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2018 骞村ぇ閫ｅ伐妤�(y猫)澶у纰╁＋鐮旂┒鐢熷叆瀛歌€冭│澶х侗
鏈夋鍖栧纰╁＋鐮旂┒鐢熷叆瀛歌€冭│澶х侗
鏈夋鍖栧鏄ぇ閫ｅ伐妤�(y猫)澶у鍖栧锛堢悊瀛革級鐮旂┒鐢熷叆瀛歌€冭│绉戠洰涔嬩竴锛岀偤渚夸簬鑰冪敓寰�
缈掑拰鑰冭│姝ょ鐩�锛屽埗瀹氳€冭│澶х侗渚涘鐢熷弮鑰�銆傛湁姗熷寲瀛告槸瑷卞瀛哥灏堟キ(y猫)鐨勫熀绀庤
绋�锛岃姹傝€冪敓灏嶅叾鍩烘湰姒傚康銆佸熀鏈悊璜栨湁杓冩繁鍏ョ殑鐞嗚В銆傛闁€瑾茬▼瀛哥繏鐐洪亱鐢ㄥ熀
鏈悊璜栧皪鏈夋鍖栧悎鐗╅€茶鍚堟垚瑷▓銆佺祼(ji茅)妲�(g貌u)鑸囨噳鐢ㄦ€ц唱(zh矛)闂�(gu膩n)绯昏ō瑷堢瓑瀵﹂殯瑾查鎵撲笅鍩�
绀�銆�
涓€銆佽€冭│鍏�(n猫i)瀹�
1銆佹湁姗熷寲鍚堢墿鐨勫懡鍚嶅拰鐗╃悊鎬ц唱(zh矛)
锛�1锛夋湁姗熷寲鍚堢墿鐨勬櫘閫氬懡鍚嶅強鍦嬮殯 IUPAC 鍛藉悕鍘熷墖鍜屼腑鍦嬪寲瀛告渻鍛藉悕鍘熷墖鑸囧懡
鍚嶆柟娉�銆�
锛�2锛夋湁姗熷寲鍚堢墿鐨勭祼(ji茅)妲�(g貌u)鑸囩墿鐞嗘€ц唱(zh矛)闂�(gu膩n)绯�
2銆佹湁姗熷寲瀛稿弽鎳�
锛�1锛夋湁姗熷寲鍚堢墿涓噸瑕佸畼鑳藉湗鐨勭稉(j墨ng)鍏稿弽鎳夊強鐩镐簰杞�(zhu菐n)鎻涙柟娉�
閲嶈瀹樿兘鍦樺寲鍚堢墿锛氱兎鐑�銆佺儻鐑�銆佷簩鐑兇銆佺倲鐑�銆侀沟浠ｇ兇銆佽姵鐑�銆侀唶銆侀厷銆�
閱氥€侀啗銆侀叜銆侀唽銆佺晶閰稿強鍏惰鐢熺墿銆佽兒鍙婂叾浠栧惈姘寲鍚堢墿銆佺啊鍠殑闆滅挵(hu谩n)楂旂郴銆佺硸
椤�銆佹皑鍩洪吀鍜岃泲鐧借唱(zh矛)銆�
锛�2锛夐噸瑕佺殑鏈夋鍙嶆噳锛氬彇浠ｅ弽鎳�銆佸姞鎴愬弽鎳�銆佹秷闄ゅ弽鎳�銆佺府鍚堝弽鎳�銆佹哀鍖栭倓鍘�
鍙嶆噳銆侀噸鎺掑弽鎳夈€佽嚜鐢卞熀鍙嶆噳銆佸懆鐠�(hu谩n)鍙嶆噳銆�
3銆佹湁姗熷寲瀛稿熀鏈悊璜栧拰鍙嶆噳姗熺悊
锛�1锛夎獦灏庢晥鎳夈€佸叡杌涙晥鎳�銆佽秴鍏辫粵鏁堟噳銆佺珛楂旀晥鎳�
锛�2锛夌⒊姝ｉ洟瀛�銆佺⒊璨犻洟瀛愩€佺⒊鑷敱鍩�銆佸崱璩撱€佽嫰鐐旂瓑娲绘€т腑闁撻珨
锛�3锛夊叡鎸珫绨′粙鍙婄浉闂�(gu膩n)姒傚康
锛�4锛夋湁姗熷弽鎳夋鐞嗙殑琛ㄩ仈
4銆佹湁姗熷悎鎴�
锛�1锛夊畼鑳藉湗灏庡叆銆佽綁(zhu菐n)鎻�銆佷繚璀�
锛�2锛夌⒊-纰抽嵉褰㈡垚鍙婃柗瑁傜殑鍩烘湰鏂规硶
锛�3锛夐€嗗悜鍚堟垚鍒嗘瀽鐨勫熀鏈榛炲強鍏跺湪鏈夋鍚堟垚涓殑鎳夌敤
5銆佹湁姗熺珛楂斿寲瀛�
锛�1锛夊咕浣曠暟妲�(g貌u)銆佸皪鏄犵暟妲�(g貌u)銆佹(g貌u)璞＄暟妲�(g貌u)绛夌珛楂斿寲瀛哥殑鍩烘湰姒傚康
锛�2锛夊皪鏄犻珨楂旂殑鎷嗗垎鏂规硶銆佺啊鍠笉灏嶇ū鍚堟垚
锛�3锛夊彇浠ｃ€佸姞鎴�銆佹秷闄�銆侀噸鎺�銆佸懆鐠�(hu谩n)绛夊弽鎳夌殑绔嬮珨鍖栧
2
6銆侀洔鐠�(hu谩n)鍖栧悎鐗�
鍚� N 锛� S 锛� O 绛夌殑浜�銆佸叚鍏冮洔鐠�(hu谩n)鍖栧悎鐗┿€佸強鍏朵粬绲�(ji茅)妲�(g貌u)鐨勬湁姗熺～銆佺７銆佺
鍖栧悎鐗╃殑鍛藉悕銆佺祼(ji茅)妲�(g貌u)鍜屾€ц唱(zh矛)銆傜啊鍠闆滅挵(hu谩n)鍖栧悎鐗╃殑鍛藉悕銆佸悎鎴愯垏鍖栧鎬ц唱(zh矛)銆�
7 銆佺⒊姘村寲鍚堢墿銆佹补鑴�銆佹皑鍩洪吀銆佽泲鐧借唱(zh矛)銆佽悳椤�銆佺斁鏃忕瓑澶╃劧鐢�(ch菐n)鐗╃殑绲�(ji茅)妲�(g貌u)銆佹€�
璩�(zh矛)鍜岀敤閫�
8銆佹湁姗熷寲鍚堢墿鐨勫父鐢ㄧ殑鍖栧銆佺墿鐞嗛憭瀹氭柟娉�
锛�1锛夊父瑕嬪畼鑳藉湗鐨勭壒寰佸寲瀛搁憭鍒ユ柟娉�
锛�2锛夊父瑕嬫湁姗熷寲鍚堢墿鐨勬牳纾佸叡鎸瓬銆佺磪澶栧厜璀溿€佺传澶栧厜璀�銆佸拰璩�(zh矛)璀滅殑璀滃鐗瑰緛
锛�3锛夐亱鐢ㄤ互涓婃柟娉曞皪绨″柈鏈夋鍖栧悎鐗╅€茶绲�(ji茅)妲�(g貌u)閼掑畾
浜屻€佽€冭│瑕佹眰锛堝悇绔犵瘈(ji茅)鐨勫叿楂斿収(n猫i)瀹癸級
绗竴绔犵窉璜�
1.1 姗熷寲鍚堢墿鐨勬兜缇�銆佹湁姗熷寲瀛稿強鍏剁櫦(f膩)灞曠啊鍙�銆佹湁姗熷寲瀛哥殑閲嶈鎬�
1.2 鐔熸倝骞舵帉鎻℃湁姗熷寲鍚堢墿鐨勭祼(ji茅)妲�(g貌u)鑸囩壒鎬�
1.2.1 鍏卞児閸电殑鏈唱(zh矛)锛堝児閸垫硶銆佸垎瀛愯粚閬撴硶銆佸叡鎸珫锛�
1.2.2 鍏卞児閸电殑涓昏鍙冩暩(sh霉)锛氶嵉闀�銆侀嵉瑙�銆侀嵉鑳姐€佸厓绱犵殑闆昏矤鎬у拰閸电殑妤垫€�
1.2.3 鏈夋鍖栧悎鐗╃殑鐗规€э細鐗╃悊鐗规€�銆佺珛楂旂暟妲�(g貌u)銆佸畼鑳藉湗鐣版(g貌u)銆佸悓鍒嗙暟妲�(g貌u)鐝�(xi脿n)璞�銆�
妲�(g貌u)鍨嬭垏妲�(g貌u)璞�
1.2.4 鍏卞児閸垫柗瑁傛柟寮忓拰鏈夋鍙嶆噳椤炲瀷
1.2.5 鏈夋鍖栧悎鐗╃殑閰稿牽姒傚康
绗簩绔犵兎鐑村拰鐠�(hu谩n)鐑风兇
2.1 鐑风兇鐨勫垎椤�銆佸懡鍚�銆佺祼(ji茅)妲�(g貌u)銆佸悓绯诲垪鍜屽悓鍒嗙暟妲�(g貌u)鐝�(xi脿n)璞�锛涚兎鐑寸殑绲�(ji茅)妲�(g貌u)锛氱⒊鍘熷瓙鐨�
SP3 闆滃寲銆佄� 閸靛舰鎴愶紙妲�(g貌u)鍨嬫蹇碉級
2.2 鐑风兇鐨勯噸瑕佺墿鐞嗘€ц唱(zh矛)锛氱啍榛�銆佹哺榛炪€佸瘑搴�銆佹憾瑙ｅ害銆佹姌鍏夌巼
鍒嗗瓙绲�(ji茅)妲�(g貌u)灏嶇墿鐞嗗寲瀛告€ц唱(zh矛)鐨勫奖闊�銆�
2.3 鐑风兇鐨勫弽鎳�
鐑风兇鐨勯沟浠ｅ弽鎳夋绋嬨€佹父闆㈠熀銆侀€ｉ帠鍙嶆噳銆佽兘閲忔洸绶�銆侀亷娓＄媭鎱�(t脿i)銆佹父闆㈠熀鐨勭┅(w臎n)瀹�
鎬у拰楣典唬鍙嶆噳鐨勫彇鍚�銆�
2.4 鐠�(hu谩n)鐑风兇鍛藉悕鍙婂寲瀛告€ц唱(zh矛)
灏忕挵(hu谩n)鐑风兇鐨勫嫉鍔涖€佺┅(w臎n)瀹氭€ц垏鍩烘湰鍙嶆噳锛�
2.5 鐑风兇鐨勬(g貌u)璞�
涔欑兎鍜屼竵鐑风殑妲�(g貌u)璞�锛涚挵(hu谩n)宸辩兎鐨勬(g貌u)璞★紙妞呭紡/鑸瑰紡妲�(g貌u)鍨�銆佸彇浠ｇ挵(hu谩n)宸茬兎鍜屽崄姘寲
钀樼殑妲�(g貌u)璞★級銆�
绗笁绔犱笉椋藉拰鐑�
3
3.1 涓嶉＝鍜岀兇鐨勫懡鍚�銆佺祼(ji茅)妲�(g貌u)銆佺暟妲�(g貌u)楂�銆佺墿鐞嗘€ц唱(zh矛)
3.1.1 涓嶉＝鍜岀兇鐨勭祼(ji茅)妲�(g貌u) SP2銆丼P 闆滃寲鍜屜€ 閸垫€ц唱(zh矛)
3.1.2 涓嶉＝鍜岀兇鐨勫悓鍒嗙暟妲�(g貌u)楂斿拰鍛藉悕锛堢⒊鏋剁暟妲�(g貌u)銆佷綅缃暟妲�(g貌u)銆侀爢鍙嶇暟妲�(g貌u)銆佺郴绲�(t菕ng)鍛�
鍚嶆硶銆侀爢鍙嶇暟妲�(g貌u)楂旂殑鍛藉悕锛�
3.1.3 涓嶉＝鍜岀兇鐨勭墿鐞嗘€ц唱(zh矛)
3.2 涓嶉＝鍜岀兇鐨勫熀鏈弽鎳�
瑕浕鍔犳垚鍙嶆噳姝风▼銆佹捍閹撻洟瀛�銆佽Κ闆昏│鍔�銆佺⒊姝ｉ洟瀛愬強鍏剁┅(w臎n)瀹氭€�銆侀Μ姘忚(gu墨)鍓�銆�
瑾樺皫鏁堟噳锛屾父姝峰熀鍔犳垚鍙嶆噳姝风▼銆侀亷姘у寲鐗╂晥鎳夌殑瑙ｉ噵銆侀Μ鐖惧彲灏煎彲澶(gu墨)鍓囥€佸姞
鎴愬弽鎳変腑鐨勭⒊姝ｉ洟瀛�銆佺⒊姝ｉ洟瀛愮殑绲�(ji茅)妲�(g貌u)鍙婃€ц唱(zh矛)銆�
3.2.1 鍔犳垚鍙嶆噳
鍌寲鍔犳矮銆佺〖姘寲銆佸姞楣电礌銆佸姞楣靛寲姘€佸姞纭吀銆侀吀鍌寲鍔犳按銆佽垏鏈夋閰搁唶
閰氬姞鎴�銆佸姞娆￠沟閰�銆佽嚜鐢卞熀鍔犳垚绛�銆�
3.2.2 鑸囧崱璩撶殑鍙嶆噳銆佺儻鐑寸殑闋嗗弽鐣版(g貌u)鍙嶆噳
3.2.3 姘у寲鍙嶆噳锛堢挵(hu谩n)姘у寲銆侀珮閷抽吀閴€姘у寲鍜岃嚟姘у寲锛�
3.2.4 伪 鈥旀矮鍘熷瓙鐨勯沟浠ｅ弽鎳�
3.2.5 鑱氬悎鍙嶆噳
3.3 涓嶉＝鍜岀兇鐨勪締婧愬拰鍒跺倷
3.4 鐐旂兇鐨勭壒娈婂弽鎳�
3.4.1 鐐旂兇鐨勮Κ鏍稿姞鎴�
3.4.2 鐐旂兇鐨勬椿鎾ユ矮鍙嶆噳
鐐旂兇鐨勬椿鎾ユ矮閰告€�銆侀憭鍒ャ€佽垏鍫块噾灞弽鎳�銆佺倲鐑寸殑鐑峰熀鍖栧弽鎳�銆�
绗洓绔犲叡杌涗簩鐑兇鍜屽叡杌涙晥鎳�
4.1 鍏辫粵浜岀儻鐑寸殑鎬ц唱(zh矛)銆佺祼(ji茅)妲�(g貌u)鐗归粸
4.2 鍏辫粵鏁堟噳
4.3 鍏辫粵浜岀儻鐑寸殑鍖栧鐗规€�
鍔犳垚鍙嶆噳銆佺媱鑰虫柉鈥旈樋鐖惧痉锛圖iels-Alder 锛夌挵(hu谩n)鍔犳垚鍙嶆噳銆佽仛鍚堝弽鎳�銆�
绗簲绔犺姵棣欑兇
鑺抽鐑撮鍖栧悎鐗╃殑鍛藉悕銆佺祼(ji茅)妲�(g貌u)鍙婅姵棣欐€�銆傛帉鎻¤姵鐑撮鍖栧悎鐗╃殑閲嶈鎬ц唱(zh矛)锛氳嫰
鍙婂悓鍒嗙墿鐨勫弽鎳夈€佸彇浠ｅ弽鎳夌殑瀹氫綅瑕�(gu墨)寰�銆佸彇浠ｆ晥鎳夌殑瑙ｉ噵銆佸悎鎴愬彇浠ｈ嫰銆備簡瑙ｅ
鐠�(hu谩n)鑺抽鍖栧悎鐗╂€ц唱(zh矛)鍜岄潪鑻姵棣欓珨绯�
5.1 鑺抽鐑�
5.1.1 鑻殑鍒嗗瓙绲�(ji茅)妲�(g貌u)锛堝嚤搴嫆銆佸垎瀛愯粚閬撴硶銆佸叡鎸珫绨′粙锛岃姵棣欐€цВ閲嬶級
5.1.2 鍠挵(hu谩n)鑺抽鐑寸殑鐣版(g貌u)鐝�(xi脿n)璞�銆佸懡鍚嶅拰鐗╃悊鎬ц唱(zh矛)
5.1.3 鍠挵(hu谩n)鑺崇兇鐨勫寲瀛告€ц唱(zh矛)
4
5.1.3.1 鍙栦唬鍙嶆噳
楣典唬銆佺鍖�銆佺：鍖�銆佸倕鈥斿厠锛團ridel-Crafts锛夊弽鎳�锛涜嫰鐠�(hu谩n)瑕浕鍙栦唬鍙嶆噳姝�
绋嬶紱鑻挵(hu谩n)涓婂彇浠ｅ弽鎳夌殑瀹氫綅瑕�(gu墨)寰嬶紙鐞嗚珫瑙ｉ噵鍜屽悎鎴愪笂鐨勬噳鐢級銆�
5.1.3.2 楣电礌鐢插熀鍖栧弽鎳夈€佸姞鐗规浖 (Gatterman)- 绉戣但 (Koch)鍙嶆噳
5.1.3.3 浼锛� Birch 锛夐倓鍘熷弽鎳�
5.1.3.4 姘у寲鍙嶆噳锛堣嫰鐠�(hu谩n)姘у寲銆佸伌(c猫)閺堟哀鍖栵級
5.2 澶氱挵(hu谩n)鍙婄鐠�(hu谩n)鑺崇兇
5.2.1 涓夎嫰鐢插熀鍖栧悎鐗╁強鍏堕洟瀛愬拰鑷敱鍩虹殑绌�(w臎n)瀹氭€�銆佽伅(li谩n)鑻壒鎬у強鍚堟垚
5.2.2 钀樼殑绲�(ji茅)妲�(g貌u)鑸囧寲瀛告€ц唱(zh矛)锛堝彇浠ｅ弽鎳�銆佸姞鎴愬弽鎳夈€佹哀鍖栧弽鎳夛級
5.2.3 钂藉拰鑿茬殑绲�(ji茅)妲�(g貌u)鍜屾€ц唱(zh矛)
5.3 浼戝厠鐖捐(gu墨)鍓囧垽鏂烽潪鑻姵鐑�
绗叚绔犻沟浠ｇ兇
鎺屾彙楣典唬鐑寸殑鍒嗛鍜岀墿鐞嗘€ц唱(zh矛)銆佺祼(ji茅)妲�(g貌u)銆佸埗鍌欏拰鍖栧鎬ц唱(zh矛)
6.1 楣典唬鐑寸殑鍒嗛鍙婂懡鍚�銆佺祼(ji茅)妲�(g貌u)銆佸悓鍒嗙暟妲�(g貌u)鍜岀墿鐞嗘€ц唱(zh矛)
6.2 楣典唬鐑寸殑鍖栧鎬ц唱(zh矛)
6.2.1 楣典唬鐑寸殑鍩烘湰鍙嶆噳锛氬彇浠�銆佹秷闄�銆侀倓鍘�
鍙栦唬鍙嶆噳锛堟按瑙�銆侀唶瑙�銆佹皑瑙ｃ€佽垏纭濋吀閵€鍙婃鞍鍖栭垑鐨勫弽鎳夛級銆傛秷鍘诲弽鎳夎垏鍙�
鍚�銆�
6.2.2 椋藉拰纰冲師瀛愪笂鐨勮Κ鏍稿彇浠ｅ弽鎳夎垏娑堥櫎鍙嶆噳
鍙栦唬鍙嶆噳鐨勬鐞� SN1銆丼N2锛涙秷闄ゅ弽鎳夌殑姗熺悊 E1銆丒2锛涘彇浠ｅ弽鎳夎垏娑堥櫎鍙嶆噳
鐨勭珛楂斿寲瀛搞€佸奖闊垮洜绱犲拰绔剁埈銆�
6.3 楣典唬鐑寸殑鍒舵硶锛堢敱鐑村埗鍌�銆佺敱閱囧埗鍌�銆侀沟浠ｇ兇鐨勪簰鎻涳級
6.4 楣典唬鐑磋垏閲戝爆鍙嶆噳
鏍兼皬瑭﹀姂鐨勫埗鍌�銆佹€ц唱(zh矛)銆佸弽鎳夌壒鎬ц垏鍚堟垚涓殑鎳夌敤銆傛湁姗熼嫲瑭﹀姂銆乄urtz 鍙�
鎳�銆�
6.5 楣典唬鐑兇鍜岄沟浠ｈ姵鐑寸殑鍖栧鎬ц唱(zh矛)
绗竷绔犵珛楂斿寲瀛�
7.1 浜嗚В灏嶆槧鐣版(g貌u)鐝�(xi脿n)璞�銆佺墿璩�(zh矛)鐨勬棆鍏夋€ц垏鍒嗗瓙绲�(ji茅)妲�(g貌u)鐨勯棞(gu膩n)绯伙紙鎵嬫€�銆佸皪绋卞洜绱�銆佸钩
闈㈠亸鎸厜鍜屾棆鍏夋€�銆佹棆鍏夊剙鍜屾瘮鏃嬪厜搴︼級
7.2 鍚湁鎵嬫€х⒊鍘熷瓙鍖栧悎鐗╃殑灏嶆槧鐣版(g貌u)
7.2.1 鍚湁涓€鍊嬫墜鎬х⒊鍘熷瓙鍖栧悎鐗╃殑灏嶆槧鐣版(g貌u)锛堝皪鏄犻珨銆佸娑堟棆楂�銆佽不姝囩埦鎶曞奖
寮忥級
7.2.2 灏嶆槧鐣版(g貌u)楂旂殑妲�(g貌u)鍨嬶紙鐩稿皪妲�(g貌u)鍨嬪拰绲曞皪妲�(g貌u)鍨嬨€佹(g貌u)鍨嬬殑 R/S 娉�銆丏/L 娉曪級
7.2.3 鍚叐鍊嬫墜鎬х⒊鍘熷瓙鍖栧悎鐗╃殑灏嶆槧鐣版(g貌u)
5
7.2.4 鐠�(hu谩n)鐙€鐨勫寲鍚堢墿鐨勫皪鏄犵暟妲�(g貌u)
7.3 鍚墜鎬ц桓鎴栧惈鎵嬫€ч潰鐨勫寲鍚堢墿鐨勭珛楂旂暟妲�(g貌u)楂�锛屽惈鎵嬫€х⒊鍘熷瓙鍖栧悎鐗╃殑灏嶆槧鐣�
妲�(g貌u)锛堜笝浜岀儻鍨�銆佽伅(li谩n)鑻瀷锛岃灪鏃嬪瀷鍖栧悎鐗╋級
7.4 澶栨秷鏃嬮珨銆佹媶鍒嗗拰涓嶅皪绋卞悎鎴�
7.5 鎺屾彙绔嬮珨鍖栧鍦ㄧ爺绌跺弽鎳夋绋嬩腑鐨勬噳鐢�
绗叓绔犳湁姗熷寲鍚堢墿鐨勬尝璀滃垎鏋�
鐔熸倝绱銆佺磪澶栧厜璀�銆佹牳纾佸叡鎸瓬鐨勫熀鏈師鐞嗗強鍦ㄦ湁姗熷寲鍚堢墿绲�(ji茅)妲�(g貌u)娓畾涓殑
鎳夌敤浜嗚В璩�(zh矛)璀滅殑鍩烘湰鍘熺悊鍙婃噳鐢�銆�
8.1 绱呭鍏夎瓬
8.1.1 绱呭鍏夎瓬鐨勫熀鏈師鐞嗭紙鍒嗗瓙鎸嫊椤炲瀷銆佺磪澶栧厜璀滃湒鐨勮〃绀烘柟娉曪級
8.1.2 閲嶈瀹樿兘鍦樼殑鐗瑰緛鍚告敹宄�銆佸奖闊跨磪澶栧惛鏀朵俊铏熶綅绉荤殑鍥犵礌
8.1.3 绱呭鍏夎瓬鐨勮В鏋�
8.2 鏍哥鍏辨尟璀�
8.2.1 浜嗚В鏍哥鍏辨尟鐨勫熀鏈師鐞�
8.2.2 鍏稿瀷鍖栧悎鐗╃殑鏍哥鍏辨尟璀滃墫鏋愶紙灞忚斀鏁堟噳銆佸寲瀛镐綅绉汇€佸嘲闈㈢⿳銆�
宄板挤搴�銆佽嚜鏃嬪伓鍚堣垏鑷棆瑁傚垎锛�
8.3 绱鍏夎瓬
绱鍏夎瓬鐨勫熀鏈師鐞嗐€佺传澶栧厜璀滃湒銆佸悇椤炲寲鍚堢墿鐨勯浕瀛愯簫閬枫€佺传澶栧厜璀滆垏鍒�
瀛愮祼(ji茅)妲�(g貌u)鐨勯棞(gu膩n)绯�銆�
8.4 璩�(zh矛)璀�
璩�(zh矛)璀滅殑鍩烘湰鍘熺悊鑸囪唱(zh矛)璀滃剙銆傝唱(zh矛)璀滃湒闆㈠瓙鐨勪富瑕侀鍨嬨€佸舰鎴愬強鎳夌敤锛屽奖闊�
闆㈠瓙褰㈡垚鐨勫洜绱狅紝鍚勯鍖栧悎鐗╃殑璩�(zh矛)璀滃湒鐗瑰緛銆�
绗節绔犻唶銆侀厷鍜岄啔
9.1 閱�
9.1.1 閱囩殑鐗╃悊
閱囩殑姘嵉灏嶉唶鐗╃悊鎬ц唱(zh矛)褰遍熆銆�
9.1.2 閱囩殑鍖栧鎬ц唱(zh矛)
閱囪垏娲绘綉閲戝爆鍙嶆噳銆佽垏楣靛寲纾凤紙鎴栦簽纭叞姘級鍙嶆噳銆佽垏鐒℃閰革紙姘沟閰搞€佺～
閰�銆佺閰革級鑸囬叞姘拰閰搁厫绛夊弽鎳�銆傞唶鐨勮劔姘�銆佹哀鍖栧拰鑴矮鍙嶆噳銆傞劙浜岄唶鐗规湁鐨勫弽
鎳夛紙闋诲摢閱囬噸鎺掞級銆侀劙鍩哄弮鑸�銆�
9.1.3 娑堝幓鍙嶆噳鑸囧彇浠ｅ弽鎳夋绋�
9.1.4 鎺屾彙閱囩殑鍒舵硶
9.2 閰�
6
閰氱茎鍩虹殑鎬ц唱(zh矛)锛氬急閰告€с€侀厷閱氱殑鐢熸垚銆侀’鑹插弽鎳�銆傞厷椤炶嫰鐠�(hu谩n)涓婅Κ闆诲彇浠ｅ弽鎳夈€�
姘у寲鍙嶆噳銆�
9.3 閱�
9.3.1 閱氱殑鍒舵硶
9.3.2 閱氱殑鐗╃悊鍖栧鎬ц唱(zh矛)鍙婂弽鎳夛細楣界殑鐢熸垚銆侀啔閸电殑鏂疯銆侀亷姘у寲鐗╃殑鐢熸垚
绗崄绔犻啗銆侀叜鍜岄唽
10.1 閱�銆侀叜鐨勭墿鐞嗘€ц唱(zh矛)
10.2 閱涖€侀叜鐨勫寲瀛告€ц唱(zh矛)
10.2.1 瑕牳鍔犳垚鍙嶆噳
閱涙垨閰垏姘鞍閰�銆佷簽纭吀姘垑銆侀唶銆佹皑鐨勮鐢熺墿銆佹牸鍒╅泤瑭﹀姂銆佺倲閳夎Κ鏍稿姞鎴愬弽
鎳夊強鎳夌敤銆�
10.2.2 閱涙垨閰殑伪 鈥旀矮鍘熷瓙鐨勫弽鎳�
閱涙垨閰湪閰告垨鍫垮偓鍖栨浠朵笅楣典唬銆傜茎閱涚府鍚堝弽鎳�
10.2.3 閱涙垨閰殑姘у寲閭勫師鍙嶆噳
鎵樺€│鍔戙€佽不鏋楄│鍔戠殑寮辨哀鍖栧弽鎳�锛涢珮閷抽吀閴€绛夊挤姘у寲鍔戠殑姘у寲鍙嶆噳銆�
閱涙垨閰殑閭勫師鍙嶆噳锛氬绋浠朵笅閭勫師鎴愰唶銆侀倓鍘熸垚浜炵敳鍩恒€�
姝у寲鍙嶆噳锛氬悍灏兼煡缇呭弽鎳�銆�
10.3 閱涖€侀叜鐨勫埗娉曪紙閱囩殑姘у寲銆佺兇鐨勬哀鍖�銆佸仌浜岄沟浠ｇ墿鐨勬按瑙ｃ€佸倕鈥斿厠?锛涱姮?br/>鍙嶆噳銆佺倲鐑寸殑缇板熀鍖�銆佺晶閰稿強鍏惰鐢熺墿鐨勯倓鍘燂級
10.4 閲嶈鐨勯啗銆侀叜鐗规€э細鐢查啗銆佷箼閱涳紙涔欑儻姘у寲鍚堟垚涔欓啗锛夈€佷笁姘箼閱�銆佽嫰鐢查啗
锛堝畨鎭绺悎锛夈€佷笝閰�銆佷竵浜岄叜锛堥幊瑭﹀姂锛夈€佺挵(hu谩n)宸遍叜
10.5 涓嶉＝鍜岀景鍩哄寲鍚堢墿鐨勫寲瀛告€ц唱(zh矛)锛毼� 锛屛� 鈥斾笉椋藉拰閱涢叜鐨勫姞鎴愬弽鎳�銆佹彃鐑(gu墨)
寰�
绗崄涓€绔犵晶閰稿強缇ч吀琛嶇敓鐗�
11.1 缇ч吀鍙婄晶閰歌鐢熺墿鐨勫懡鍚�銆佺墿鎬у強鍏夎瓬鐗规€�
11.2 缇ч吀鐨勭祼(ji茅)妲�(g貌u)鑸囬吀鎬э紙瑾樺皫鏁堟噳锛屽叡杌涙晥鎳夊強鍫存晥鎳夌殑褰遍熆锛�
11.3 缇ч吀鐨勫埗鍌�
11.4 缇ч吀鐨勫寲瀛稿弽鎳�
缇ч吀鐨勯吀鎬�銆佺晶鍩轰腑姘師瀛愮殑鍙嶆噳锛堝彇浠ｅ熀灏嶉吀鎬х殑褰遍熆銆佽獦灏庢晥鎳夛級銆佺晶
閰歌鐢熺墿鐨勭敓鎴�銆佽劔缇у弽鎳夈€佺晶閰肝� 鈥擧 鐨勯沟浠ｅ弽鎳�銆侀倓鍘燂紙琚矮鍖栭媮閶伴倓鍘燂級銆�
閰寲鍙嶆噳鐨勬鐞�銆�
11.5 浜屽厓閰稿拰缇ュ熀閰哥殑鎬ц唱(zh矛)銆�
11.6 缇ч吀琛嶇敓鐗╃殑鍖栧鎬ц唱(zh矛)
7
缇ч吀琛嶇敓鐗╃殑鍙栦唬銆侀倓鍘熷弽鎳夈€傜晶閰歌鐢熺墿鑸囨牸鍒╅泤瑭﹀姂鍙嶆噳銆傜晶閰歌鐢熺墿鐨勭壒
鎬э紙閰€侀叞鑳虹殑鐗规€э級銆�
11.7 涔欓叞涔欓吀涔欓叝鍜屼笝浜岄吀浜屼箼閰殑鍒跺倷鑸囨噳鐢�
涔欓叞涔欓吀涔欓叝鐨勫埗鍌�銆佷簰璁婄暟妲�(g貌u)鍙婂叾鍦ㄥ悎鎴愪笂鐨勬噳鐢�銆備笝浜岄吀浜屼箼閰強鍏跺湪
鍚堟垚涓婄殑鎳夌敤銆�
绗崄浜岀珷鍚爱鍖栧悎鐗�
12.1 鑳虹殑鍒嗛銆佸懡鍚�銆佺祼(ji茅)妲�(g貌u)銆佺墿鐞嗘€ц唱(zh矛)鍜屽厜璀滅壒寰�
12.2 鑳虹殑鍖栧鎬ц唱(zh矛)
12.2.1 鑳虹殑绲�(ji茅)妲�(g貌u)鍜屽牽鎬э紙绲�(ji茅)妲�(g貌u)鐗归粸銆佹墜鎬�銆佸牽鎬у強褰遍熆鍫挎€уぇ灏忕殑鍥犵礌锛�
12.2.2 鎴愰菇銆佸洓绱氶姩楣界殑褰㈡垚銆佺壒榛炲強鎳夌敤锛堝竟搴曠敳鍩哄寲鍙嶆噳銆佸洓绱氶姩鍫跨殑褰�
鎴�锛岀浉杞�(zhu菐n)绉诲偓鍖栧姂锛�銆� Hofmann 娑堥櫎
12.2.3 閰板熀鍖栧弽鎳夛紙涔�?锛涱嚃鈶磀鏂牎鍙嶆噳锛�
12.2.4 鑳虹殑姘у寲鍜� Cope 娑堥櫎锛堥爢鍨嬫秷闄わ級
12.2.5 鑳鸿垏浜炵閰哥殑鍙嶆噳锛堥噸姘寲鍙嶆噳锛夎垏鎳夌敤
12.2.6 鑳虹殑鐗规畩鍙嶆噳锛堟哀鍖�銆佽嫰鐠�(hu谩n)涓婃槗鍙栦唬锛汳annich 鍙嶆噳鍙婂叾鎳夌敤锛�
12.3 鑳虹殑鍒跺倷
12.4 閲嶆爱鍜屽伓姘寲鍚堢墿锛堥噸姘敳鐑峰強鍗¤硴銆佹爱鐑€佺枈姘寲鐗╃殑鍒跺倷銆佸弽鎳夛級
12.5 閲嶆爱楣界殑鎬ц唱(zh矛)鑸囨噳鐢�
12.6 纭濆熀鍖栧悎鐗�
浜嗚В纭濆熀鍖栧悎鐗╁垎椤�銆佺祼(ji茅)妲�(g貌u)鍜屽懡鍚嶃€傜鍩哄寲鍚堢墿鐨勬€ц唱(zh矛)锛堢鍩哄皪伪 鈥旀矮鍘熷瓙鐨勫奖
闊匡紙浜掕畩鐣版(g貌u)锛夐倓鍘�銆佺鍩哄皪鑻挵(hu谩n)涓婂彇浠ｅ熀鐨勫奖闊匡級
12.7 鑵堝拰鐣拌厛锛堝垎瀛愮祼(ji茅)妲�(g貌u)銆佹按瑙ｅ拰閭勫師鍙嶆噳锛�
绗崄涓夌珷鍚～銆佺７銆佺鍖栧悎鐗�
13.1 纭€佺７鍏冪礌鍘熷瓙鐨勯浕瀛愭(g貌u)鍨嬪拰鎴愰嵉鐗瑰緛
13.2 鍚～鍖栧悎鐗╃殑绲�(ji茅)妲�(g貌u)椤炲瀷鍜屽懡鍚嶅強鍜屽悎鎴愯垏鍙嶆噳
13.3 鍚７鍖栧悎鐗╃殑閲嶈鍙嶆噳锛堝舰鎴愬纾烽菇鐨勫弽鎳�銆佺董鐙勫笇瑭﹀姂鍙婂叾鍙嶆噳锛�
13.4 楣典唬纭呯兎鍙婄閱�銆佺姘х兎鐨勫悎鎴愬強鍏舵噳鐢�
绗崄鍥涚珷闆滅挵(hu谩n)鍖栧悎鐗�
14.1 鐠�(hu谩n)鍖栧悎鐗╃殑鍒嗛鍜屽懡鍚嶏紙闊宠娉曪級
14.2 浜斿厓鍜屽叚鍏冮洔鐠�(hu谩n)鍖栧悎鐗╃殑鍖栧鎬ц唱(zh矛)
14.3 闆滅挵(hu谩n)鍖栧悎鐗╃殑鍒跺倷鏂规硶
绗崄浜旂珷鍛ㄧ挵(hu谩n)鍙嶆噳
闆荤挵(hu谩n)鍖栧弽鎳�锛涳紙2+2锛夈€侊紙2+4锛�銆丏iels-Alder 鐠�(hu谩n)鍔犳垚鍙嶆噳锛浵� -閬风Щ鍙嶆噳锛汣ope
閲嶆帓锛涙矮鍘熷瓙鎴栫⒊鍘熷瓙鍙冨姞鐨勯伔绉诲弽鎳�銆�
8
绗崄鍏珷纰虫按鍖栧悎鐗�
16.1 鍠硸绲�(ji茅)妲�(g貌u)鑸囩墿鐞嗗寲瀛告€ц唱(zh矛)
16.1.1 鍠硸鐨勭祼(ji茅)妲�(g貌u)锛堝柈绯栫殑妲�(g貌u)閫犲紡鐨勭⒑瀹氥€佺珛楂旀(g貌u)鍨�銆佺挵(hu谩n)鐙€绲�(ji茅)妲�(g貌u)閫忚寮忋€佹(g貌u)璞�
寮忥級
16.1.2 鍠硸鐨勬€ц唱(zh矛)锛堝樊鍚戠暟妲�(g貌u)鍖�銆佹哀鍖栬垏閭勫師銆佹垚鑴庡弽鎳�銆佹垚鑻峰弽鎳夛級
16.1.3 閲嶈鐨勫柈绯栵紙钁¤悇绯�銆佹灉绯栥€佸崐涔崇硸銆佹牳绯�銆佽劔姘ф牳绯栵級
16.2 浜岀硸锛堥亥鑺界硸銆佺簴缍簩绯栥€佷钩绯�銆佽敆绯栵級
16.3 澶氱硸锛堟穩绮夈€佺簴缍礌銆佸崐绾栫董绱�銆佸彸鏃嬬硸閰愶級
绗崄涓冪珷姘ㄥ熀閰搞€佸鑲藉拰铔嬬櫧璩�(zh矛)
17.1 姘ㄥ熀閰哥殑绲�(ji茅)妲�(g貌u)銆佸垎椤�銆佸懡鍚�銆佸埗娉曪紙Strecker 鍚堟垚銆佅� - 楣典唬閰告皑瑙ｃ€�
Gabriel 鍚堟垚銆佷笝浜岄吀閰硶锛夈€佸寲瀛告€ц唱(zh矛)锛堝叐鎬у拰绛夐浕榛�銆佹皑鍩虹殑鍙嶆噳銆佽劔缇у弽
鎳夈€佽垏姘村悎鑼氫笁閰弽鎳夛級
17.2 澶氳偨绲�(ji茅)妲�(g貌u)纰哄畾鍜屽悎鎴愬師鐞嗙啊浠�
17.3 浜嗚泲鐧借唱(zh矛)鐨勫垎椤�銆佺祼(ji茅)妲�(g貌u)鍜岄噸瑕佹€ц唱(zh矛)锛堝叐鎬у拰绛夐浕榛炪€佽啝楂旀€ц唱(zh矛)銆佹矇娣€銆佽畩
鎬�銆佹按瑙ｃ€侀’鑹插弽鎳夛級
绗崄鍏珷钀滈銆佺斁鏃忓寲鍚堢墿
18.1 钀滈鐨勫畾缇┿€佸垎椤�銆佺暟鎴婁簩鐑(gu墨)鍓囷細鍠悳銆佸€嶅崐钀滃強鍏跺畠钀滈
钀滃寲鍚堢墿鐨勭祼(ji茅)妲�(g貌u)鐨勪竴鑸浉瀵柟娉曪細VA銆佽儭铇垮崪绱�銆佹妾啗銆佹鍖栭唶銆侀钁夐唶銆佽杽
鑽烽唶銆佽拵绋€銆侀緧鑵�銆佹鑵︺€�
18.2 鐢炬棌鍖栧悎鐗╃殑鍩烘湰楠ㄦ灦鍜屽懡鍚�
涓�銆佸弮鑰冨湒鏇�
1 锛夐偄鍏舵瘏绛夈€婂熀绀庢湁姗熷寲瀛搞€� (涓�,涓嬪唺 ) 绗笁鐗堬紝鍖椾含锛岄珮绛夋暀鑲插嚭鐗堢ぞ锛�
2005 骞� 6 鏈�
2 锛夊嫉鏂囧嫟绛夈€婃湁姗熷寲瀛搞€嬬浜旂増锛屽寳浜�锛岄珮鏁欏嚭鐗堢ぞ锛�2014 骞� 7 鏈�
鍏嶈铂鑱叉槑锛氭湰鏂囩郴杞�(zhu菐n)杓夎嚜缍�(w菐ng)绲★紝濡傛湁渚电姱锛岃珛鑱�(li谩n)绯绘垜鍊戠珛鍗冲埅闄�锛屽彟锛氭湰鏂囧儏浠ｈ〃浣滆€呭€嬩汉瑙€榛�锛岃垏鏈恫(w菐ng)绔欑劇闂�(gu膩n)銆傚叾鍘熷壍(chu脿ng)鎬т互鍙婃枃涓櫝杩版枃瀛楀拰鍏�(n猫i)瀹规湭缍�(j墨ng)鏈珯璀夊锛屽皪鏈枃浠ュ強鍏朵腑鍏ㄩ儴鎴栬€呴儴鍒嗗収(n猫i)瀹广€佹枃瀛楃殑鐪熷鎬�銆佸畬鏁存€�銆佸強鏅傛€ф湰绔欎笉浣滀换浣曚繚璀夋垨鎵胯锛岃珛璁€鑰呭儏浣滃弮鑰�锛屽苟璜嬭嚜琛屾牳瀵︾浉闂�(gu膩n)鍏�(n猫i)瀹广€�
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鏂囩珷鎼滅储
鎮ㄧ従(xi脿n)鍦ㄧ殑浣嶇疆锛� 
