鍙嬫儏鎻愮ず锛氭湰绔欐彁渚涘叏鍦�(gu贸)400澶氭墍楂樼瓑闄㈡牎鎷涙敹纰╁+銆佸崥澹爺绌剁敓鍏ュ(xu茅)鑰冭│姝峰勾鑰冪爺鐪熼銆佽€冨崥鐪熼銆佺瓟妗�锛岄儴鍒嗗(xu茅)鏍℃洿鏂拌嚦2012骞�锛�2013骞�锛涘潎鎻愪緵鏀惰不(f猫i)涓嬭級銆� 涓嬭級娴佺▼锛� 鑰冪爺鐪熼 榛�(di菐n)鎿娾€�鑰冪爺瑭﹀嵎鈥濃€濅笅杓�; 鑰冨崥鐪熼 榛�(di菐n)鎿娾€�鑰冨崥瑭﹀嵎搴�(k霉)鈥� 涓嬭級
2016骞村叏鍦�(gu贸)纰╁+鐮旂┒鐢熷叆瀛�(xu茅)鑰冭│鎷涚敓鍠綅鑷懡椤岃│鍗� A鍗� 810锛圓 鍗凤級绗� 1 闋�(y猫)锛屽叡 2 闋�(y猫) 瀹夊窘宸ユキ(y猫)澶у(xu茅) 2016 骞寸ⅸ澹爺绌剁敓鎷涚敓灏堟キ(y猫)鍩虹(ch菙)瑾茶│鍗凤紙A 鍗凤級 绉戠洰鍚嶇ū锛氱墿鐞嗗寲瀛�(xu茅) 绉戠洰浠g⒓锛� 810 婊垮垎锛� 150 鍒� 鑰冪敓璜�(q菒ng)娉ㄦ剰锛氭墍鏈夌瓟妗堝繀闋堝鍦ㄧ瓟椤岀礄涓�锛屽仛鍦ㄨ│椤岀礄鎴栬€呰崏绋跨礄涓婄殑涓€寰嬬劇(w煤)鏁堬紒 涓€銆佸晱(w猫n)绛旈锛�60 鍒�锛屾瘡灏忛 10 鍒嗭級 1銆佸弽鎳�(y墨ng) A(g)+2B(g)鈥斺啋C(g) 鐨勎� rHm(298.2K)锛�0锛屽墖姝ゅ弽鎳�(y墨ng)閫�(j矛n)琛屾檪(sh铆)蹇呭畾鍚哥啽锛屽皪(du矛)鍡�锛� 鐐轰粈涔�锛� 2銆�263K 鐨勯亷(gu貌)鍐锋按绲�(ji茅)鎴� 263K 鐨勫啺锛屛� S锛�0锛岃垏鐔靛鍔犲師鐞嗙浉鐭涚浘鍡�锛熺偤浠€涔堬紵 3銆佸皪(du矛)浜庝竴鍊�(g猫)绛夋韩绛夊涓嬬殑灏侀枆鍙嶆噳(y墨ng)楂旂郴锛屽洜鍏段� G锛�-RTLnK锛屾晠鍙嶆噳(y墨ng)楂旂郴鐨勬(bi膩o)婧�(zh菙n)鎱�(t脿i)鍗� 鏄钩琛℃厠(t脿i)锛岄€欏€�(g猫)姒傚康鏄惁姝g⒑锛熷鏋滈珨绯荤殑鎯呮硜鐐何� G 顙擄紳 0锛屽墖楂旂郴鏄惁鏄钩琛℃厠(t脿i)锛� 4銆佸偓鍖栧姂鐐轰粈涔堜笉鏈�(hu矛)鏀硅畩鍖栧(xu茅)骞宠 浣嶇疆? 5銆佸悓涓€鍙嶆噳(y墨ng)濡� Cu2锛� 锛媄n锛滳u锛媄n2锛� ,鍖栧(xu茅)鍙嶆噳(y墨ng)鐨勭啽鏁堟噳(y墨ng)鍜岄浕鍖栧(xu茅)鍙嶆噳(y墨ng)鐨勭啽鏁堟噳(y墨ng)鏄惁鐩� 鍚�? 鐐轰粈涔�? 6銆佸湪瑁濇湁閮ㄥ垎娑查珨鐨勬瘺绱�(x矛)绠′腑锛岀暥(d膩ng)涓€绔姞鐔辨檪(sh铆)锛屽鍦� 11锛�8 鎵€绀�锛�(a) 娼�(r霉n)婵曟€ф恫楂斿悜 姣涚窗(x矛)绠″摢涓€绔Щ鍕�(d貌ng)锛� (b) 涓嶆饯(r霉n)婵曟恫楂斿悜鍝竴绔Щ鍕�(d貌ng)锛熺偤浠€涔�锛� (a) (b) 浜�銆佽▓(j矛)绠楅锛�90 鍒嗭級 1銆侊紙15 鍒嗭級灏囩疆浜庡鍏�(n猫i)鐨勪竴闆诲啺绠辩殑绠遍杸鎵撻枊锛屼娇鍏惰嚧鍐锋(j墨)閬�(y霉n)杞�(zhu菐n)锛岃兘鍚﹂檷浣庡叏瀹ゆ韩搴�锛� 瑷�(sh猫)瑭叉(j墨)鍦� 0鈩冭垏瀹ゆ韩(25鈩�)浣滅悊鎯冲彲閫嗗惊鐠�(hu谩n)姣忓皬鏅�(sh铆)鑳藉噸鍑� 1Kg 鐨勫啺锛屽鎴块枔鐨勭附鐔卞鐐� 150KJ路K-1 锛屼及绠楅浕鍐扮宸ヤ綔 10 灏忔檪(sh铆)鍚庡鍏�(n猫i)婧害鐨勮畩鍖�锛熷凡鐭� 1 鍏嬫按鐨勬瘮鐔辩偤 4.184J路K-1 锛�1 鍏嬫按鐨勫嚌鍥虹啽鐐� 339 J路g-1 銆� 2銆侊紙15 鍒嗭級鍦ㄩ珮婧笅姘磋捀姘i€氶亷(gu貌)鐏肩啽鐨勭叅灞�锛屾寜涓嬪+鐢熸垚姘寸叅姘o細 C锛堢煶澧級+H2O(g) ? H2(g)+CO(g) 鑻ュ湪 1000K 鍙� 1200K 鏅�(sh铆)锛孠? 鍒嗗垾鐐� 2.505 鍙� 38.08锛岃│瑷�(j矛)绠楁婧害鑼冨湇鍏�(n猫i)骞冲潎鍙嶆噳(y墨ng)鐔� ?rHm 鍙婂湪 1100K 鏅�(sh铆)鍙嶆噳(y墨ng)鐨勬(bi膩o)婧�(zh菙n)骞宠 甯告暩(sh霉) K? 銆� 3銆侊紙20 鍒嗭級25?C 鏅�(sh铆)锛岄浕姹� Zn?ZnCl2(0.555mol路kg-1 )?AgCl(s)?Ag 鐨勯浕鍕�(d貌ng)鍕�(sh矛) E=1.015V銆� 宸茬煡 E? (Zn2+ ?Zn)=-0.7620V, E? {Cl-1 ?AgCl(s)?Ag?=0.2222V锛岄浕姹犻浕鍕�(d貌ng)鍕�(sh矛)鐨勬韩搴︾郴鏁�(sh霉) 14 1002.4)( ?? ???? ? ? KV T E p .瑷�(j矛)绠楋細 锛�1锛夊鍑洪浕姹犲弽鎳�(y墨ng)銆� 锛�2锛夎▓(j矛)绠楀弽鎳�(y墨ng)鐨勬(bi膩o)婧�(zh菙n)骞宠 甯告暩(sh霉) K? 銆� 锛�3锛夎▓(j矛)绠楅浕姹犲弽鎳�(y墨ng)鐨勫彲閫嗙啽 Qr锛宮銆� 2016骞村叏鍦�(gu贸)纰╁+鐮旂┒鐢熷叆瀛�(xu茅)鑰冭│鎷涚敓鍠綅鑷懡椤岃│鍗� A鍗� 810锛圓 鍗凤級绗� 2 闋�(y猫)锛屽叡 2 闋�(y猫) 锛�4锛夋眰婧舵恫涓� ZnCl2 鐨勫钩鍧囬洟瀛愭椿搴﹀洜瀛�??銆� 4.锛�20 鍒嗭級鍦ㄦ韩搴︾偤 298K銆�100kPa 澹撳姏涓�锛屽凡鐭� C锛堥噾鍓涚煶锛夊拰 C锛堢煶澧級鐨勬懇鐖剧喌銆� 鎽╃埦鐕冪噿鐒撳拰瀵嗗害鍒嗗垾鐐猴細 鐗╄唱(zh矛) Sm/(J路mol-1 路K-1 ) ?cHm/(kJ路mol-1 ) ?/(kg路m-3 ) C(閲戝墰鐭�) 2..45 -395.40 3513 C锛堢煶澧級 5.71 -393.51 2260 锛�1锛� 鍦� 298K 鍙� 100kPa 涓�锛岃│姹� C锛堢煶澧級?C锛堥噾鍓涚煶锛夌殑?trsGm ? ; 锛�2锛� 鍦� 298K 鍙� 100kPa 涓�锛屽摢鍊�(g猫)鏅堕珨鏇寸偤绌�(w臎n)瀹氾紵 锛�3锛夊鍔犲鍔涜兘鍚︿娇涓嶇┅(w臎n)瀹氱殑鏅堕珨鍚戠┅(w臎n)瀹氭櫠楂旇綁(zhu菐n)璁�锛熷鏋滃彲鑳斤紝鑷冲皯瑕佸姞澶氬ぇ鐨� 澹撳姏锛屾墠鑳藉(sh铆)鐝�(xi脿n)閫欑ó杞�(zhu菐n)鍖�锛� 5.锛�20 鍒嗭級鍦� 673K 鏅�(sh铆)锛岃ō(sh猫)鍙嶆噳(y墨ng) NO2锛坓锛�= NO(g)+1/2O2锛坓锛夊彲浠ラ€�(j矛n)琛屽畬鍏�锛屽苟瑷�(sh猫)鐢�(ch菐n) 鐗� 灏�(du矛) 鍙� 鎳�(y墨ng) 閫熺巼 鐒�(w煤) 褰� 闊匡紝 缍�(j墨ng) 瑭� 椹�(y脿n)璀� 鏄� 瑭� 鍙嶆噳(y墨ng) 鐐� 浜� 绱�(j铆)鍙� 鎳�(y墨ng) 锛� 閫熺巼 鏂� 绋� 鍙〃 绀� 鐐� 2 2 2 ][ ][ NOk dt NOd ?? 閫� 鐜� 甯� 鏁�(sh霉) k 鑸� 婧� 搴� T 涔� 闁� 鐨� 闂�(gu膩n) 绯� 鐐� 27.20 / 7.12886 )( ln 113 ? ? ? ?? ??? KTsdmmol k 瑭﹁▓(j矛)绠楋細锛�1锛夎┎鍙嶆噳(y墨ng)鐨勬寚鍓嶅洜瀛� A 鍙婅│椹�(y脿n)娲诲寲鑳� Ea锛� 锛�2锛夎嫢鍦� 673K 鏅�(sh铆)锛屽皣 NO2锛坓锛夐€氬叆鍙嶆噳(y墨ng)鍣紝浣垮叾澹撳姏鐐� 26.66kPa锛岀劧鍚庣櫦(f膩) 鐢熶笂杩板弽鎳�(y墨ng)锛岀暥(d膩ng)鍙嶆噳(y墨ng)鍣ㄤ腑鐨勫鍔涢仈(d谩)鍒� 32.0kPa 鏅�(sh铆)鎵€闇€鐨勬檪(sh铆)闁擄紙瑷�(sh猫)姘i珨鐐虹悊鎯虫埃楂旓級 锛堣│椤屽畬锛�
鍏嶈铂(z茅)鑱叉槑锛氭湰鏂囩郴杞�(zhu菐n)杓夎嚜缍�(w菐ng)绲�(lu貌)锛屽鏈変镜鐘�锛岃珛(q菒ng)鑱�(li谩n)绯绘垜鍊戠珛鍗冲埅闄�锛屽彟锛氭湰鏂囧儏浠h〃浣滆€呭€�(g猫)浜鸿榛�(di菐n)锛岃垏鏈恫(w菐ng)绔欑劇(w煤)闂�(gu膩n)銆傚叾鍘熷壍(chu脿ng)鎬т互鍙婃枃涓櫝杩版枃瀛楀拰鍏�(n猫i)瀹规湭缍�(j墨ng)鏈珯璀夊(sh铆)锛屽皪(du矛)鏈枃浠ュ強鍏朵腑鍏ㄩ儴鎴栬€呴儴鍒嗗収(n猫i)瀹�銆佹枃瀛楃殑鐪熷(sh铆)鎬�銆佸畬鏁存€�銆佸強鏅�(sh铆)鎬ф湰绔欎笉浣滀换浣曚繚璀夋垨鎵胯锛岃珛(q菒ng)璁€鑰呭儏浣滃弮鑰�锛屽苟璜�(q菒ng)鑷鏍稿(sh铆)鐩搁棞(gu膩n)鍏�(n猫i)瀹广€�
|