勬按鍚堟櫠楂� A路3H2O锛坰锛夌殑鑴按閬�(gu貌)绋嬬偤
鈶� A路3H2O锛坰锛� A路2H2O锛坰锛�+ H2O锛坓锛� K1
0
鈶� A路2H2O锛坰锛� A路H2O锛坰锛�+ H2O锛坓锛� K2
0
鈶� A路H2O锛坰锛� A锛坰锛�+ H2O锛坓锛� K3
0
鐐轰簡浣� A路2H2O锛坰锛変繚鎸佺┅(w臎n)瀹�锛岋紙鏃笉鐧�(f膩)鐢熼ⅷ(f膿ng)鍖�锛屼篃涓嶇櫦(f膩)鐢熸疆瑙ｏ級锛屽墖
瀹瑰櫒涓� H2O 鐨勮捀姹藉鑸囧钩琛″父鏁�(sh霉)鐨勯棞(gu膩n)绯绘噳(y墨ng)婊�(m菐n)瓒�
A. K2
0
銆塸 (H2O) / p0
銆塊3
0
B. p(H2O) / p0
銆塊2
0
C. p(H2O) / p0
銆塊1
0
D. K1
0
銆塸(H2O) / p0
銆塊2
0
16锛庝笅鍒楁矮姘у寲鐗╂棦鑳芥憾浜庢矮姘у寲閳夊張鑳芥憾浜庢績姘ㄦ按鐨勬槸
A锛嶤o(OH)2 B锛嶧e(OH)3 C锛嶤r(OH)3 D锛嶢l(OH)3
17锛庝笅鍒楀摢绲勬憾娑蹭腑鐨勯洟瀛愪笉鑳藉叡瀛�
A锛嶯H4
+
銆丆l-
銆丯a+
銆丯O3
-
B锛嶧e2+
銆並+
銆丆l-
銆丼O4
2-
C锛嶯a+
銆丼O3
2-
銆丠+
銆丮nO4
-
D锛嶢l3+
銆丆l-
銆並+
銆丯H4
+
绗� 8 闋�(y猫)锛屽叡 11 闋�(y猫)
18锛庨懎绯绘敹绺殑鍚庢灉涔嬩竴鏄娇涓嬪垪鍝祫鍏冪礌鐨勬€ц唱(zh矛)鏇寸浉浼�
A锛嶮n 鍜� Tc B锛嶳u銆丷h銆丳d C锛嶴c 鍜� La D锛嶼r 鍜� Hf
19. 涓嬪垪鍖栧悎鐗╁爆浜庣己闆诲瓙鍖栧悎鐗╃殑鏄�
A. BCl3 B. H[BF4] C.Na2B4O7?8H2O D.Na[Al(OH)4]
20锛嶽Pt(Cl)4]2-
鑸� C2H4 鍙嶆噳(y墨ng)鐢熸垚[Pt(C2H4)(Cl)3]-
锛岃珛(q菒ng)鍟�(w猫n) Pt 鑸� C2H4 涔嬮枔鐨勫寲瀛�(xu茅)閸靛爆
浜�
A锛幭� 閰嶉嵉 B锛幭€ 閰嶉嵉
C锛幭€鈥斚�* 閰嶉嵉 D锛幭冣€斚€* 閰嶉嵉
21锛嶬MnO4 鍛堢传鑹�锛岀敘(ch菐n)鐢熺殑鍘熷洜鏄�
A锛巇-d 鍏夎瓬 B锛庤嵎绉诲厜璀� C锛巉-f 鍏夎瓬 D锛庢媺鏇煎厜璀�
22锛庝笅鍒楀摢绋景鍩哄寲鍚堢墿绗﹀悎 18e 瑕�(gu墨)鍓�
A锛嶤o(CO)4 B锛嶸(CO)6 C锛嶮n(CO)5 D锛嶮n2(CO)10
23锛嶱b(II)鍖栧悎鐗╁緢绌�(w臎n)瀹�锛岃€� Pb(IV)鍖栧悎鐗╃殑绌�(w臎n)瀹氭€фサ宸�锛屾槗琚倓鍘熺偤 Pb(II)
鍖栧悎鐗�锛岄€欑ó鎬ц唱(zh矛)鑸� Pb 鐨勪笅鍒楀摢绋洜绱犵壒鍒ユ湁闂�(gu膩n)
A锛嶱b 鏄噸鍘熷瓙锛� B锛嶱b 鐨勯浕瀛愬堡澶�锛�
C锛嶱b 鐨� 6S2
鎯版€ч浕瀛愬皪(du矛)鏁堟噳(y墨ng)锛� D锛嶱b(IV)鐨勫崐寰戝皬銆�
24. 娆蹭娇閷崇う锛圡nO2锛夎綁(zhu菐n)璁�?y艒u)?KMnO4, 鎳�(y墨ng)閬告搰鐨勮│鍔戞槸
A. KClO3(s) + KCl(s); B. 婵� HNO3; C. Cl2; D. O2
25. 鐢� Cr2O3 鐐哄師鏂欏埗鍌欓壔閰搁菇鎳�(y墨ng)閬哥敤鐨勮│鍔戞槸
A. 婵冪閰� B. KOH(s) +KClO3(s)
C. Cl2 D. H2O2
浜�銆佸～绌洪锛堝叡 30 鍊�(g猫)绌猴紝姣忕┖ 1 鍒�锛屽叡 30 鍒嗭級
26. 纭吀浜炵閰告牴浜旀皑鍚堥埛锛圛II锛夌殑鍖栧(xu茅)寮忔槸 锛�
27. 鑷劧鐣屼腑纭害鏈€澶х殑鍠唱(zh矛) ; 鐔旈粸(di菐n)鏈€楂樼殑閲戝爆鍏冪礌鏄� .
28. 宸茬煡鍙嶆噳(y墨ng) 锛�1锛塅e2O3锛坰锛�+ 3CO锛坓锛�= 2Fe锛坰锛�+3CO2锛坓锛�锛涳紙2锛�3Fe2O3
锛坰锛�+ CO锛坓锛�= 2Fe3O4锛坰锛�+CO2锛坓锛夛紱锛�3锛塅e3O4锛坰锛�+ CO锛坓锛�=3FeO锛坰锛�
+ CO2锛坓锛�. 鍓囧弽鎳�(y墨ng) FeO锛坰锛�+CO锛坓锛�= Fe锛坰锛�+CO2锛坓锛夌殑鎭掑鍙嶆噳(y墨ng)鐔辫▓(j矛)绠�
鍏紡鏄�
29. XeF4 鍒嗗瓙骞句綍妲�(g貌u)鍨嬬偤 銆�
30. 鐩稿悓鐗╄唱(zh矛)鐨勯噺婵冨害鍜岀浉鍚岄珨绌嶇殑 CaCl2锛孠Cl锛孋6H12O6 (钁¤悇绯�)鍜� H2C2O4
(Ka1?10-4
) 婧舵恫锛屽叾鍑濆浐榛�(di菐n)鐢变綆鍒伴珮鐨勯爢搴忔槸 銆�
31. 闆㈠瓙妤靛寲鐨勭祼(ji茅)鏋滀娇鍖栧悎鐗╃殑閸靛瀷鐩告噳(y墨ng)鍦扮敱闆㈠瓙閸靛悜 閸甸亷(gu貌)娓�锛岄€氬父鏈�(hu矛)浣�
绗� 9 闋�(y猫)锛屽叡 11 闋�(y猫)
鍖栧悎鐗╃殑鐔斻€佹哺榛�(di菐n) 銆�
32. 鑻ュ弽鎳�(y墨ng)鈶燦2锛坓锛�+O2锛坓锛�=2NO锛坓锛夛紱鈶� N2锛坓锛�+3H2锛坓锛�=2NH3锛坓锛�锛�
鍦ㄤ笅鍒楀叐绋儏娉佷笅锛屽畠鍊戝悇鑷槸浠€涔堥亷(gu貌)绋嬶紙鎸囨亽澹撱€佹亽瀹癸級锛�
A.鍦ㄥ瘑闁夌殑瀹瑰櫒涓€�(j矛n)琛岋細鍙嶆噳(y墨ng)鈶� 锛�
B.鍦ㄩ枊(k膩i)鍙ｇ殑瀹瑰櫒涓€�(j矛n)琛岋細鍙嶆噳(y墨ng)鈶� 锛�
33. 鍦ㄧ浉鍚屾浠朵笅锛孒Br (g)鍜� PH3(g) 鐩告瘮锛� 鐨勬摯(ku貌)鏁ｉ€熷害蹇�锛�
34. 涓€灏侀枆楂旂郴鍦ㄦ煇閬�(gu貌)绋嬩腑鍚戠挵(hu谩n)澧冨惛鏀朵簡 30kJ 鐨勭啽閲忥紝灏�(du矛)鐠�(hu谩n)澧冨仛浜嗕簡 50kJ 鐨勫姛锛�
鍓囬珨绯诲湪瑭查亷(gu貌)绋嬩腑鐨勭啽鍔涘(xu茅)鑳借畩鍖栫偤 锛�
35. 浜屽厓寮遍吀鐨勯吀鏍规績搴﹁繎浼肩瓑浜� 锛�
36. 灏�(du矛)鍚堟垚姘ㄥ弽鎳�(y墨ng) N2(g) + 3H2(g) 2NH3(g)閬�(d谩)鍒板钩琛℃檪(sh铆)锛屽湪鎭掓韩鎭掑涓嬮€氬叆姘�
姘ｏ紝灏囦娇骞宠 绉诲嫊(d貌ng)锛堟鍚�銆侀€嗗悜銆佷笉锛�锛�
37. 鍋囧畾 NO2 + SO2 NO + SO3 鏄熀鍏冨弽鎳�(y墨ng)锛屽墖瑭插弽鎳�(y墨ng)鐨勭礆(j铆)鏁�(sh霉)鐐� 锛�
38. 宸茬煡 )/(
23 ??
FeFe
?
? = 0.77 V锛� )/( 2
?
BrBr
?
? = 1.1 V锛� )/( 2
?
ClCl
?
? = 1.36 V锛�
鍓囨涓夐浕灏�(du矛)绲勫悎鏅�(sh铆)锛岃嚜鐧�(f膩)閫�(j矛n)琛岃定鍕�(sh矛)鏈€澶х殑鍙嶆噳(y墨ng)鏂圭▼寮忔槸 锛�
39. 闈為噾灞厓绱犵殑鍚哀閰镐腑锛岄潪缇ュ熀姘у師瀛愯秺澶�锛屽叾閰告€� 锛�
40. H3PO2 鏄� 鍏冮吀锛�
41. 姣旇純澶у皬鍜岄珮浣庯紙鐢� 銆夋垨銆� 琛ㄧず锛�
鍫� 鎬э細Ca(OH)2 Zn(OH)2锛�
闆㈠瓙鎬э細KCl CuCl锛�
鐔� 榛�(di菐n)锛欶eCl3 FeCl2锛�
姘存憾鎬э細AgF AgI锛�
姘磋В鎬э細Sn2+
Sn4+
锛�
42. 鎴戝湅(gu贸)鐮斿埗鐨勨€滈暦(zh菐ng)寰佷簩铏�(h脿o)鈥濈伀绠殑涓昏鍘熸枡鏄亸浜岀敳鑲硷紝宸茬煡瀹冩槸涓€绋垎瀛愮祼(ji茅)妲�(g貌u)
涓嶅皪(du矛)绋�(ch膿ng)鐨勬サ鎬у寲鍚堢墿锛屽垎瀛愮浉灏�(du矛)璩�(zh矛)閲忕偤 60锛屽叾涓�锛孋 40%锛孒 13.33%锛屽叾浣欐槸
N銆傜伀绠捣椋涙檪(sh铆)锛屽彲浠ョ湅鍒颁竴绱�(j铆)鐏鍐掑嚭绱呮鑹叉埃楂旓紝閫欐槸鐐轰簡淇濊瓑璨鐨勫畨鍏�锛�
鐢变繚闅�(xi菐n)闁€(m茅n)鑷嫊(d貌ng)闁�(k膩i)鍟熸帓鍑洪儴鍒嗛珮澹撶殑姘у寲鍔戣畩鍖栬€屼締(l谩i)鐨勩€傚亸浜岀敳鑲肩殑绲�(ji茅)妲�(g貌u)绨�(ji菐n)寮�
鐐� 锛岀噧鐕掑弽鎳�(y墨ng)鐨勫寲瀛�(xu茅)鏂圭▼寮忔槸 锛�
43. 瀵�(sh铆)椹�(y脿n)瀹ゅ瓨鏀句笅鍒楃墿璩�(zh矛)鐨勬柟娉曞垎鍒ユ槸锛氱櫧纾� 锛涢噾灞垑 锛�
44. 鍦ㄩ潰蹇冪珛鏂归噾灞妳鏅堕珨涓�锛屾瘡鍊�(g猫)鏅惰優鎵€鍚妳鍘熷瓙鏁�(sh霉)鐐� .锛�
45. O2
+
, N2, NO, CN-
涓簰鐐虹瓑闆诲瓙楂旂殑鏄� 锛�
46. 閰嶇疆 FeCl2 婧舵恫瑕佺敤楣介吀鑰屼笉鏄捀椁炬按鐨勫師鍥� 銆�
绗� 10 闋�(y猫)锛屽叡 11 闋�(y猫)
涓�銆佸畬鎴愬寲瀛�(xu茅)鏂圭▼寮忥紙鎴栭洟瀛愭柟绋嬪紡锛夛紙鍏� 5 灏忛锛屾瘡灏忛 2 鍒�锛屽叡 10 鍒嗭級
47銆佷互妯�(bi膩o)婧�(zh菙n)纭唬纭吀閳夋憾娑叉脯(c猫)瀹氭憾娑蹭腑鐨� I2 鍚噺 锛�
48銆侀墠閰搁垑鑸� MnSO4 鍦ㄧ█纭吀浠嬭唱(zh矛)涓弽鎳�(y墨ng)锛�
49銆佹哀鍖栭埛锛圛II锛夎婵冮菇閰告憾瑙ｏ紱
50銆佺鏀惧叆瓒抽噺 NaOH 婧舵恫涓�锛�
51. 纭寲閵呰垏绋€纭濋吀鍏辩啽銆�
鍥�銆佺啊(ji菐n)绛旈锛堝叡 4 灏忛锛屽叡 20 鍒嗭級
52锛�4 鍒嗭級. 宸茬煡瀹ゆ韩涓� H3PO4 鐨� Ka1 = 7.5脳10-3
锛孠a2 = 6.2脳10-8
锛孠a3 =2.2脳10-13
锛�
H2O 鐨� Kw = 1脳10-14
銆傝│瑙ｉ噵 NaH2PO4 婧舵恫鍛堥吀鎬�锛岃€� Na2HPO4 婧舵恫鍛堝牽鎬�銆�
53.锛�4 鍒嗭級浠€涔堟槸绶╂矕婧舵恫锛熷垪鑸� 2 渚嬭(shu艒)鏄庝綘鎵€鐭ラ亾鐨勭珐娌栨憾娑查珨绯�銆�
54.锛�8 鍒嗭級瀵�(xi臎)鍑轰笅鍒楃墿璩�(zh矛)鐨勫悕绋�(ch膿ng)鍜岀祼(ji茅)妲�(g貌u)寮�
P4O10; H4P2O7; CrO5; B2H6
55.锛�4 鍒嗭級Au 涓嶆憾浜庢績纭濋吀锛屼絾鍙憾浜庣帇姘�锛岃珛(q菒ng)绲﹀嚭 Au 婧朵簬鐜嬫按鐨勫弽鎳�(y墨ng)寮忥紝
骞惰В閲嬬帇姘磋兘姘у寲 Au 鐨勪富瑕佸師鍥�銆�
浜�銆佽▓(j矛)绠楅锛堝叡 3 灏忛锛屽叡 30 鍒嗭級
56.锛�12 鍒嗭級298 K銆佹(bi膩o)婧�(zh菙n)澹撳姏鏅�(sh铆)锛岄噾鍓涚煶鍜岀煶澧ㄧ殑鐔卞姏瀛�(xu茅)鏁�(sh霉)鎿�(j霉)濡備笅锛�
鐭冲ⅷ 閲戝墰鐭�
Sm
0
/J?K?mol-1
5.7 2.4
鈻砪Hm
0
/ kJ?mol-1
(鐕冪噿鐔�) -393.4 -395.3
锛�1锛� 鍦ㄦ(bi膩o)婧�(zh菙n)鐙€娉佷笅锛岀煶澧ㄨ綁(zhu菐n)鍖栫偤閲戝墰鐭崇殑鈻硆Gm
0
; 锛�6 鍒嗭級
锛�2锛� 鍒ゆ柗鍦ㄥ父婧父澹撲笅鍝竴绋櫠鍨嬬┅(w臎n)瀹�锛涳紙2 鍒嗭級
锛�3锛� 鑳藉惁鐢ㄥ崌楂樻韩搴︾殑鏂规硶浣跨煶澧ㄨ綁(zhu菐n)鍖栫偤閲戝墰鐭�锛熺偤浠€涔堬紵锛�4 鍒嗭級
57.锛�10 鍒嗭級鍦� 298 K 鏅�(sh铆)锛屽皣婵冨害鍧囩偤 0.3 mol路dm-3
CdSO4銆丯iSO4 鍜� MnSO4 绛�
楂旂⿳娣峰悎浣跨附楂旂⿳鐐� 1 dm3
锛� 灏� 101 kPa銆�24.53 dm3
H2S 姘ｉ珨閫氬叆鍒版贩鍚堟憾娑蹭腑
褰㈡垚椋藉拰婧舵恫锛堝亣瀹氭憾娑查珨绌嶄笉璁婏級銆�
鈶� 娆蹭娇 Cd2+
娌夋穩瀹岀暍鑰� Ni2+
銆丮n2+
涓嶆矇娣€锛屾憾娑茬殑 H+
婵冨害鎳�(y墨ng)鎺у埗鍦ㄤ綍鑼冨湇锛�
鈶� 娆蹭娇 Cd2+
銆丯i2+
娌夋穩瀹岀暍鑰� Mn2+
涓嶆矇娣€锛屾憾娑茬殑 H+
婵冨害鎳�(y墨ng)鎺у埗鍦ㄤ綍鑼冨湇锛�
宸茬煡锛欿sp(CdS)鈮�10-29
; Ksp(NiS)鈮�10-21
; Ksp(MnS)鈮�10-15
; H2S锛欿a1鈮�10-7
锛汯a2鈮�10-15
58.锛�8 鍒嗭級宸茬煡 ?
? (Fe3+
/Fe2+
) = 0.77V锛� ?
? (Ag+
/Ag) = 0.799V锛汯 绌�(w臎n)([Fe(CN)6]3-
)鈮�10
42
锛�
K 绌�(w臎n)([Fe(CN)6]4-
)鈮�10
35
锛汯sp锛孉gCl = 1脳10-10
锛� ?
? 锛圓g
+
/Ag 锛�= 0.799V銆傝│閫氶亷(gu貌)瑷�(j矛)绠楄(shu艒)鏄�
绗� 11 闋�(y猫)锛屽叡 11 闋�(y猫)
[Fe(CN)6]3-
+ Ag + Cl-
??? [Fe(CN)6]4-
+ AgCl 鍙嶆噳(y墨ng)鐨勮嚜鐧�(f膩)鎬с€�
锛堝亣瀹氶櫎[Fe3+
]銆乕Fe2+
]鍜孾Ag+
]澶�锛屽叾瀹冮洟瀛愮殑婵冨害鍧囩偤 1 mol/dm-3
锛�
鍏€佹帹鏂烽锛�10 鍒嗭級
59. 鍖栧悎鐗� A 鏄竴绋粦鑹插浐楂�锛屼笉婧朵簬姘�銆佺█ HAc 鍙婄█ NaOH 婧舵恫涓紝鑰屾槗婧�
浜庣啽 HCl 婧舵恫涓�锛岀敓鎴愪竴绋稜鑹茬殑婧舵恫 B锛涘鏋滄憾娑� B 鑸囬妳绲蹭竴璧风叜娌�锛屽嵆閫�
婕哥敓鎴愬湡榛冭壊婧舵恫 C锛涜嫢鐢ㄨ純澶ч噺姘寸█閲嬫憾娑� C锛岀敓鎴愮櫧鑹叉矇娣€ D銆侱 鍙憾浜庢皑
姘翠腑鐢熸垚鐒�(w煤)鑹叉憾娑� E锛涚劇(w煤)鑹叉憾娑� E 鍦ㄧ┖姘ｄ腑杩呴€熻畩鎴愯槶鑹叉憾娑� F锛涘線 F 涓姞鍏�
KCN 鏅�(sh铆)锛岀敓鎴愮劇(w煤)鑹叉憾娑� G锛涘線 G 涓姞鍏ラ媴绮夊墖鐢熸垚绱呰壊娌夋穩 H锛汬 涓嶆憾浜庣█閰�
鎴栫█鍫夸腑锛屼絾鍙憾浜庣啽 HNO3 涓敓鎴愯槶鑹叉憾娑� I锛涘線 I 涓參鎱㈠姞鍏� NaOH 婧舵恫鍓�
鐢熸垚娌夋穩 J锛涘皣 J 閬�(gu貌)婵俱€佸彇鍑哄悗锛屽挤(qi谩ng)鐔卞張寰楀埌鍘熷寲鍚堢墿 A銆傚(xi臎)鍑� A~J 鐨勫寲瀛�(xu茅)寮�銆�
鍏嶈铂(z茅)鑱叉槑锛氭湰鏂囩郴杞�(zhu菐n)杓夎嚜缍�(w菐ng)绲�(lu貌)锛屽鏈変镜鐘紝璜�(q菒ng)鑱�(li谩n)绯绘垜鍊戠珛鍗冲埅闄�锛屽彟锛氭湰鏂囧儏浠ｈ〃浣滆€呭€�(g猫)浜鸿榛�(di菐n)锛岃垏鏈恫(w菐ng)绔欑劇(w煤)闂�(gu膩n)銆傚叾鍘熷壍(chu脿ng)鎬т互鍙婃枃涓櫝杩版枃瀛楀拰鍏�(n猫i)瀹规湭缍�(j墨ng)鏈珯璀夊(sh铆)锛屽皪(du矛)鏈枃浠ュ強鍏朵腑鍏ㄩ儴鎴栬€呴儴鍒嗗収(n猫i)瀹�銆佹枃瀛楃殑鐪熷(sh铆)鎬с€佸畬鏁存€�銆佸強鏅�(sh铆)鎬ф湰绔欎笉浣滀换浣曚繚璀夋垨鎵胯锛岃珛(q菒ng)璁€鑰呭儏浣滃弮鑰�锛屽苟璜�(q菒ng)鑷鏍稿(sh铆)鐩搁棞(gu膩n)鍏�(n猫i)瀹�銆�
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鏂囩珷鎼滅储
鎮ㄧ従(xi脿n)鍦ㄧ殑浣嶇疆锛� 
