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鍙嬫儏鎻愮ず锛氭湰绔欐彁渚涘叏鍦�400澶氭墍楂樼瓑闄㈡牎鎷涙敹纰╁＋銆佸崥澹爺绌剁敓鍏ュ(xu茅)鑰冭│姝峰勾鑰冪爺鐪熼銆佽€冨崥鐪熼銆佺瓟妗�锛岄儴鍒嗗(xu茅)鏍℃洿鏂拌嚦2012骞达紝2013骞�锛涘潎鎻愪緵鏀惰不涓嬭級銆� 涓嬭級娴佺▼锛� 鑰冪爺鐪熼 榛炴搳鈥�鑰冪爺瑭﹀嵎鈥濃€濅笅杓�; 鑰冨崥鐪熼 榛炴搳鈥�鑰冨崥瑭﹀嵎搴�鈥� 涓嬭級

2018 骞寸ⅸ澹爺绌剁敓鎷涚敓鍏ュ(xu茅)鑰冭│瑭﹂
绉戠洰浠ｇ⒓鍙婂悕绋�:627 鏈夋鍖栧(xu茅) II 閬╃敤灏堟キ(y猫)锛氬寲瀛�(xu茅)鐢熺墿瀛�(xu茅)
锛堣珛鑰冪敓鍦ㄧ瓟椤岀礄涓婄瓟椤岋紝鍦ㄦ瑭﹂绱欎笂绛旈鐒℃晥锛�
涓€銆佸鍑轰笅鍒楀寲鍚堢墿鐨勭祼(ji茅)妲�(g貌u)寮忔垨绯荤当(t菕ng)鍛藉悕涓嬪垪鍖栧悎鐗╋紙姣忛 2 鍒�锛屽叡 20 鍒嗭級
1. 3-涔欏熀-6-婧�-2-宸辩儻-1-閱�
2. 4锛嶇挵(hu谩n)涓欏熀鑻敳閰�
3. 涔欑儻鍩轰箼鐐�
4. 鑻箼閰拌兒
5. 2锛嶇敳鍩猴紞锛擄紞婧翠竵鐑�
6.
7.
8.
9.
10.
绗� 1 闋侊紝鍏� 7 闋�
a.
C=C
H3C
H
CH 2CH 2OH
H
b. CH 3CHCH 2OH
Br
c. CH3CH-Ch2CH2-CHCH2CH3
OH OH
d. C6H5CHCH 2CHCH 3
CH 3 OH
e.
CH 3
OH
f. CH 3OCH 2CH 2OCH 3
g.
O
CH 3
h.
H
C CH 3
OH
i.
OH
j.
OH
O p. C
O
H-Ch2CH2-CHCH2CH3
H OH
H 3
g.
O
CH 3
b. CH 2CHO c. H3C CHO d. (CH 3)2CHCOCH 3
3)2
f.
CHO
O H3C
g. (CH3)2C=CHCHO h. 尾锛� 婧� 鍖� 涓� 閱�
a.
C=C
H3C
H
CH 2CH 2OH
H
b. CH 3CHCH 2OH
Br
c. CH3CH-Ch2CH2-CHCH2CH3
OH OH
d. C6H5CHCH 2CHCH 3
CH 3 OH
e.
CH 3
OH
f. CH 3OCH 2CH 2OCH 3
g.
O
CH 3
h.
H
C CH 3
OH
i.
OH
CH 3
j.
OH
NO 2
浜�銆侀伕鎿囬锛堟瘡灏忛鏈夎嫢骞插€嬮伕闋咃紝璜嬮伕鍑烘纰虹殑涓€鍊�锛屾瘡椤� 2 鍒�锛屽叡 40 鍒嗭級
1. 灏� CH3Br 閫茶瑕牳鍙栦唬鏅�锛屼互涓嬮洟瀛愯Κ鏍告€ф渶寮风殑鏄細锛� 锛�
(A). CH3COO
-
(B). CH3CH2O
-
(C). C6H5O
-
(D). OH
-
2. 涓嬪垪鍖栧悎鐗╀腑閰告€ф渶寮风殑鏄紙锛�
A. CH3CH2OH B. p-O2NC6H4OH
C. C6H5OH D. p-CH3C6H4OH
3. 鎸囧嚭涓嬪垪鍖栧悎鐗╃殑鐩稿皪闂�(gu膩n)绯伙紙锛�
CO OH
H
CH3
CH2CH3
COO H
H3C
CH2CH3
H
A. 鐩稿悓 B.灏嶆槧鐣版(g貌u) C. 闈炲皪鏄犻珨 D.娌掗棞(gu膩n)绯�
4. 涓嬪垪鍙嶆噳(y墨ng)鐨勮綁(zhu菐n)鍖栭亷绋嬬稉(j墨ng)姝蜂簡( )
C=CHCH 2CH 2CH 2CH=C
H3C
H3C
CH 3
CH 3
H
+
C=C
H3C
H3C
C CH 2
CH 2
H2C C
H2
H3C CH 3
A.瑕浕鍙栦唬 B.瑕牳鍔犳垚
C.姝ｇ⒊闆㈠瓙閲嶆帓 D.鍙嶅紡娑堥櫎
5. 涓嬪垪鍖栧悎鐗╁牽鎬ф渶澶х殑鏄紙锛�
A. 姘� B. 涔欒兒 C. 鑻兒 D. 涓夎嫰鑳�
6. 鑳借垏鎵樺€ │鍔戝弽鎳�(y墨ng)鐢�(ch菐n)鐢熼妧閺＄殑鏄�( )
A. CCl3COOH B. CH3COOH C. CH2ClCOOH D. HCOOH
绗� 2 闋�锛屽叡 7 闋�
7. 鑸� NaOH 姘存憾娑茬殑鍙嶆噳(y墨ng)娲绘€ф渶寮风殑鏄紙锛�
A. CH3CH2COCH2Br B. CH3CH2CHCH2Br C. (CH3)3CH2Br D. CH3(CH2)2CH2Br
CH3
8.涓嬪垪鍝ó鐗╄唱(zh矛)涓嶈兘鐢ㄤ締鍘婚櫎涔欓啔涓殑閬庢哀鍖栫墿锛� 锛�
A. KI B. 纭吀浜為惖 C. 浜炵～閰搁垑 D. 闆欐哀姘�
9. 涓嬪垪鍖栧悎鐗╀笉鐧�(f膩)鐢熺浠垮弽鎳�(y墨ng)鐨勬槸( )
A. C6H5COCH3 B. C2H5OH
C. CH3CH2COCH2CH3 D. CH3COCH2CH3
10锛庝笉鑸囪嫰閰氬弽鎳�(y墨ng)鐨勬槸( )
A. Na B. NaHCO3
C. FeCl3 D. Br2
11. 涓嬪垪鍖栧悎鐗╀腑鍏锋湁鑺抽鎬х殑鏄紙锛�
12. 浠ヤ笅骞剧ó鍖栧悎鐗╀腑閰告€ф渶寮风殑鏄紙锛�
A. 涔欓唶 B. 姘� C. 纰抽吀 D. 鑻厷
13. 鑸� HNO2 浣滅敤娌掓湁 N2 鐢熸垚鐨勬槸( )
A. H2NCONH2 B. CH3CH锛圢H2锛塁OOH C. C6H5NHCH3
D. C6H5NH2
14.涓嬪垪鍝€嬪寲鍚堢墿涓嶅爆浜庣鍩哄寲鍚堢墿锛� 锛�
A. B. C. D.
15. 涓嬪垪涓嶆槸闁撲綅瀹氫綅鍩虹殑鏄紙锛�
A.-SO3H B. 鈥揅OOH C. -CH3 D. -CHO
绗� 3 闋�锛屽叡 7 闋�
A
O
O
O
O
N
H
B C D
CH 3
NO 2
NO 2
CH 3
CH 3
CH 2
NO 2
CH 3
ONO 2
16. SN1 鍙嶆噳(y墨ng)鐨勭壒寰佹槸锛�(鈪�)鐢熸垚姝ｇ⒊闆㈠瓙涓枔楂旓紱(鈪�)绔嬮珨鍖栧(xu茅)鐧�(f膩)鐢熸(g貌u)鍨嬬炕杞�(zhu菐n)锛�(鈪�)鍙嶆噳(y墨ng)
閫熺巼鍙楀弽鎳�(y墨ng)鐗╂績搴﹀拰瑕牳瑭﹀姂婵冨害鐨勫奖闊�锛涳紙鈪ｏ級鍙嶆噳(y墨ng)鐢�(ch菐n)鐗╃偤澶栨秷鏃嬫贩鍚堢墿锛� 锛�
A. I銆両I B. III銆両V C. I銆両V D. II銆両V
17锛庝笅鍒楀寲鍚堢墿鑸� NaOH 涔欓唶婧舵恫鐧�(f膩)鐢� SN1 瑕牳鍙栦唬鍙嶆噳(y墨ng)閫熷害鏈€蹇殑鏄紙锛�
18锛庝笅鍒楀寲鍚堢墿鍏锋湁鎵嬫€х殑鏄摢涓€鍊嬶紙锛�
19锛庡▉寤夊妫悎鎴愭硶鍙敤浜庡悎鎴愶紙锛�
A. 楣典唬鐑� B. 娣峰悎閱� C. 浼兒 D. 楂樼礆鑴傝偑閰�
20锛庣敳鑻湪鍏夌収涓嬫捍鍖栧弽鎳�(y墨ng)姝风▼鐐猴紙锛�
A. 鑷敱鍩哄彇浠ｅ弽鎳�(y墨ng) B. 瑕浕鍙栦唬
C. 瑕牳鍙栦唬 D. 瑕浕鍔犳垚
绗� 4 闋�锛屽叡 7 闋�
涓�銆佹槸闈炲垽鏂烽锛堢敤鈥溾垰鈥濊〃绀哄皪锛岀敤鈥溍椻€濊〃绀洪尟, 姣忛 1 鍒�锛屽叡 10 鍒嗭級
1. 鐢变簬鐑兇鍏锋湁涓嶉＝鍜岄嵉锛屽叾涓€ 閸靛鏄撴柗瑁傦紝琛ㄧ従(xi脿n)鍑烘椿娼戠殑鍖栧(xu茅)鎬ц唱(zh矛)锛屽洜姝�
鍏惰姣旂浉鎳�(y墨ng)鐑风兇鎬ц唱(zh矛)娲绘綉銆� 锛� 锛�
2. 鍑℃槸鑳借垏瀹冪殑閺¤薄閲嶅悎鐨勫垎瀛愶紝灏变笉鏄墜鎬у垎瀛�锛屽氨娌掓湁鏃嬪厜鎬�銆傦紙锛�
3. 閱涢叜鍖栧(xu茅)鎬ц唱(zh矛)姣旇純娲绘綉锛岄兘鑳借姘у寲鍔戞哀鍖栨垚鐩告噳(y墨ng)鐨勭晶閰�銆傦紙锛�
4. 鐢变簬鐑兇鍏锋湁涓嶉＝鍜岄嵉锛屽叾涓€ 閸靛鏄撴柗瑁傦紝琛ㄧ従(xi脿n)鍑烘椿娼戠殑鍖栧(xu茅)鎬ц唱(zh矛)锛屽洜姝ゅ叾瑕佹瘮鐩告噳(y墨ng)
鐑风兇鎬ц唱(zh矛)娲绘綉銆� 锛� 锛�
5. 鍙鍚湁伪姘殑閱涙垨鑰呴叜鍧囪兘澶犵櫦(f膩)鐢熺浠垮弽鎳�(y墨ng)銆傦紙锛�
6. 鑴傜挵(hu谩n)鐑翠腑涓夊厓鐠�(hu谩n)寮靛姏寰堝ぇ锛屾瘮杓冨鏄撴柗瑁�锛屽鏄撶櫦(f膩)鐢熷寲瀛�(xu茅)鍙嶆噳(y墨ng)锛岄€氬父姣斿叾浠栧ぇ鐠�(hu谩n)娲绘綉浜涖€�
锛� 锛�
7. 鐠�(hu谩n)宸辩兎閫氬父绌�(w臎n)瀹氱殑妲�(g貌u)璞℃槸鑸瑰紡妲�(g貌u)璞�銆傦紙锛�
8. 鍒嗗瓙妲�(g貌u)閫犵浉鍚岀殑鍖栧悎鐗╀竴瀹氭槸鍚屼竴鐗╄唱(zh矛)銆傦紙锛�
9. 鍚墜鎬х⒊鍘熷瓙鐨勫寲鍚堢墿閮藉叿鏈夋棆鍏夋€�銆傦紙锛�
10. 鍚爱鏈夋鍖栧悎鐗╅兘鍏锋湁鍫挎€с€傦紙锛�
涓�銆佸畬鎴愪笅鍒楀弽鎳�(y墨ng)寮�锛屽鍑虹敘(ch菐n)鐗╂垨鎵€闇€瑭﹀姂锛堟瘡椤� 3 鍒�锛屽叡 45锛�
1.
2.
3.
4.
5.
绗� 5 闋�锛屽叡 7 闋�
d. CH3CH2CH=CH2
CH 3CH 2CH-CH 3
OH
e. (CH3)2C=CHCH2CH3
O 3
Zn H2O,
f. CH2=CHCH2O H ClCH 2CH-CH 2OH
OH
a. (CH 3)2CHCH 2CH 2OH + HBr
b.
OH + HCl
鐒� 姘� ZnCl2
c.
OCH 3
CH 2CH 2OCH 3
+ HI (閬� 閲� )
d.
O CH 3
+ HI (閬� 閲� )
e. (CH 3)2CHBr + NaOC 2H5
f. CH 3(CH 2)3CHCH 3
OH
KMnO 4
O H
锛�
g.
HIO 4
CH3CO O H + CH 3CH 2CHO
h. HIO 4
CH 3COCH 2CH 2CHO
i.
OH
CH 3
+ Br 2
a. CH 3COCH 2CH 3 + H2N锛� O H
b. Cl 3CCHO + H2O
c. H3C CHO + KMnO 4
H
+
d. CH 3CH 2CHO 绋€ NaOH
e. C6H5COCH 3 + C6H5MgBr
H
+
H2O
f. O + H2NNHC 6H5
g. (CH 3)3CCHO 婵� NaOH
h.
O
+ (CH 3)2C(CH 2OH) 2
鐒� 姘� HClO
i. + K2Cr2O 7
H
+
j. CH 3(CH 2)2CH
OH
CH 2CH 3
婵�
鍒� 瀛� 鍏�(n猫i) 鑴� 姘�
H2SO 4
k. C
O
Cl 2 , H2O
O H
锛�
C
O
CH 2Cl
CH 3 COOH + CHCl 3
l. C
O
CH 3 + Cl 2
H
+
m. CH2=CHCH2CH2CO CH3 + HCl CH 3-CHCH 2CH 2COCH 3
Cl
+
Cl OH
CH
n. CH2=CHCO CH3 + HBr BrCH 2CH 2COCH 3
o. CH2=CHCHO + HCN NCCH 2CH 2CHO + CH2=CHCH
OH
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
绗� 6 闋�锛屽叡 7 闋�
a. (CH 3)2CHCH 2CH 2OH + HBr
b.
OH + HCl
鐒� 姘� ZnCl2
c.
OCH 3
CH 2CH 2OCH 3
+ HI (閬� 閲� )
d.
O CH 3
+ HI (閬� 閲� )
e. (CH 3)2CHBr + NaOC 2H5
f. CH 3(CH 2)3CHCH 3
OH
KMnO 4
O H
锛�
g.
HIO 4
CH3CO O H + CH 3CH 2CHO
k. C
O
Cl 2 , H 2O
O H
锛�
CH 3
l. C
O
CH 3 + Cl 2
H
+
d. CH3CH2CH=CH2
CH 3CH 2CH-CH 3
OH
e. (CH3)2C=CHCH2CH3
O 3
Zn H2O,
f. CH2=CHCH2O H ClCH 2CH-CH 2OH
OH
a. CH 3COCH 2CH 3 + H2N锛� O H
b. Cl 3CCHO + H2O
c. H3C CHO + KMnO 4
H
+
d. CH 3CH 2CHO 绋€ NaOH
e. C6H5COCH 3 + C6H5MgBr
H
+
H2O
f. O + H2NNHC 6H5
g. (CH 3)3CCHO 婵� NaOH
h.
O
+ (CH 3)2C(CH 2OH) 2
鐒� 姘� HClO
i. + K2Cr2O 7
H
+
j. CHO
KMnO 4
瀹� 婧�
n. CH2=CHCO CH3 + HBr
o. CH2=CHCHO + HCN
p. C6H5CHO + CH 3COCH 3
绋€ NaOH
n. CH2=CHCO CH3 + HBr
o. CH2=CHCHO + HCN
p. C6H5CHO + CH 3COCH 3
绋€ NaOH
f.
Zn锛� powder , H2O
g.
CH 3
H2SO 4
H2O ,
h.
+ CH 2Cl 2
AlCl 3
i.
CH 3
+ HNO 3
j. + KMnO 4
H
+
k.
CH=CH 2
+ Cl 2
a. (CH 3)2CHCH 2CH 2OH + HBr
b.
OH + HCl
鐒� 姘� ZnCl2
c.
OCH 3
CH 2CH 2OCH 3
+ HI (閬� 閲� )
d.
O CH 3
+ HI (閬� 閲� )
e. (CH 3)2CHBr + NaOC 2H5
f. CH 3(CH 2)3CHCH 3
OH
KMnO 4
O H
锛�
g.
HIO 4
CH3CO O H + CH 3CH 2CHO
h. HIO 4
CH 3COCH 2CH 2CHO
i.
OH
CH 3
+ Br 2
a. CH 3COCH 2CH 3 + H2N锛� O H
b. Cl 3CCHO + H2O
c. H3C CHO + KMnO 4
H
+
d. CH 3CH 2CHO 绋€ NaOH
e. C6H5COCH 3 + C6H5MgBr
H
+
H2O
f. O + H2NNHC 6H5
g. (CH 3)3CCHO 婵� NaOH
h.
O
+ (CH 3)2C(CH 2OH) 2
鐒� 姘� HClO
i. + K2Cr2O 7
H
+
j. CHO
KMnO 4
瀹� 婧�
a.
CH 3
HBr
b. + Cl 2
楂� 婧�
c. + Cl 2
d.
CH 2CH 3
+ Br 2
FeBr 3
e.
CH(CH 3)2
+ Cl 2
楂� 婧�
f.
CH 3
O 3
Zn锛� powder , H2O
g.
CH 3
H2SO 4
H2O ,
h.
+ CH 2Cl 2
AlCl 3
i.
CH 3
+ HNO 3
j. + KMnO 4
H
+
k.
CH=CH 2
+ Cl 2
鍥涖€侀憭鍒ヨ垏鎺ㄦ柗椤岋紙鍏� 35 鍒嗭級
1. 鏌愬厜瀛�(xu茅)娲绘€у寲鍚堢墿 A(C12H16O)绱呭鍏夎瓬鍦栦腑鍦� 3000-3500 cm-1
鏈変竴鍊嬪挤鍚告敹宄�锛屽湪 1580
鍜� 1500 cm-1
铏曞垎鍒ユ湁涓瓑寮峰害鐨勫惛鏀跺嘲锛岃┎鍖栧悎鐗╀笉鑸� 2,4 涓€浜岀鍩鸿嫰鑲煎弽鎳�(y墨ng)锛屼絾鐢�
I2/NaOH 铏曠悊锛孉琚哀鍖�锛岀櫦(f膩)鐢熺浠垮弽鎳�(y墨ng)銆侫缍�(j墨ng)鑷哀鍖栧弽鎳�(y墨ng)閭勫師姘磋В寰楀埌 B(C9H10)鍜�
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鏋溿€侭缍�(j墨ng)纭濆寲锛圚NO3/H2SO4锛夊彲寰楀埌鍏╁€嬩竴纭濆寲鍚堢墿 D 鍜� E銆備絾瀵﹂殯涓婂嵒鍙緱鍒� D銆傚皣 C
鍜� Tollens 瑭﹀姂鍙嶆噳(y墨ng)鐨勭敘(ch菐n)鐗╅吀鍖栧悗鍔犵啽锛屽緱鍒� F(C6H8O4)銆傝┎鍖栧悎鐗╃殑绱呭鍏夎瓬鍦栦腑鍦� 3100
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2. 鍒嗗瓙寮忕偤 C5H10 鐨勫寲鍚堢墿 A锛岃垏 1 鍒嗗瓙姘綔鐢ㄥ緱鍒� C5H12 鐨勫寲鍚堢墿銆侫鍦ㄩ吀鎬ф憾娑蹭腑鑸�
楂橀尦閰搁墍浣滅敤寰楀埌涓€鍊嬪惈鏈� 4 鍊嬬⒊鍘熷瓙鐨勭晶閰�銆侫缍�(j墨ng)鑷哀鍖栧苟閭勫師姘磋В锛屽緱鍒板叐绋笉鍚岀殑
閱�銆傛帹娓� A 鐨勫彲鑳界祼(ji茅)妲�(g貌u)锛岀敤鍙嶆噳(y墨ng)寮忓姞绨¤瑾槑琛ㄧず鎺ㄦ柗閬庣▼銆傦紙4 鍒嗭級
3. 鍒嗗瓙寮忕偤 C5H12O 鐨� A锛屾哀鍖栧悗寰� B锛圕5H10O锛�锛孊鑳借垏 2,4-浜岀鍩鸿嫰鑲煎弽鎳�(y墨ng)锛屽苟鍦ㄨ垏纰�
鐨勫牽婧舵恫鍏辩啽鏅傜敓鎴愰粌鑹叉矇娣€銆侫鑸囨績纭吀鍏辩啽寰� C锛圕5H10锛�锛孋缍�(j墨ng)楂橀尦閰搁墍姘у寲寰椾笝閰�
鍙婁箼閰�銆傛帹鏂� A銆丅銆丆鐨勭祼(ji茅)妲�(g貌u)锛屽苟瀵嚭鎺ㄦ柗閬庣▼鐨勫弽鎳�(y墨ng)寮忋€傦紙5 鍒嗭級
4. 鍒嗗瓙寮忕偤 C6H12O 鐨� A锛岃兘鑸囪嫰鑲间綔鐢ㄤ絾涓嶇櫦(f膩)鐢熼妧閺″弽鎳�(y墨ng)銆侫缍�(j墨ng)鍌寲姘寲寰楀垎瀛愬紡鐐�
C6H14O 鐨� B锛孊鑸囨績纭吀鍏辩啽寰� C锛圕6H12锛�銆侰缍�(j墨ng)鑷哀鍖栧苟姘磋В寰� D 鍜� E銆侱鑳界櫦(f膩)鐢熼妧閺�
鍙嶆噳(y墨ng)锛屼絾涓嶈捣纰樹豢鍙嶆噳(y墨ng)锛岃€� E 鍓囧彲鐧�(f膩)鐢熺浠垮弽鎳�(y墨ng)鑰岀劇閵€閺″弽鎳�(y墨ng)銆傚鍑� A-E 鐨勭祼(ji茅)妲�(g貌u)寮忓強鍚勬
鍙嶆噳(y墨ng)寮�銆傦紙10 鍒嗭級
5. 鍒嗗瓙寮忕偤 C6H10 鐨� A 鍙� B锛屽潎鑳戒娇婧寸殑鍥涙隘鍖栫⒊婧舵恫瑜壊锛屽苟涓旂稉(j墨ng)鍌寲姘寲寰楀埌鐩稿悓鐨�
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鍙嶆噳(y墨ng)寮忓姞绨¤瑾槑琛ㄧず鎺ㄦ柗閬庣▼銆傦紙4 鍒嗭級
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